CdS thin films were deposited by the ion layer gas reaction (ILGAR) method. Structural, chemical, topographical development as well as optical and electrical properties of as-deposited and annealed thin films were investigated by XRD,SEM, XPS, AFM and UV-VIS. The results showed that the thin films are uniform, compact and good in adhesion to the substrates, and the growth of the films is 2.8 nm/cycle. The evolution of structure undergoes from the cubic structure to the hexagonal one with a preferred orientation along the (002) plane after annealing at 673 K. An amount of C, O and Cl impuriries can be reduced by increasing the drying temperature or by annealing in N2 atmosphere. It was found that the band gap of the CdS films shifts to higher wavelength after annealing or increasing film thickness. The electrical resistivity decreases with increasing annealing temperature and film thickness.
参考文献
[1] | Salata OV;Dobsib PJ;Hull PJ;Hutchison JL .Preparation of nanoparticulate CdS films suitable for opto-electronic device applications[J].Thin Solid Films,1996,288(1-2):235. |
[2] | C. Guillen;M.A. Martinez;J. Herrero .CuInSe_(2) thin films obtained by a novel electrodeposition and sputtering combined method[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2000(4):594-601. |
[3] | Toyama T .Interfacial mixed-crystal layer in CdS/CdTe heterostructure elucidated by electroreflectance spectroscopy[J].Fuel and Energy Abstracts,1998,39(01):39. |
[4] | Anil Kumar;Arvind Kumar Jain .Photophysics and photochemistry of colloidal CdS-TiO_2 coupled semiconductors-photocatalytic oxidation of indole[J].Journal of molecular catalysis, A. Chemical,2001(1/2):265-273. |
[5] | Oliva AI.;Castro-Rodriguez R.;Solis-Canto O.;Sosa V.;Quintana P.;Pena JL. .Comparison of properties of US thin films grown by two techniques[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):56-64. |
[6] | Ni JZ.;Belbruno JJ. .MECHANISTIC DETAILS FOR DIMETHYLCADMIUM DECOMPOSITION AND CDS PRODUCTION BY MOCVD[J].Journal of Crystal Growth,1997(3/4):321-328. |
[7] | Enriguez JP.;Mathew X. .Influence of the thickness on structural, optical and electrical properties of chemical bath deposited CdS thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(3):313-322. |
[8] | Pence S;Bates CW;Varner L .Morphological features in films of CdS prepared by chemical spray Pyrolysis[J].Materials Letters,1995,23(4-6):195. |
[9] | B. R. Sankapal;R. S. Mane;C. D. Lokhande .Deposition of CdS thin films by the successive ionic layer adsorption and reaction (SILAR) method[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2000(2):177-184. |
[10] | Cordoncillo E.;Monros G.;Tena MA.;Orera V.;Carda J.;Escribano P. .THE PREPARATION OF CDS PARTICLES IN SILICA GLASSES BY A SOL-GEL METHOD[J].International Journal of Quantum Chemistry,1995(1):1-5. |
[11] | Zhang J.;Sun LD.;Liao CS.;Yan CH. .Size control and photoluminescence enhancement of CdS nanoparticles prepared via reverse micelle method[J].Solid State Communications,2002(1/2):45-48. |
[12] | Lee J;Tsakalakos T .Influences of growth conditions on physical, optical properties, and quantum size effects of CdS nanocluster thin films[J].THIN SOLID FILMS,1997,8(04):381. |
[13] | Nel JM.;Gaigher HL.;Auret FD. .Microstructures of electrodeposited CdS layers[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(2):186-195. |
[14] | Bar M.;Fischer CH.;Lux-Steiner MC.;Muffler HJ. .ILGAR technology IV: ILGAR thin film technology extended to metal oxides[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):113-120. |
[15] | Moeller J;Fischer ChH;Muffer HJ;KoEnenkamp R, Kaiser I, Kelch C .and Lux-Steiner MC,ILGAR-a novel thin-film technology for sulfides[J].Thin Solid Films,2000,361(01):113. |
[16] | S. A. Al Kuhaimi .Influence of preparation technique on the structural, optical and electrical properties of polycrystalline CdS films[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,1998(3):349-355. |
[17] | H. Oumous;H. Hadiri .Optical and electrical properties of annealed CdS thin films obtained from a chemical solution[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2001(1):87-90. |
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