Preparation of Gd2O2S:Pr Scintillation Ceramics by Pressureless Reaction Sintering Method

材料科学技术（英文）, 2009, 25(2): 254-258.

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

2.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

3.Key Laboratory for EPM of Ministry of Education, Northeastern University, Shenyang 110004, China

4.College of Materials & Chemical Engineering, Liaoning Institute of Technology, Jinzhou 121001, China

5.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

6.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

Preparation of Gd2O2S:Pr Scintillation Ceramics by Pressureless Reaction Sintering Method

Jingbao Lian ^1, , Xudong Sun ^2, , Tie Gao ^3, , Qiang Li ^4, , Xiaodong Li ^5, , Zhigang Liu ^6,

1.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

2.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

3.Key Laboratory for EPM of Ministry of Education, Northeastern University, Shenyang 110004, China

4.College of Materials & Chemical Engineering, Liaoning Institute of Technology, Jinzhou 121001, China

5.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

6.Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

Keywords： Scintillation ceramics

Fabrication of Gd2O2S:Pr scintillation ceramics by pressureless reaction sintering was investigated. The 2Gd2O3.(Gd,Pr)2(SO4)3.mH2O precursor was made by hydrotherrnal reaction using commercially available Gd2O3, Pr6O11 and H2SO4 as the starting materials. Then single phase Gd2O2SO4:Pr powder was obtained by calcining the precursor at 750℃ for 2 h. The Gd2O2SO4:Pr powder compacts can be sintered to single phase Gd2O2S:Pr ceramics with a relative density of 99% and mean grain size of 30 μm at 1750℃ for 2 h in flowing hydrogen atmosphere. Densification and microstructural development of the Gd2O2S:Pr ceramics were examined. Luminescence spectra of the Gd2O2S:Pr ceramic under 309 nm UV excitation and X-ray excitation show a green emission at 511 nm as the most prominent peak, which corresponds to the 3P0-ZH4 transition of Pr3+ ions.

参考文献

[1]	Y.Ito;H.Yamada;M.Yoshida;H.Fujii G.Toda H.Takeuchi and Y.Tsukuda .[J].Journal of Applied Physics,1988,27:1371.
[2]	R.Nakamura .[J].Journal of the American Ceramic Society,1999,82:2407.
[3]	M.Yoshida;M.Nakagawa;H.Fujii .[J].Japanese Journal of Applied Physics,1988,27:1574.
[4]	J.Y.Chen;Y.Shi;T.Feng;J.L.Shi .[J].Journal of Alloys and Compounds,2005,391:181.
[5]	H.Yamada;A.Suzuki;Y.Uchida .[J].Journal of the Electrochemical Society,1989,138:2713.
[6]	J.Leppert;W.Rossner .[P].U.S.Patent No.5296163,1994.
[7]	C.Greskovich;S.Duclos .GE Technical Report,96CRD166[R].,1996.
[8]	Takahara .[P].U.S.Patent No.6504156B1,2003.
[9]	S.Ludmila;D.V]adimir;G.Etena .[P].WO2005IB51562,2005.
[10]	E. I. Gorokhova;V. A. Demidenko;O. A. Khristich;S. B. Mikhrin;P. A. Rodnyi .Luminescence properties of ceramics based on terbium-doped gadolinium oxysulfide[J].Journal of optical technology,2003(10):693-698.
[11]	Leppert .[P].U.S.Patent No.6296824B1,2001.
[12]	K.Ikeue;T.Kawano;M.Eto;D.J.Zhang and M.Machida .[J].Journal of Alloys and Compounds,2008,451:338.
[13]	W.Paul .[J].Journal of Magnetism and Magnetic Materials,1990,87:29.
[14]	M.Machida;K.Kawarnura;K.Ito;K.Ikeue .[J].Chemistry of Materials,2005,7:1489.
[15]	E.I.Gorokhova;V.A.Demidenko;S.B.Eronko;O.A.Khristich .[J].Journal of Optical Technology,2005,72:54.
[16]	E.I.Gorokhova;V.A.Demidenko;S.B.Eronko;O.A.Khristich .[J].Journal of Optical Technology,2006,73:133.
[17]	L.S.Bolyasnikova;V.A.Demidenko;S.B.Eron;ko and O.P.Ovsyannikova .[J].Journal of Optical Technology,2006,73:139.
[18]	W.Rossner;M.Ostertag;F.Jermann .[J].Phys Chem Lumin Mater -Proc Electrochem Soc,1998,24:189.
[19]	R.Nakamura;N.Yamada;M.Ishii .[J].Japanese Journal of Applied Physics,1999,38:6923.
[20]	Y.Tian;W.H.Cao;X.X.Luo;Y.Fu .[J].Journal of Alloys and Compounds,2007,433:317.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Preparation of Gd2O2S:Pr Scintillation Ceramics by Pressureless Reaction Sintering Method

参考文献