{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"以<span style=\"color:red\">纤维素</span>和<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span>异氰酸<span style=\"color:red\">酯</span>为原料合成了<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>), 并采用两种不同的方法将其涂敷于小粒径(平均粒径5 μm，平均孔径13 nm，比表面积110 m2/g)的<span style=\"color:red\">氨基</span>丙烷化硅胶(APS)上, 制得了在<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)类衍生物涂敷的硅基手性固定相中具有较佳手性识别能力的固定相。通过元素分析、扫描电子显微镜对两种手性固定相进行了表征，用高效液相色谱法对两种固定相的手性拆分能力进行了评价和比较。","authors":[{"authorName":"侯经国","id":"f064ec3a-54bc-4ac8-8219-23f9ed7c975a","originalAuthorName":"侯经国"},{"authorName":"邓启良","id":"0f8de584-310a-49f3-a3c2-4d3d84f6ef1a","originalAuthorName":"邓启良"},{"authorName":"孟晓蓉","id":"ba17381a-fdd3-4e53-98e2-4a4c4017cec8","originalAuthorName":"孟晓蓉"},{"authorName":"刘慧玲","id":"0bfbb4d1-88b5-45ab-8589-78475ffaae15","originalAuthorName":"刘慧玲"},{"authorName":"杨武","id":"7abc37ba-5d1d-4653-a1ff-5106e3df80c4","originalAuthorName":"杨武"},{"authorName":"莫尊理","id":"9f19167b-1470-4d4b-8342-8ff80a0f0f16","originalAuthorName":"莫尊理"},{"authorName":"高锦章","id":"b43be2d6-a588-45f2-a209-fccb74004da5","originalAuthorName":"高锦章"}],"doi":"10.3321/j.issn:1000-8713.2001.02.016","fpage":"154","id":"089d336f-8040-412d-9c5a-ed9c11ae0b5b","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"11b8bcf3-3565-4ec7-ae2b-9a5a353ff160","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"4454cfcb-596e-447c-bf99-c8887ac64f9b","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)"},{"id":"cb6c4ac8-b0a9-4224-b98f-a36e1b39ba56","keyword":"手性固定相","originalKeyword":"手性固定相"}],"language":"zh","publisherId":"sp200102016","title":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)涂敷手性固定相的制备、表征及评价","volume":"19","year":"2001"},{"abstractinfo":"合成了<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span> <span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)(CDMPC)衍生物,并将其涂敷于自制的球形硅胶上,制备出用于高效液相色谱手性拆分的固定相.在正相条件下,用该固定相对5种酸性外消旋联苯类药物进行了直接拆分,并考察了流动相组成和样品结构对保留和拆分的影响,讨论了固定相对样品的作用模式.结果表明,在正己烷/异丙醇流动相体系中加入少量<span style=\"color:red\">三</span>氟乙酸,可对外消旋羧酸类化合物进行有效的手性拆分.","authors":[{"authorName":"刘月启","id":"e6e27485-4277-474b-b89b-921ec3726ea3","originalAuthorName":"刘月启"},{"authorName":"蔡青松","id":"57b430ed-f947-4f4f-9b12-f48c6ff2eea6","originalAuthorName":"蔡青松"},{"authorName":"于兆文","id":"771b06cb-403a-466f-86a3-72776f022515","originalAuthorName":"于兆文"},{"authorName":"常俊标","id":"ba6e1c0f-6921-4017-b764-2414ac820407","originalAuthorName":"常俊标"},{"authorName":"蒋生祥","id":"b698b997-cea6-4d2d-a4fc-85050afd7c42","originalAuthorName":"蒋生祥"},{"authorName":"陈立仁","id":"94383a4b-15d2-4783-97e0-597dea8ebb69","originalAuthorName":"陈立仁"}],"doi":"10.3321/j.issn:1000-8713.2000.04.002","fpage":"287","id":"ed452221-1503-4039-9f5a-65adfee4f029","issue":"4","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"14fda6f9-1ada-40a2-ad9b-040534aa2715","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"acdc7