{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"用钛酸丁酯作前驱物,N-甲基吡咯烷酮(<span style=\"color:red\">NMP</span>)作溶剂,冰乙酸为稳定剂,通过溶胶-凝胶法制得了TiO2溶胶. 通过加水方式,加水量,溶剂量,pH值和温度等因素对TiO2溶胶-凝胶过程影响的实验. 得出了在<span style=\"color:red\">NMP</span>中制备稳定TiO2溶胶的最佳条件. 结果表明,室温下,当<span style=\"color:red\">NMP</span>与钛酸丁酯的体积比为2～3;V(水)/V(钛酸丁酯)为3～4;pH值为2～4时所得TiO2溶胶稳定,透明性好.","authors":[{"authorName":"杜宏伟","id":"8663cf8c-2d68-481c-b572-3e43b15f635b","originalAuthorName":"杜宏伟"},{"authorName":"孔瑛","id":"3cdc9dd7-3bd7-43f1-8615-99f033d67aa6","originalAuthorName":"孔瑛"}],"doi":"10.3969/j.issn.1000-0518.2002.09.015","fpage":"882","id":"4e075874-2c72-442f-b68b-b0a215ec8cc5","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"91600be7-8b48-432a-a84e-1f90701a23a1","keyword":"TiO2溶胶","originalKeyword":"TiO2溶胶"},{"id":"d465705b-b6bb-43c6-99a2-b3be12fc33d9","keyword":"<span style=\"color:red\">NMP</span>","originalKeyword":"NMP"},{"id":"f5c0387c-caa2-4a6f-8850-8e4565118b7f","keyword":"溶胶-凝胶过程","originalKeyword":"溶胶-凝胶过程"}],"language":"zh","publisherId":"yyhx200209015","title":"<span style=\"color:red\">NMP</span>中制备TiO2溶胶及其凝胶化","volume":"19","year":"2002"},{"abstractinfo":"用~1H-NMR和~(13)C-NMR核磁共振技术研究了聚芳硫醚砜(PASS)的结构,并通过~(13)C-~1H异核相关谱提供的信息确定了其~1H谱和~(13)C谱中各谱峰的归属,为聚合物的表征提供了依据.并通过~1H-NMR对比了PASS与N-甲基吡咯烷酮(<span style=\"color:red\">NMP</span>)溶液结晶过程前后的结构变化.","authors":[{"authorName":"王孝军","id":"d2c09c0b-13f2-4701-adc8-106e4dc365a6","originalAuthorName":"王孝军"},{"authorName":"贾向明","id":"8967e928-c815-42c8-8de9-d6a183281fa6","originalAuthorName":"贾向明"},{"authorName":"王波","id":"bf8a5692-07d0-4290-9b54-b5cf48c6d2ad","originalAuthorName":"王波"},{"authorName":"候康","id":"a70537cd-8f4c-4aae-868b-b88a12dff5c5","originalAuthorName":"候康"},{"authorName":"杨杰","id":"3d4f7226-5877-4bf9-bb9e-19346045f658","originalAuthorName":"杨杰"},{"authorName":"李光宪","id":"50914c93-acbe-4dd5-8b0a-946213ece3ec","originalAuthorName":"李光宪"}],"doi":"","fpage":"107","id":"c16ac270-8575-46d5-a698-9bf9a10afd66","issue":"11","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4247ce9b-0e6e-444f-b604-3ca2bfb41aa0","keyword":"核磁共振","originalKeyword":"核磁共振"},{"id":"640c24c9-65ce-4b97-89b0-d8eb5e09c6b3","keyword":"聚芳硫醚砜","originalKeyword":"聚芳硫醚砜"},{"id":"c319112c-82c3-4134-92b1-198ddf160fff","keyword":"结晶溶剂化物","originalKeyword":"结晶溶剂化物"}],"language":"zh","publisherId":"gfzclkxygc200911030","title":"NMR法表征PASS及PASS/<span style=\"color:red\">NMP</span>溶液结晶过程","volume":"25","year":"2009"},{"abstractinfo":"以含二氮杂萘酮结构的新型聚芳醚砜酮(PPESK)为底膜材料,以硅橡胶为涂层材料,制备了中空纤维气体分离复合膜.