木质素是一种自然界唯一能提供再生芳基化舍物的天然可再生资源.水热液化技术是一种环境友好、可持续发展的高新技术,不仅能将木质素转化为生物燃料,也可将木质素转化为酚类化合物等高附加值化学品.文中阐述了超(亚)临界水热液化降解木质素为酚类化学品的最新进展,主要介绍了木质素的结构、超(亚)临界水的性质及水热液化的优点,并分析了水热液化木质素的影响因素及反应机理.最后对超(亚)临界水热液化降解木质素为酚类化学品的前景进行了展望.
参考文献
| [1] | Turunen M.;Alvila L.;Pakkanen TT.;Rainio J. .Modification of phenol-formaldehyde resol resins by lignin, starch, and urea[J].Journal of Applied Polymer Science,2003(2):582-588. |
| [2] | Alonso MV;Oliet A;Perez JM;Rodriguez F;Echeverria J .Determination of curing kinetic parameters of lignin-phenol-formaldehyde resol resins by several dynamic differential scanning calorimetry methods[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2004(1/2):161-167. |
| [3] | Tejado A;Pena C;Labidi J;Echeverria JM;Mondragon I .Physico-chemical characterization of lignins from different sources for use in phenol-formaldehyde resin synthesis[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2007(8):1655-1663. |
| [4] | 王明存.木质素超临界溶剂降解反应及其在酚醛树脂合成中的应用[J].高分子学报,2011(12):1433-1438. |
| [5] | 孔令照,李光明,贺文智,王华.超（亚）临界水热法处理有机废物的研究进展[J].化工进展,2006(05):469-474. |
| [6] | Kruse A;Dinjus E .Hot compressed water as reaction medium and reactant - Properties and synthesis reactions[J].The Journal of Supercritical Fluids,2007(26):362-380. |
| [7] | 彭文才 .农作物秸秆水热液化过程及机理的研究[D].华东理工大学,2011. |
| [8] | Saqib Sohail Toor;Lasse Rosendahl;Andreas Rudolf .Hydrothermal liquefaction of biomass: A review of subcritical water technologies[J].Energy,2011(5):2328-2342. |
| [9] | Hunter SE;Savage PE .Recent advances in acid- and base-catalyzed organic synthesis in high-temperature liquid water[J].Chemical Engineering Science,2004(22/23):4903-4909. |
| [10] | 傅木星 .生物质水热法液化行为研究[D].湖南大学,2006. |
| [11] | Tymchyshyn, M;Xu, CB .Liquefaction of bio-mass in hot-compressed water for the production of phenolic compounds[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2010(7):2483-2490. |
| [12] | Wahyudiono;Takayuki Kanetake;Mitsuru Sasaki .Decomposition of a Lignin Model Compound under Hydrothermal Conditions[J].Chemical Engineering & Technology: Industrial Chemistry -Plant Equipment -Process Engineering -Biotechnology,2007(8):1113-1122. |
| [13] | Hanna Pinkowska;Pawel Wolak;Adrianna Zlocinska.Hydrothermal decomposition of alkali lignin in sub- and supercritical water[J].Chemical engineering journal,2012:410-414. |
| [14] | 张良 .亚临界条件下水葫芦的水热液化研究[D].复旦大学,2012. |
| [15] | Wahyudiono;Mitsuru Sasaki;Motonobu Goto .Recovery of phenolic compounds through the decomposition of lignin in near and supercritical water[J].Chemical Engineering and Processing,2008(9/10):1609-1619. |
| [16] | Motofumi Saisu;Takafumi Sato;Masaru Watanabe;Tadafumi Adschiri;Kunio Arai .Conversion of Lignin with Supercritical Water-Phenol Mixtures[J].Energy & Fuels,2003(4):922-928. |
| [17] | Takafumi Sato;Takeshi Furusawa;Yasuyoshi Ishiyama;Hirokazu Sugito;Yasutomo Miura .Effect of Water Density on the Gasification of Lignin with Magnesium Oxide Supported Nickel Catalysts in Supercritical Water[J].Industrial & Engineering Chemistry Research,2006(2):615-622. |
| [18] | Liquefaction of empty palm fruit bunch (EPFB) in alkaline hot compressed water[J].Renewable energy,2010(6):1220. |
| [19] | Ning Yan;Chen Zhao;Paul J. Dyson;Chen Wang;Ling-tao Liu;Yuan Kou .Selective Degradation of Wood Lignin over Noble-Metal Catalysts in a Two-Step Process[J].ChemSusChem,2008(7):626-629. |
| [20] | Zhang, B;Huang, HJ;Ramaswamy, S .Reaction kinetics of the hydrothermal treatment of lignin[J].Applied Biochemistry and Biotechnology. Part A, Enzyme Engineering and Biotechnology,2008(1/3):119-131. |
| [21] | Barbier, J.;Charon, N.;Dupassieux, N.;Loppinet-Serani, A.;Mahe, L.;Ponthus, J.;Courtiade, M.;Ducrozet, A.;Quoineaud, A. A.;Cansell, F..Hydrothermal conversion of lignin compounds. a detailed study of fragmentation and condensation reaction pathways.[J].Biomass & Bioenergy,2012:479-491. |
| [22] | Shimin Kang;Xianglan Li;Juan Fan .Classified Separation of Lignin Hydrothermal Liquefied Products[J].Industrial & Engineering Chemistry Research,2011(19):11288-11296. |
| [23] | Shimin Kang;Xianglan Li;Juan Fan;Jie Chang .Hydrothermal conversion of lignin: A review[J].Renewable & sustainable energy reviews,2013(Nov.):546-558. |
| [24] | Faravelli, T.;Frassoldati, A.;Migliavacca, G.;Ranzi, E. .Detailed kinetic modeling of the thermal degradation of lignins[J].Biomass & Bioenergy,2010(3):290-301. |
| [25] | Tau Len-Kelly Yong;Yukihiko Matsumura .Kinetic Analysis of Lignin Hydrothermal Conversion in Sub- and Supercritical Water[J].Industrial & Engineering Chemistry Research,2013(16):5626-5639. |
| [26] | Wahyudiono;Mitsuru Sasaki;Motonobu Goto .Thermal decomposition of guaiacol in sub- and supercritical water and its kinetic analysis[J].Journal of Material Cycles and Waste Management,2011(1):68-79. |
| [27] | Wahyudiono;Mitsuru Sasaki;Motonobu Goto .Conversion of biomass model compound under hydrothermal conditions using batch reactor[J].Fuel,2009(9):1656-1664. |
| [28] | Guillermo Gonzalez;Joan Salvado;Daniel Montane .Reactions of vanillic acid in sub- and supercritical water[J].The Journal of Supercritical Fluids,2004(1):57-66. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%