118-1bbd-442c-98ea-6e32f0a1d776","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)"},{"id":"687eea7d-3c29-4b8c-b7ae-46613923a1dd","keyword":"外消旋联苯类药物","originalKeyword":"外消旋联苯类药物"},{"id":"89afeb60-6196-48fb-ac19-7f405f2b6e77","keyword":"手性拆分","originalKeyword":"手性拆分"}],"language":"zh","publisherId":"sp200004002","title":"酸性外消旋联苯类药物在<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)固定相上的直接拆分","volume":"18","year":"2000"},{"abstractinfo":"在<span style=\"color:red\">纤维</span>索-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)(CDMPC)手性固定相上,分别采用正相、反相及极性有机相色谱模式对氟环唑外消旋体进行了拆分,并考察了流动相组成在手性识别中对手性分离的影响.氟环唑在ChiralcelOD-H手性色谱柱(填充CDMPC手性固定相)上采用反相色谱模式,以甲醇-水(体积比为80:20)为流动相,获得了最佳的拆分,其两对对映异构体的分离度Rs分别为1.64和6.50.","authors":[{"authorName":"韩小茜","id":"e323022f-bb94-4b73-8abe-97f753823cf6","originalAuthorName":"韩小茜"},{"authorName":"魏燕","id":"640d76db-d8ae-4bb2-9d28-559bbfdff86f","originalAuthorName":"魏燕"},{"authorName":"刘艳华","id":"f1d25999-bf51-4861-87cf-debbc49ec93b","originalAuthorName":"刘艳华"},{"authorName":"常静","id":"a23a95b4-4249-4bf7-85a6-9d37da69843b","originalAuthorName":"常静"},{"authorName":"仇伟","id":"f1762ea1-282a-4d34-b765-f112a0f578d7","originalAuthorName":"仇伟"},{"authorName":"陈峰","id":"bc2fb5d2-148e-4104-8f27-1f311007f2a6","originalAuthorName":"陈峰"}],"doi":"10.3321/j.issn:1000-8713.2008.05.021","fpage":"631","id":"75f01af0-3239-4f21-bdfe-883f2a7de9cf","issue":"5","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"b7f60b3a-8895-46ad-8d9d-3e67bc5909a5","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)手性固定相"},{"id":"87e3a2a3-0a6c-49c4-9217-e6e075b2088f","keyword":"正相色谱","originalKeyword":"正相色谱"},{"id":"ea943daf-a948-4acc-be79-4098c89c8ec0","keyword":"反相色谱","originalKeyword":"反相色谱"},{"id":"34998db2-6993-41d8-8ebc-471b3bd1632e","keyword":"极性有机相色谱","originalKeyword":"极性有机相色谱"},{"id":"05cffaf5-6fa1-4164-99a5-375b9bcc38e8","keyword":"对映异构体分离","originalKeyword":"对映异构体分离"},{"id":"410c7376-c1ce-4bc6-82e1-c207ed751b59","keyword":"氟环唑外消旋体","originalKeyword":"氟环唑外消旋体"}],"language":"zh","publisherId":"sp200805021","title":"氟环唑外消旋体在<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相上的高效液相色谱法拆分","volume":"26","year":"2008"},{"abstractinfo":"以<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>（<span style=\"color:red\">3，5-</span><span style=\"color:red\">二甲苯基</span><span style=\"color:red\">氨基甲酸酯</span>）为手性固定相（Chiralcel OD-H）在高效液相色谱上拆分了氨鲁米特对映体。通过测定氨鲁米特在正己烷/乙醇和正己烷/异丙醇中的溶解度，优选了对样品溶解度大的流动相体系，并考察了流动相添加剂乙醇胺对拆分效果的影响。在此基础上进一步研究了流动相中乙醇含量、柱温和进样量对分离因子、分离度、不对称因子和理论板数的影响，从而确定了最佳的拆分条件：固定相为 Chiralcel OD-H，流动相为正己烷/乙醇/乙醇胺（体积比为30：70：0.1），柱温25℃。