重点考察了N-甲基吡咯烷酮(<span style=\"color:red\">NMP</span>)/乙醇(EtOH)θ组成对气体分离膜性能的影响.结果表明,<span style=\"color:red\">NMP</span>/EtOHθ组成对膜性能有较明显的影响,采用略低于<span style=\"color:red\">NMP</span>/EtOHθ组成的铸膜液制备的膜分离性能较好.","authors":[{"authorName":"王志鹏","id":"55ee27ec-d6b5-4bfb-b681-ee2496bf84d9","originalAuthorName":"王志鹏"},{"authorName":"杨大令","id":"cae83cb0-b6da-4361-8d42-6ba2df1c91ff","originalAuthorName":"杨大令"},{"authorName":"张守海","id":"1e8ca542-df1d-430a-9345-42d8cbfbeebc","originalAuthorName":"张守海"},{"authorName":"富海涛","id":"6e79d03b-ad16-42a3-935d-c63ac92af1a1","originalAuthorName":"富海涛"},{"authorName":"蹇锡高","id":"88a74f18-44f1-458b-952b-da73b4352336","originalAuthorName":"蹇锡高"}],"doi":"10.3969/j.issn.1007-8924.2008.02.002","fpage":"9","id":"d9987c41-5d43-478a-8acc-e201cc551ec5","issue":"2","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"99950fa5-b556-4f4e-8a86-3bca6cafa536","keyword":"聚芳醚砜酮","originalKeyword":"聚芳醚砜酮"},{"id":"4d1d0452-bba3-4e29-b5d3-60b812359cfc","keyword":"θ组成","originalKeyword":"θ组成"},{"id":"4758c7aa-ab11-412a-bfaa-fdbdc58e7508","keyword":"气体分离","originalKeyword":"气体分离"},{"id":"d0c7abc4-d0ca-49e1-b2ec-a5b14f0106fa","keyword":"复合膜","originalKeyword":"复合膜"}],"language":"zh","publisherId":"mkxyjs200802002","title":"<span style=\"color:red\">NMP</span>/EtOH θ组成对PPESK气体分离膜性能的影响","volume":"28","year":"2008"},{"abstractinfo":"Poly (phthalazinone ether sulfone) (PPES) with 1:1 and 1:3 ratios of bisphenol A (BPA) unit to phthalazinone unit were selected as samples. Polymer precipitation curves for the ternary systems PPES (1:1)/<span style=\"color:red\">NMP</span>/ non-solvent and PPES (1:3)/<span style=\"color:red\">NMP</span>/non-solvent were determined by a titration method. Comparison between two sets of data is made. Non-solvents used were H2O, ethyl ether (EE), diethylene glycol (DEGC), ethyleneglycol methylether (EGME) and butanone (BO). <span style=\"color:red\">NMP</span>/non-solvent theta-compositions for PPES (1:1) and PPES (1:3) were also estimated. It was found that the volume ratio of non-solvent to <span style=\"color:red\">NMP</span> at the property mutation or worsening of PPES membrane is close to the theta-composition.","authors":[{"authorName":"Yi SU","id":"7d727257-c43b-4a56-b48e-e27b1a2afe34","originalAuthorName":"Yi