欢迎登录材料期刊网

材料期刊网

中国科学院金属研究所 科学出版社
高级检索
  1. 首页
  2. 期刊
  3. 材料导报
  4. Mg-Ni系储氢合金元素取代改性的研究进展

材料导报, 2004, 18(12): 29-33.

Mg-Ni系储氢合金元素取代改性的研究进展

陈玉安 1, , 苗鹤 2, , 丁培道 3,

1.重庆大学材料科学与工程学院,重庆,400044

2.重庆大学材料科学与工程学院,重庆,400044

3.重庆大学材料科学与工程学院,重庆,400044

基金项目:   重庆市应用基础研究基金(7941)   重庆大学校科研和教改项目(713411003)  

关键词： Mg-Ni系储氢合金 , Mg-Ni系储氢电极 , 充放氢性能 , 电化学性能

Recent Development of Element Partial Substitution to Improve the Characteristics of Mg-Ni-based Hydrogen Storage Alloys

综述了对Mg-Ni系储氢合金进行元素取代改性的最新研究进展,分析了Mg-Ni系储氢合金A、B两侧元素的构成,并分别按Mg-Ni系中A、B两侧元素的性质,讨论了这些元素部分取代A2B型Mg2Ni和AB型MgNi合金中的Mg和Ni对Mg-Ni系合金储氢性能的影响.对近年来研究的多元Mg基储氢合金的充放氢性能和电化学性能进行了系统的阐述,总结了取代元素在降低Mg-Ni系储氢合金的氢化物生成热和放氢温度、提高合金电极循环寿命时的作用.