本文所得结果可为工业放大提供基础数据。","authors":[{"authorName":"林小建","id":"9493c1bc-3ede-45e5-b525-1e97d07dbc5d","originalAuthorName":"林小建"},{"authorName":"龚如金","id":"24f17208-0c3a-4e6f-ae0b-337aac1b6f8e","originalAuthorName":"龚如金"},{"authorName":"李平","id":"fda1fadb-d5b0-44fa-a0a5-f275dd7102eb","originalAuthorName":"李平"},{"authorName":"于建国","id":"8b602fe4-a136-4104-9d93-e767ccb979b9","originalAuthorName":"于建国"}],"doi":"10.3724/SP.J.1123.2014.04022","fpage":"880","id":"c396c396-2e59-44c7-820c-384149b5423e","issue":"8","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"d4c76fd1-8415-472e-ba23-02d42698b41d","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"5f551590-f5f3-4a67-be7d-7ac647abffec","keyword":"手性固定相","originalKeyword":"手性固定相"},{"id":"0cde9139-5d32-4ce1-a214-8e2afcdc3f1b","keyword":"手性拆分","originalKeyword":"手性拆分"},{"id":"cd8202be-17ac-405b-ad93-e715550158de","keyword":"氨鲁米特","originalKeyword":"氨鲁米特"}],"language":"zh","publisherId":"sp201408015","title":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>（<span style=\"color:red\">3，5-</span><span style=\"color:red\">二甲苯基</span><span style=\"color:red\">氨基甲酸酯</span>）手性固定相拆分氨鲁米特对映体","volume":"","year":"2014"},{"abstractinfo":"合成了直链淀粉-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相.用该固定相对6种单硫代甘油醚和4 种双硫代甘油醚进行了手性拆分.单硫代甘油醚对映异构体得到了较好的分离, 而双硫代甘油醚完全不能拆分.提出了样品与固定相的作用模式.","authors":[{"authorName":"于兆文","id":"bb596b37-3a75-4517-a48e-c4f7b0f31ffe","originalAuthorName":"于兆文"},{"authorName":"刘霞","id":"d6866a96-9b11-4d7d-8dbd-d1dde7be9ae4","originalAuthorName":"刘霞"},{"authorName":"蒋生祥","id":"82ca506e-1d5f-481b-8097-1afc80b2a460","originalAuthorName":"蒋生祥"},{"authorName":"陈立仁","id":"53f3d204-c15c-4944-bc5b-cef8fc6575f6","originalAuthorName":"陈立仁"}],"doi":"10.3321/j.issn:1000-8713.2000.01.011","fpage":"39","id":"6400b1a0-8d67-4b85-bbc6-255070be8482","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"2659cc22-c033-4161-9060-3bf441492573","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"cb3664bf-fa01-45cf-a1fd-c81712900fa8","keyword":"手性固定相","originalKeyword":"手性固定相"},{"id":"bf2451ea-6b49-4bb4-8849-74e37de9a025","keyword":"对映体分离","originalKeyword":"对映体分离"}],"language":"zh","publisherId":"sp200001011","title":"单硫代和双硫代甘油醚在直链淀粉-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)固定相上的手性拆分","volume":"18","year":"2000"},{"abstractinfo":"合成了<span style=\"color:red\">纤维素</span>-2,<span style=\"color:red\">3</span>,6-<span style=\"color:red\">三</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>、<span style=\"color:red\">纤维素</span>-2,3-<span style=\"color:red\">二</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>、<span style=\"color:red\">纤维素</span>-2,<span style=\"color:red\">3</span>,6-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)和<span style=\"color:red\">纤维素</span>-2,3-<span style=\"color:red\">二</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)4种<span style=\"color:red\">纤维素</span>衍生物手性固定相,用正己烷-异丙醇(体积比为9∶1)混合液作流动相,对9种手性化合物进行了高效液相色谱拆分.