SU"},{"authorName":" Xigao JIAN","id":"4f1d6ad3-9915-4547-bc02-bb24ccb48707","originalAuthorName":" Xigao JIAN"},{"authorName":"null","id":"ff6c80d4-33a1-4330-90b2-8701bb00fa82","originalAuthorName":"null"}],"categoryName":"|","doi":"","fpage":"430","id":"4218c464-d996-4ee5-945a-2545d7b36d10","issue":"3","journal":{"abbrevTitle":"CLKXJSY","coverImgSrc":"journal/img/cover/JMST.jpg","id":"11","issnPpub":"1005-0302 ","publisherId":"CLKXJSY","title":"材料科学技术（英文）"},"keywords":[{"id":"a999dfef-f3d0-4c6a-9bc9-9e986c4e7561","keyword":"Polymer precipitation curve","originalKeyword":"Polymer precipitation curve"},{"id":"c9aa8edc-8ea3-47bd-a9dc-ce7487325655","keyword":"precipitation","originalKeyword":"precipitation"},{"id":"c5456da3-f75e-464b-bbf6-d1a76399a701","keyword":"curve","originalKeyword":"curve"},{"id":"48af7ac2-858c-4c84-98d5-235ef456945c","keyword":"Poly","originalKeyword":"Poly"},{"id":"5b37794a-df23-405b-bdc2-1c2a8fae44f6","keyword":"(phthal","originalKeyword":"(phthal"}],"language":"en","publisherId":"1005-0302_2005_3_23","title":"Phase Separation and Theta-compositions of PPES/<span style=\"color:red\">NMP</span>/non-solvent Systems","volume":"21","year":"2005"},{"abstractinfo":"依据文献报道的PES/<span style=\"color:red\">NMP</span>(聚醚砜/N-甲基吡咯烷酮)制膜体系的浊点数据和特性粘数,从传统的宏观热力学和铸膜液中高分子的构象两方面讨论了非溶剂添加剂的种类和加入量(邻近比)对PES/<span style=\"color:red\">NMP</span>铸膜液性质的影响.非溶剂添加剂改变了PES/<span style=\"color:red\">NMP</span>铸膜液的热力学性质和PES分子的构象.这种效应依非溶剂种类的不同而显著不同.非溶剂添加剂对铸膜液性质的影响不仅表现在种类的差别上,也和无因次量——邻近比密切相关.邻近比可以表征铸膜液的热力学状态和混合溶剂的质量.铸膜液的邻近比增大,混合溶剂的质量下降,铸膜液的热力学稳定性降低,PES分子的构象也由舒展状态逐渐收缩.聚合物分子的构象对成膜过程的影响十分显著,研究成膜机理不能忽视非溶剂添加剂对铸膜液中高分子构象的影响.","authors":[{"authorName":"李战胜","id":"53b3aca7-2153-47f4-9cc8-56e7f93bf6ff","originalAuthorName":"李战胜"},{"authorName":"江成璋","id":"7762a6a8-2d12-4fd6-818c-b10159042e2a","originalAuthorName":"江成璋"}],"doi":"10.3969/j.issn.1007-8924.2001.05.001","fpage":"1","id":"888edb84-6fe1-46cf-8e35-c6502abdd78e","issue":"5","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"c31e9307-b12b-4a35-979b-bc30e9709e12","keyword":"非溶剂添加剂","originalKeyword":"非溶剂添加剂"},{"id":"3ee95bc0-dee4-48ef-b400-4223baafe03d","keyword":"溶剂质量","originalKeyword":"溶剂质量"},{"id":"0f9bfa6e-2eb2-4794-a0cd-6e639e4126f7","keyword":"热力学","originalKeyword":"热力学"},{"id":"2fb594f8-847f-432a-841e-e19713dbbdcb","keyword":"相互作用参数","originalKeyword":"相互作用参数"},{"id":"b540600a-5089-4861-b9f6-e52aeefa155d","keyword":"构象","originalKeyword":"构象"}],"language":"zh","publisherId":"mkxyjs200105001","title":"非溶剂添加剂对PES/<span