参考文献

[1] 王辉,曾美琴,罗堪昌,车晓舟,朱敏.Mg基贮氢合金研究进展[J].金属功能材料,2002(02):4-7.
[2] 房文斌,张文丛,于振兴,王尔德.镁基储氢材料的研究进展[J].中国有色金属学报,2002(05):853-862.
[3] Kohno T.;Kanda M. .EFFECT OF PARTIAL SUBSTITUTION ON HYDROGEN STORAGE PROPERTIES OF MG2NI ALLOY[J].Journal of the Electrochemical Society,1997(7):2384-2388.
[4] 袁华堂,李秋荻,王一菁,宋赫男,冯艳.新型镁基储氢合金的合成及电化学性能的研究[J].高等学校化学学报,2002(04):517-520.
[5] 吕光烈,陈林深,胡秀荣,王连邦,袁华堂.Mg3MNi2（M=Ti,Al）的晶体结构[J].金属学报,2001(05):459-462.
[6] LüGL;Chen L S;Wang L B et al.StudyonthephasecompositionofMg2-xMxNiM=Al,Tialloys[J].Journal of Alloys and Compounds,2001,321:L1.
[7] 薛建设,李国勋,胡尧沁.Mg2Ni系储氢合金电化学性能的研究[J].稀有金属,2000(02):128-130.
[8] YuanHT;Li Q D;Song H N et al.ElectrochemicalcharacteristicsofMg2Ni-typealloyspreparedbymechanicalalloying[J].Journal of Alloys and Compounds,2003,353:322.
[9] Woo JH;Lee JH;Lee KS;Jung CB .Electrochemical characteristics of nanocrystalline ZrCr sub 2 and Mg sub 2 Ni type metal hydrides prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):556-563.
[10] GooNH;Lee K S .TheelectrochemicalhydridingpropertiesofMg-Ni-Zramorphousalloy[J].International Journal of Hydrogen Energy,2002,27:433.
[11] KohnoT;Yamamoto M;Kanda M .ElectrochemicalpropertiesofmechanicallygroundMg2Nialloy[J].Journal of Alloys and Compounds,1999,293-295:643.
[12] LiangG;Huot J;Boily S et al.HydrogenstoragepropertiesofnanocrystallineMg19Ti01Nimadebymechanicalalloying[J].Journal of Alloys and Compounds,1999,282:286.
[13] WangL;Yuan H T;Wang Y J et al.ThehydrogenationpropertiesofMg18Ag02Nialloy[J].Journal of Alloys and Compounds,2002,336:297.
[14] YamauraSI;Kim H Y;Kimura H et al.Thermalstabilitiesanddischargecapacitiesofmelt-spunMg-Ni-basedamorphousalloys[J].Journal of Alloys and Compounds,2002,339:230.
[15] RangelovaV;Spassov T .PrimarycrystallizationkineticsinrapidlyquenchedMg-basedMg-Ni-Yalloys[J].Journal of Alloys and Compounds,2002,345:148.
[16] SpassovT;Rangelova V;Neykov N .NanocrystallizationandhydrogenstorageinrapidlysolidifiedMg-Ni-REalloys[J].Journal of Alloys and Compounds,2002,334:219.
[17] Liu YN.;Zhang XJ. .Effect of lanthanum additions on electrode properties of Mg2Ni[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):231-234.
[18] Liquan Li;Itoko Saita;Katsushi Saito .Hydriding combustion synthesis of hydrogen storage alloys of Mg-Ni-Cu system[J].Intermetallics,2002(10):927-932.
[19] DehoucheZ;Djaozandry R;Goyette J et al.EvaluationtechniquesofcyclingeffectonthermodynamicandcrystalstructurepropertiesofMg2Nialloy[J].Journal of Alloys and Compounds,1999,288:269.
[20] 李金平 .机械合金化MgNiCu合金贮氢性能的研究[D].哈尔滨:哈尔滨工业大学,1996.
[21] 张允仕;陈声昌;袁华堂.贮氢化合物Mg2Ni075Pd025的合成及吸放氢性能的研究[J].南开大学学报(自然科学版),1991(01):93.
[22] ZaluskiL;Zaluska A;Tessier P et al.CatalyticeffectofPdonhydrogenabsorptioninmechanicallyalloyedMg2Ni,LaNi5andFeTi[J].Journal of Alloys and Compounds,1995,217:295.
[23] YamauraSI;Kim H Y;Kimura H et al.ElectrodepropertiesofrapidlysolidifiedMg67Ni23Pd10amorphousalloy[J].Journal of Alloys and Compounds,2002,347:239.
[24] 王秀丽,涂江平,张孝彬,高嵘岗,陈长聘.掺Cr纳米晶Mg2 Ni合金的气态储氢性能[J].中国有色金属学报,2002(05):907-911.
[25] Tsushio Y.;Akiba E.;Enoki H. .Hydrogenation properties of MgNi(0.86)M1(0.03) (M1 = Cr, Fe, Co, Mn) alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(2):301-305.
[26] Zhang YS.;Yuan HT.;Yang ED.;Zhou ZX.;Song DY.;Yang HB. .Dehydriding properties of ternary Mg2Ni1-xZrx hydrides synthesized by ball milling and annealing[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):278-283.