实验结果表明:对所测的9个样品,<span style=\"color:red\">纤维素</span>-2,3-<span style=\"color:red\">二</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>的手性选择性大大好于<span style=\"color:red\">纤维素</span>-2,<span style=\"color:red\">3</span>,6-<span style=\"color:red\">三</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>;而<span style=\"color:red\">纤维素</span>-2,3-<span style=\"color:red\">二</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)与<span style=\"color:red\">纤维素</span>-2,<span style=\"color:red\">3</span>,6-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)的分离因子针对不同的对映体各有优点,但前者通常具有更小的保留因子,可以缩短一定的分析时间.","authors":[{"authorName":"常银霞","id":"999bd783-9e25-4bf1-bc9a-0ee5a2b06b43","originalAuthorName":"常银霞"},{"authorName":"周玲玲","id":"a5857633-e7aa-44bd-ac28-398f52b2d579","originalAuthorName":"周玲玲"},{"authorName":"袁黎明","id":"6fc1d0e2-da6d-4103-9e96-98e8e514ca2a","originalAuthorName":"袁黎明"}],"doi":"10.3321/j.issn:1000-8713.2007.02.015","fpage":"203","id":"af0d8e2a-a03f-4440-9574-56329b531515","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"136d6fe2-cf04-4cf9-b96f-3911361befff","keyword":"<span style=\"color:red\">纤维素</span>衍生物","originalKeyword":"纤维素衍生物"},{"id":"6b9546ba-58ec-4986-9ab6-d8f509fdd7ac","keyword":"手性固定相","originalKeyword":"手性固定相"},{"id":"0096acdf-0581-4351-a0db-bdd74b42a167","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"}],"language":"zh","publisherId":"sp200702015","title":"<span style=\"color:red\">纤维素</span>2,3-位和2,<span style=\"color:red\">3</span>,6-位<span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>手性固定相的选择性研究","volume":"25","year":"2007"},{"abstractinfo":"在自制的涂敷型<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)(CDMPC)手性固定相上拆分了一些结构相似的有机硒手性化合物,详细考察了<span style=\"color:red\">三</span>元流动相对手性拆分的影响,并探讨了溶质分子与手性固定相相互作用的模式.实验结果表明:在<span style=\"color:red\">二</span>元流动相中加入极少量的质子性改性剂(醇)或非质子性改性剂(乙腈),可使溶质的保留和手性拆分发生较大的变化.","authors":[{"authorName":"韩小茜","id":"947734d2-9886-4ea2-b306-5b219941ce8f","originalAuthorName":"韩小茜"},{"authorName":"齐邦峰","id":"327b45e1-7f98-442d-b074-c4c3c1611b30","originalAuthorName":"齐邦峰"},{"authorName":"敦惠娟","id":"0f77ff86-019a-4d9b-9906-f69493e5e235","originalAuthorName":"敦惠娟"},{"authorName":"祝馨怡","id":"93750624-db34-44f7-b4a5-b7cc6cba61ab","originalAuthorName":"祝馨怡"},{"authorName":"纳鹏君","id":"3186ad6d-6d15-410c-a5f8-37602eee3e3e","originalAuthorName":"纳鹏君"},{"authorName":"蒋生祥","id":"69920cfd-d77e-42d6-b1d5-012259e794eb","originalAuthorName":"蒋生祥"},{"authorName":"陈立仁","id":"85a12f0b-2163-4a8f-9657-c1b54f07ada3","originalAuthorName":"陈立仁"}],"doi":"10.3321/j.issn:1000-8713.2002.03.013","fpage":"241","id":"a45a6fb4-3636-42c0-953f-fc301d410904","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"2bae5430-3000-4b18-94d5-dcc140cf33f2","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"168e5c27-fa12-419a-8b8b-1969aba04e5e","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)"},{"id":"66ffec92-b470-4385-8d4e-c6a6baadcbe3","keyword":"<span style=\"color:red\">三</span>元流动相","originalKeyword":"三元流动相"},{"id":"ab7f09ed-c2b8-4b9e-9225-7b02b51c5717","keyword":"手性拆分","originalKeyword":"手性拆分"},{"id":"512bc5db-6273-46db-a015-af1a6fb2122f","keyword":"有机硒","originalKeyword":"有机硒"}],"language":"zh","publisherId":"sp200203013","title":"流动相组成对有机硒手性化合物拆分的影响","volume":"20","year":"2002"},{"abstractinfo":"为了扩展多糖类手性固定相的种类,制备了基于淀粉及<span style=\"color:red\">纤维素</span><span style=\"color:red\">三</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">三</span>氟<span style=\"color:red\">甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)的涂敷型手性固定相,以正己烷-异丙醇混合液为流动相,对8种手性化合物进行了高效液相色谱拆分.