NixCo4-xSb12化合物的制备及热电性能研究

功能材料, 2004, 35(z1): 929-935.

NixCo4-xSb12化合物的制备及热电性能研究

张隆 ^1, , 张久兴 ^2, , 路清梅 ^3, , 刘科高 ^4,

1.北京工业大学,新型功能材料教育部重点实验室,北京,100022

2.北京工业大学,新型功能材料教育部重点实验室,北京,100022

3.北京工业大学,新型功能材料教育部重点实验室,北京,100022

4.北京工业大学,新型功能材料教育部重点实验室,北京,100022

基金项目: 国家自然科学基金(50271001)

关键词： n型热电材料 , Skutterudite化合物 , Ni置换 , 放电等离子烧结

Preparation and thermoelectric properties of NixCo4-xSb12 compounds

以Ni作为添加元素,利用放电等离子技术制备了NixCo4-xSb12(x=0-0.35)化合物热电材料.通过先进的性能表征手段,深入探讨了NixCo4-xSb12化合物的热电性能,为n型热电材料的研究提供了有价值的参考.实验结果表明,一定量Ni的添加,能有效改善材料热电性能,提高热电优值;在Ni添加量x=0.2时,Ni0.2Co3.8Sb12化合物在温度T=773K时具有最大的热电性能优值ZTmax=0.45.

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材料期刊网

NixCo4-xSb12化合物的制备及热电性能研究

Preparation and thermoelectric properties of NixCo4-xSb12 compounds

参考文献