[27] YangH;Yuan H T;Ji J T et al.CharacteristicsofMg2Ni075M025M=Ti,Cr,Mn,Fe,Co,Ni,CuandZnalloysaftersurfacetreatment[J].Journal of Alloys and Compounds,2002,330-332:640.
[28] TerashitaN;Takahashi M;Kobayashi K et al.Synthesisandhydriding/dehydridingpropertiesofamorphousMg2Ni09M01alloysmechanicallyalloyedfromMg2Ni09M01M=none,Ni,Ca,La,Y,Al,Si,CuandMnandNipowder[J].Journal of Alloys and Compounds,1999,293-295:541.
[29] YuanHT;Cao R;Wang L B et al.CharacteristicofanewMg-Nihydrogenstoragesystem:Mg2-xNi1-yTixMny0x1,0y1alloys[J].Journal of Alloys and Compounds,2001,322:246.
[30] CuiN;Luo J L .ElectrochemicalstudyofhydrogendiffusionbehaviorinMg2Ni-typehydrogenstoragealloyelectrodes[J].International Journal of Hydrogen Energy,1999,24:37.
[31] CuiN;Luan B;Liu H K et al.DischargebehaviourofMg2Ni-typehydrogen-storagealloyelectrodesin6MKOHsolutionbyelectrochemicalimpedancespectroscopy[J].Journal of Power Sources,1996,63:209.
[32] LeiYQ;Wu Y M;Yang Q M et al.ElectrochemicalbehaviorofsomemechanicallyalloyedMg-Nibasedamorphoushydrogenstoragealloy[J].Zeitschrift für Physikalische Chemie,1994,183:379.
[33] SunD;Lei Y;Liu W et al.TherelationbetweenthedischargecapacityandcyclingnumberofmechanicallyalloyedMgxNi100-xamorphouselectrodealloys[J].Journal of Alloys and Compounds,1995,231:621.
[34] 吴煜明,雷永泉,吴京.机械合金化Mg-Ni基非晶态贮氢合金的电化学特性[J].稀有金属材料与工程,1997(03):26-29.
[35] OrimoS;Züttel A;Ikeda K et al.HydridingpropertiesoftheMgNi-basedsystems[J].Journal of Alloys and Compounds,1999,437:293-295.
[36] IwakuraC;Shin-Ya R;Miyanohara K et al.EffectsofTiVsubstitutiononelectrochemicalandstructuralcharacteristicsofMgNialloypreparedbymechanicalalloying[J].Electrochimica Acta,2001,46:2781.
[37] RuggeriS;Roue L;Huot J et al.PropertiesofmechanicallyalloyedMg-Ni-TiternaryhydrogenstoragealloysforNiMHbatteries[J].Journal of Power Sources,2002,112:547.
[38] Han S.C.;Lee P.S. .Effects of Ti on the cycle life of amorphous MgNi-based alloy prepared by ball milling[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):219-226.
[39] Ye H.;Chen LS.;Zhang H.;Lei YQ. .Electrochemical characteristics of amorphous Mg0.9M0.1Ni (M=Ni, Ti, Zr, Co and Si) ternary alloys prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(2):194-199.
[40] ZHANGY;Liao B;Chen L X et al.TheeffectofNicontentontheelectrochemicalandsurfacecharacteristicsofMg90-xTi10Nixx=50,55,60ternaryhydrogenstorageelectrodealloys[J].Journal of Alloys and Compounds,2001,327:195.
[41] ZHANGY;Zhang S K;Chen L X .ThestudyontheelectrochemicalperformanceofmechanicallyalloyedMg-Ti-Ni-basedternaryandquaternaryhydrogenstorageelectrodealloys[J].International Journal of Hydrogen Energy,2001,26:801.
[42] Nohara S.;Zhang SG.;Inoue H.;Iwakura C.;Hamasaki K. .Electrochemical characteristics of an amorphous Mg0.9V0.1Ni alloy prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):104-106.
[43] Ikeda K.;Zuttel A.;Schlapbach L.;Fujii H.;Orimo S. .Cobalt- and copper-substitution effects on thermal stabilities and hydriding properties of amorphous MgNi[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):279-283.
[44] ZHANGY;Chen L X;Lei Y Q et al.ThereductionofcyclingcapacitydegradationofMg-Ni-basedelectrodealloysbyFesubstitution[J].International Journal of Hydrogen Energy,2002,27:501.
[45] 叶辉,陈立新,雷永泉.含Ni量对机械合金化Mg-Ni系二元贮氢合金结构和电化学性能的影响[J].稀有金属材料与工程,2000(03):193-196.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
作者相关
文章评分
  • 您的评分：
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%

版权所有©2010中国科学院金属研究所中国科技出版传媒股份有限公司

本系统由北京仁和汇智信息技术有限公司设计开发

技术支持：info@rhhz.net