研究表明:虽然与应用最广泛的分别以淀粉及<span style=\"color:red\">纤维素</span><span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)为手性选择因子的商品化手性柱Chiralpak AD和Chiralcel OD相比,所制备的手性固定相的手性分离能力较低,但<span style=\"color:red\">纤维素</span><span style=\"color:red\">三</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">三</span>氟<span style=\"color:red\">甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相显示出特异的手性识别能力,一些手性化合物在此固定相上得到了比在Chiracel OD上更好的分离;所制备的手性固定相的手性识别能力随流动相中异丙醇含量的降低而变好,当流动相中正己烷与异丙醇的体积比为95∶5时所制备的手性固定相显示出相对较高的手性识别能力;总体来说,淀粉<span style=\"color:red\">三</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">三</span>氟<span style=\"color:red\">甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相的手性识别能力稍强于<span style=\"color:red\">纤维素</span><span style=\"color:red\">三</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">三</span>氟<span style=\"color:red\">甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相,同时两种手性固定相的手性识别能力具有一定的互补性.","authors":[{"authorName":"金召磊","id":"0766d62d-c168-4f3d-b84c-51b9adaee9c8","originalAuthorName":"金召磊"},{"authorName":"胡芳芳","id":"28a36f54-07cd-4e9b-9eea-68be85049ef4","originalAuthorName":"胡芳芳"},{"authorName":"汪一波","id":"7465d63b-62d7-45c1-9145-676f24eba6f6","originalAuthorName":"汪一波"},{"authorName":"刘贵花","id":"cf972a08-e8eb-4615-9728-093b15c7c62c","originalAuthorName":"刘贵花"},{"authorName":"王芳","id":"bfb38f76-8f29-419e-9ce5-64fa15b4eb52","originalAuthorName":"王芳"},{"authorName":"潘富友","id":"a3089683-dc20-4e55-8d1d-957c973a8368","originalAuthorName":"潘富友"},{"authorName":"唐守万","id":"dcb6a715-1111-4ab6-8e07-1f0a42a145b2","originalAuthorName":"唐守万"}],"doi":"10.3724/SP.J.1123.2011.01087","fpage":"1087","id":"9787ce91-e9ce-4248-8c19-b6b764089da5","issue":"11","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"15882fd0-e8b9-481b-9540-cc97edb7a835","keyword":"手性固定相","originalKeyword":"手性固定相"},{"id":"6ee3a8dd-9c98-4baf-9b93-84e2ec77759a","keyword":"涂敷","originalKeyword":"涂敷"},{"id":"2a70645c-1fac-44ab-8c1b-d8b6f36db278","keyword":"手性识别","originalKeyword":"手性识别"},{"id":"56b2421d-435e-4e2d-b0c2-94701bd374dd","keyword":"多糖衍生物","originalKeyword":"多糖衍生物"}],"language":"zh","publisherId":"sp201111008","title":"淀粉及<span style=\"color:red\">纤维素</span><span style=\"color:red\">三</span>(<span style=\"color:red\">3</span>-<span style=\"color:red\">三</span>氟<span style=\"color:red\">甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相的制备及其性能评价","volume":"29","year":"2011"},{"abstractinfo":"在自制的涂敷型<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)手性固定相上直接拆分了新近合成的外消旋四面体金属簇合物,得到了满意的色谱分离结果,为进一步实现色谱制备具有旋光活性的金属簇合物提供了基础条件.