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设计了一种全新的乳液聚合法,并结合自下而上的模板辅助电化学沉积方法制备了大面积有序周期常数为135nm的金属银双渔网结构超材料.新的制备方法在纳米颗粒经过预处理后,依然能够保持优良的单分散型,易于获得高质量的大面积纳米级二维胶体晶体模板,并且电磁谐振现象明显增强.

参考文献

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[4] Chanda, D.;Shigeta, K.;Gupta, S.;Cain, T.;Carlson, A.;Mihi, A.;Baca, A.J.;Bogart, G.R.;Braun, P.;Rogers, J.A. .Large-area flexible 3D optical negative index metamaterial formed by nanotransfer printing[J].Nature nanotechnology,2011(7):402-407.
[5] Retsch, M;Zhou, ZC;Rivera, S;Kappl, M;Zhao, XS;Jonas, U;Li, Q .Fabrication of Large-Area, Transferable Colloidal Monolayers Utilizing Self-Assembly at the Air/Water Interface[J].Macromolecular chemistry and physics,2009(3/4):230-241.
[6] Colson, P.;Cloots, R.;Henrist, C. .Experimental design applied to spin coating of 2d colloidal crystal masks: A relevant method?[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(21):12800-12806.
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