style=\"color:red\">NMP</span>铸膜液性质的影响","volume":"21","year":"2001"},{"abstractinfo":"以对酚类化合物具有较强萃取作用和吸附作用的丙烯酰胺(AM)和吡咯烷酮(<span style=\"color:red\">NMP</span>)为单体，采用反相悬浮聚合法和浸渍法合成季铵盐修饰的多孔聚丙烯酰胺-吡咯烷酮(P(AM-<span style=\"color:red\">NMP</span>))复合微球。研究季胺盐修饰后多孔 P(AM-<span style=\"color:red\">NMP</span>)复合微球对焦化废水中酚类化合物的脱除效率，及影响复合微球材料脱除效率的诸多因素，并进一步探究脱附条件。其主要目的是为更好地解决焦化废水中普遍存在的严重的环境污染问题及吸附剂的重复使用奠定基础，以实现焦化废水不外排，解决目前焦化废水处理中的瓶颈问题。","authors":[{"authorName":"杨菊香","id":"c6b3d202-22fe-4f7c-bc77-4a494a715438","originalAuthorName":"杨菊香"},{"authorName":"韩敏","id":"157d1fd2-0342-4604-99e9-bf2b64e94d11","originalAuthorName":"韩敏"},{"authorName":"丁晨","id":"ede59f77-1adb-43a6-b62d-f595680502af","originalAuthorName":"丁晨"},{"authorName":"刘强","id":"ed9ed09a-72c1-4e74-a410-1adc7c903ed6","originalAuthorName":"刘强"}],"doi":"10.11896/j.issn.1005-023X.2015.16.006","fpage":"27","id":"e17713ea-bd9d-459d-8c3b-7e90b1b42bbc","issue":"16","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"a14887ad-eeb6-48f7-9382-1bf4edd05c3f","keyword":"环境污染","originalKeyword":"环境污染"},{"id":"104044e1-6b55-4f68-937e-0b5139df44e4","keyword":"焦化废水","originalKeyword":"焦化废水"},{"id":"bfb6ee82-750e-4d65-a711-ec9806d400cb","keyword":"萃取法","originalKeyword":"萃取法"},{"id":"18282e87-7c73-4ed8-8313-0d21d0104f6d","keyword":"吸附法","originalKeyword":"吸附法"},{"id":"b08b033d-6e3a-48b6-adfc-57f39c187977","keyword":"复合微球","originalKeyword":"复合微球"}],"language":"zh","publisherId":"cldb201516007","title":"多孔 P（AM-<span style=\"color:red\">NMP</span>）复合微球的合成及在含酚废水处理中的应用研究?","volume":"","year":"2015"},{"abstractinfo":"以Flory-HugginS理论为基础,详细推导了聚合物-溶荆-非溶剂三元聚合物成膜体系的双节线、旋节线和临界点求解方程,提供了方程的求解方法.根据此理论和方法,分别求解了聚合物杂萘联苯聚芳醚砜酮、杂萘联苯聚芳醚砜和杂萘联苯聚芳醚酮与H2O及<span style=\"color:red\">NMP</span>组成的三元体系在25℃时的相分离曲线.将计算结果与实验测定的浊点数据进行比较.分别优化校正了溶剂<span style=\"color:red\">NMP</span>与聚合物PPES、PPEK和PPESK之间的相互作用参数g23.提出二元Flory-HugginS相互作用参数值随温度变化的一般关系.并据此关系,以25℃时的相互作用参数为基准求解PPES/PPEK/PPESK-<span