同时还考察了温度及流动相中的极性改性剂醇的种类及结构对手性拆分的影响.结果发现,醇的立体结构、极性对簇合物的手性拆分均有影响.在相同的色谱条件下,用正构醇作极性改性剂对该金属簇合物的拆分效果比用异丙醇好.","authors":[{"authorName":"韩小茜","id":"a7240d09-0c60-4996-910e-0fb720fb2b10","originalAuthorName":"韩小茜"},{"authorName":"边治国","id":"f0eb755a-84ad-403a-8fba-3ab5dac479d3","originalAuthorName":"边治国"},{"authorName":"张玉华","id":"cfbe52b6-a006-4244-8c94-840f61acb571","originalAuthorName":"张玉华"},{"authorName":"李文智","id":"a3999a53-c2da-4cfc-9c44-db10058c4179","originalAuthorName":"李文智"},{"authorName":"陈立仁","id":"750e74e9-ffb9-4683-a700-270ffb040c4c","originalAuthorName":"陈立仁"},{"authorName":"李永民","id":"6d0cbc01-930f-45c3-9d3c-285e67b7743f","originalAuthorName":"李永民"},{"authorName":"柳春辉","id":"9b614019-7091-4a91-bfd3-eb37f76b55d7","originalAuthorName":"柳春辉"}],"doi":"10.3321/j.issn:1000-8713.2003.03.020","fpage":"263","id":"4204c955-93fe-4717-8a10-fbc1a12a0157","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"59d048c9-02ac-4901-b153-4d59f8a75ff6","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"79f4c7b2-52e8-410e-9736-9a8482e1a732","keyword":"手性固定相","originalKeyword":"手性固定相"},{"id":"d795b79b-1d22-4684-8cfe-4025709774ba","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)"},{"id":"db47da46-d1bf-4aa8-a94a-2858f73d2524","keyword":"手性四面体金属簇合物","originalKeyword":"手性四面体金属簇合物"},{"id":"ec476a60-0448-40aa-8d4d-60630e8bf554","keyword":"手性拆分","originalKeyword":"手性拆分"},{"id":"a8eef12f-5f72-4478-9e6d-16a2170283ab","keyword":"流动相极性改性剂","originalKeyword":"流动相极性改性剂"}],"language":"zh","publisherId":"sp200303020","title":"液相色谱手性固定相法直接拆分外消旋金属簇合物","volume":"21","year":"2003"},{"abstractinfo":"","authors":[{"authorName":"王鹏","id":"939e63f9-c105-4e3f-8188-df04cde7d38d","originalAuthorName":"王鹏"},{"authorName":"江树人","id":"6559addd-3f3d-4ac9-916f-1facdad9e2eb","originalAuthorName":"江树人"},{"authorName":"邱静","id":"fdf7063d-7796-4cce-813c-1367a35f339a","originalAuthorName":"邱静"},{"authorName":"杨晓玲","id":"0f50e863-da10-4b31-838d-f7347753f36a","originalAuthorName":"杨晓玲"},{"authorName":"周志强","id":"d92c5ddb-ebb5-481e-b215-6cd3ffca16b4","originalAuthorName":"周志强"}],"doi":"10.3321/j.issn:1000-8713.2004.02.023","fpage":"181","id":"5dda45b1-7140-4794-996e-051515d75d60","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"d82ddb81-f505-428b-949f-0b948ce39777","keyword":"<span style=\"color:red\">纤维素</span>-<span style=\"color:red\">三</span>(<span style=\"color:red\">3,5-</span><span style=\"color:red\">二甲基</span><span style=\"color:red\">苯基</span><span style=\"color:red\">氨基甲酸酯</span>)","originalKeyword":"纤维素-三(3,5-二甲基苯基氨基甲酸酯)"},{"id":"92d05f2b-9e4e-45cd-aa94-24d4117e3ce8","keyword":"手性拆分","originalKeyword":"手性拆分"},{"id":"5c0478e8-e5f7-4597-b37c-c6f46a7ce2b0","keyword":"戊唑醇","originalKeyword":"戊唑醇"}],"language":"zh","publisherId":"sp200402023","title":"<span style=\"color:red\">纤维素</span>衍生物手性固定相对戊唑醇对映体的拆分","volume":"22","year":"2004"}],"totalpage":10849,"totalrecord":108486}