欢迎登录材料期刊网

材料期刊网

高级检索

通过向带锈耐候钢表面喷淋锈层稳定化剂进行预处理,使锈层表面形成了一层化学转化层,并进而研究了其对耐候钢继续腐蚀行为的影响.利用干湿循环交替腐蚀(CCT)、增重实验、场发射扫描电镜(SEM)及能谱仪(EDS)、X射线衍射分析仪(XRD)和电化学工作站等实验手段对经过预处理及未处理样品进行对比测试.结果表明:该转化层对腐蚀性离子Cl-有显著的拦截效应,并导致样品在腐蚀过程中增重减缓;预处理不改变腐蚀产物的类型,但会造成锈层内非晶相比例上升并使锈层颗粒更加细小;转化层的短期效应与长期影响不同,转化层的存在总体上有利于加速锈层稳定化.

参考文献

[1] Shuichi Hara;Takayuki Kamimura;Hideaki Miyuki et al.Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge[J].Corrosion Science,2007,49(03):1131-1142.
[2] 张旭,杨善武,张文华,郭晖,贺信莱.低合金耐候钢在周期性交替条件下的腐蚀行为[J].材料研究学报,2013(01):18-24.
[3] Okada H;Hosoi Y;Yukawaki et al.Structure of the rust formed on low alloy steels in atmospheric corrosion[J].Tetsu-to-Hagane,1969,55(05):355-365.
[4] Miyata S.;Takemura M. .Rust Stabilizing Surface Treatment for Weathering Steel (CUPTEN COAT M)[J].NKK技報,2000(171):14-20.
[5] 刘丽宏,齐慧滨,卢燕平,李晓刚.耐候钢的腐蚀及表面稳定化处理技术[J].腐蚀与防护,2002(12):515-518.
[6] 刘丽宏,李明,李晓刚,卢燕平,齐慧滨.耐候钢表面锈层稳定化处理用新型涂层研究[J].金属学报,2004(11):1195-1199.
[7] A. Collazo;X. R. Novoa;C. Perez;B. Puga .EIS study of the rust converter effectiveness under different conditions[J].Electrochimica Acta,2008(25):7565-7574.
[8] X. H. Chen;J. H. Dong;E. H. Han .Effect of Al alloying on corrosion performance of steel[J].Corrosion Engineering, Science and Technology,2007(3):224-231.
[9] Long Hao;Sixun Zhang;Junhua Dong;Wei Ke .Atmospheric corrosion resistance of MnCuP weathering steel in simulated environments[J].Corrosion Science,2011(12):4187-4192.
[10] Long Hao;Sixun Zhang;Junhua Dong;Wei Ke .Evolution of atmospheric corrosion of MnCuP weathering steel in a simulated coastal-industrial atmosphere[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2012(Jun.):270-276.
[11] T. Kamimura;S. Hara;H. Miyuki;M. Yamashita;H. Uchida .Composition and protective ability of rust layer formed on weathering steel exposed to various environments[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2006(9):2799-2812.
[12] WANG J H;WEI F I;CHANG Y S et al.The corrosion mechanisms of carbon steel and weathering steel in SO2 polluted atmospheres[J].Materials Chemistry and Physics,1997,47(01):1-8.
[13] 韩薇,汪俊,王振尧,于国才,李洪锡.碳钢与低合金钢耐大气腐蚀规律研究[J].中国腐蚀与防护学报,2004(03):147-150,154.
[14] Asami K;Kikuchi M .In-depth distribution of rusts on a plain carbon steel and weathering steels exposed to coastal-industrial atmosphere for 17 years[J].Corrosion Science,2003,45(11):2671-2688.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%