style=\"color:red\">NMP</span>-H2O三元体系在50℃和75℃时的相图,计算结果与浊点实验数据相吻合.","authors":[{"authorName":"林阳政","id":"e5812620-0527-4bdb-975f-5737e175f582","originalAuthorName":"林阳政"},{"authorName":"薛亚卓","id":"640c783d-f9cb-4374-8cbe-223ef5690860","originalAuthorName":"薛亚卓"},{"authorName":"李继定","id":"4f9c3730-4190-4279-a995-c0c681e1e931","originalAuthorName":"李继定"},{"authorName":"陈翠仙","id":"abb95e77-8b59-48fd-b878-751359a53353","originalAuthorName":"陈翠仙"}],"doi":"10.3969/j.issn.1007-8924.2008.03.007","fpage":"33","id":"17ff27d6-d3ae-47e5-ada7-39ead28914c8","issue":"3","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"8ab47bef-2c79-40ac-acb3-585d625b2132","keyword":"Flory-Huggins理论","originalKeyword":"Flory-Huggins理论"},{"id":"c810e200-c400-43b3-b495-d7a04c0e76e0","keyword":"双节线","originalKeyword":"双节线"},{"id":"fea0b9fe-387f-4fb8-9e80-205ab78249e0","keyword":"相互作用参数","originalKeyword":"相互作用参数"},{"id":"e2945d2c-4027-429f-896b-2f1eb5db674f","keyword":"温度","originalKeyword":"温度"},{"id":"1aa0513c-1c2d-4c83-a8f9-5ffa6e2c76c0","keyword":"相图","originalKeyword":"相图"}],"language":"zh","publisherId":"mkxyjs200803007","title":"聚合物PPES/PPEK/PPESK-<span style=\"color:red\">NMP</span>-H2O三元体系的相行为研究(Ⅱ)相图的计算","volume":"28","year":"2008"},{"abstractinfo":"采用浊点滴定法实验测定了新型成膜聚合物杂萘联苯聚芳醚砜(PPES)、杂萘联苯聚芳醚酮(PPEK)和杂萘联苯聚芳醚砜酮(PPESK)的N-甲基吡咯烷酮(<span style=\"color:red\">NMP</span>)溶液分别在3种不同温度(25,50和75℃)下用水滴定时的浊点数据.并用线性浊点方程对所得实验结果进行了参数回归,线性度甚佳.采用平板刮膜法制备了PPES,PPEK和PPESK的致密膜,并用称重法测定了3种聚合物膜对水的饱和吸附量,进而根据Flory-Rehner理论计算了聚合物与沉淀剂水之间的Flory-Huggins相互作用参数.为进一步理论计算PPES,PPEK和PPESKNMP-H2O的三元相图提供了基础数据.","authors":[{"authorName":"林阳政","id":"57b03d8d-108c-4415-aa42-27b0ab3175dc","originalAuthorName":"林阳政"},{"authorName":"李永国","id":"28cdd66a-c065-4700-8cb6-dd3c48467ac8","originalAuthorName":"李永国"},{"authorName":"陈翠仙","id":"1ea38e4b-ef17-4d12-b4de-156347e4a0d6","originalAuthorName":"陈翠仙"},{"authorName":"李继定","id":"9d020bdf-db7e-4dea-8cdd-872bfeaeeeb7","originalAuthorName":"李继定"}],"doi":"10.3969/j.issn.1007-8924.2006.06.005","fpage":"21","id":"39f22838-a7a3-4f21-9912-8bdea43f6e23","issue":"6","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"704e4dd4-f75f-46b5-9595-b34800e2caf6","keyword":"成膜聚合物","originalKeyword":"成膜聚合物"},{"id":"fdaa8ad5-ac00-41f3-997f-09959015c98b","keyword":"浊点","originalKeyword":"浊点"},{"id":"68863d2a-86ec-4212-b3a3-6ce5f3f02c04","keyword":"饱和吸附量","originalKeyword":"饱和吸附量"},{"id":"ee9e8f22-95db-4157-a7ec-5ef13c2bd8de","keyword":"Flory-Huggins相互作用参数","originalKeyword":"Flory-Huggins相互作用参数"},{"id":"3c50ab42-85e5-417d-a5c7-b55c1d4f1b22","keyword":"三元相图","originalKeyword":"三元相图"}],"language":"zh","publisherId":"mkxyjs200606005","title":"聚合物PPES/PPEK/PPESK-<span style=\"color:red\">NMP</span>-H2O三元体系的相行为研究(Ⅰ)浊点与饱和吸附量测定","volume":"26","year":"2006"},{"abstractinfo":"","authors":[{"authorName":"","id":"feecad36-7add-49bb-a321-3fd53f4c822d","originalAuthorName":""},{"authorName":"","id":"22dfd85f-654e-4c57-95c3-24f4a2dfa462","originalAuthorName":""}],"doi":"","fpage":"430","id":"0621362e-c2d0-4b51-9bac-a1ba8bcefe80","issue":"3","journal":{"abbrevTitle":"CLKXJSY","coverImgSrc":"journal/img/cover/JMST.jpg","id":"11","issnPpub":"1005-0302 ","publisherId":"CLKXJSY","title":"材料科学技术（英文）"},"keywords":[{"id":"24518bef-b577-441b-8b42-f893b9d19659","keyword":"","originalKeyword":""}],"language":"zh","publisherId":"clkxjsxb-e200503031","title":"Phase Separation and Theta-compositions of PPES/<span style=\"color:red\">NMP</span>/non-solvent Systems","volume":"21","year":"2005"},{"abstractinfo":"以氧化石墨烯为模板剂,N-甲基吡咯烷酮( <span style=\"color:red\">NMP</span>)为溶剂,通过溶剂热法制备高结晶度、片状结构钛酸锂/石墨烯复合电极材料( <span style=\"color:red\">NMP</span>-LTO/G)。与未添加氧化石墨烯的样品<span style=\"color:red\">NMP</span>-LTO相比,样品<span style=\"color:red\">NMP</span>-LTO/G的片状结构更好,结晶性与电化学性能明显提高。讨论氧化石墨烯作为模板剂的作用机理；基于双亲性结构特征和表面活性剂的特点,在复合材料制备过程中,氧化石墨烯与碱性条件、有机溶剂等产生协同作用,有利于高结晶度片状结构<span style=\"color:red\">NMP</span>-LTO/G复合材料形成。","authors":[{"authorName":"董海勇","id":"acb6c99c-9790-461a-b6fa-a59cec3e70fb","originalAuthorName":"董海勇"},{"authorName":"贺艳兵","id":"b92b0ba9-3c87-4d52-af86-9d85903f5f9a","originalAuthorName":"贺艳兵"},{"authorName":"李宝华","id":"2d8434d3-531a-458d-88b1-e6db74cf0630","originalAuthorName":"李宝华"},{"authorName":"康飞宇","id":"67684b75-98dc-461f-9d33-a14f393e4261","originalAuthorName":"康飞宇"}],"doi":"","fpage":"115","id":"e1ab59cb-2ffe-451b-93e4-035d63f5721f","issue":"2","journal":{"abbrevTitle":"XXTCL","coverImgSrc":"journal/img/cover/XXTCL.jpg","id":"70","issnPpub":"1007-8827","publisherId":"XXTCL","title":"新型炭材料"},"keywords":[{"id":"a0a9c9f8-52e5-4b55-bee9-2ead00949e83","keyword":"钛酸锂","originalKeyword":"钛酸锂"},{"id":"202bada0-3bf6-495c-a1d3-497c5a2facc8","keyword":"石墨烯","originalKeyword":"石墨烯"},{"id":"90d831a2-782a-4f04-9adc-4e69166c9925","keyword":"模板剂","originalKeyword":"模板剂"},{"id":"c4476daf-c349-42ce-85d7-fff25f68508e","keyword":"片状形貌","originalKeyword":"片状形貌"},{"id":"34827621-3a3a-4153-9e31-4fd2ebdfc013","keyword":"高结晶性","originalKeyword":"高结晶性"}],"language":"zh","publisherId":"xxtcl201602002","title":"高结晶度片状钛酸锂/石墨烯复合材料的可控制备及其电化学性能","volume":"31","year":"2016"}],"totalpage":15,"totalrecord":141}