碳纳米笼(CNC)的应用很广泛,但原始CNC具有金属核心,必须去除该核心才能得到空心CNC.采用氯化铵低温热处理原始CNC,再用水过滤得到空心产品.结果表明,这是一种很好的纯化方法.同时深入研究了该方法的机理,提出一种解释:氯化铵分解产物扩散进CNC后与金属核心反应,产物以气态形式扩散出CNC,最终消耗掉金属核心.
参考文献
[1] | L. Li;H. Song;X. Chen .Hollow carbon microspheres prepared from polystyrene microbeads[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(3):596-599. |
[2] | El Hamaoui B;Zhi LJ;Wu JS;Kolb U;Mullen K .Uniform carbon and carbon/cobalt nanostructures by solid-state thermolysis of polyphenylene dendrimer/cobalt complexes[J].Advanced Materials,2005(24):2957-2960. |
[3] | Zhang J;Perez R J et al.Documentation of damping capacity of metallic,ceramic and metal-matrix composite materials[J].Journal of Materials Science,1993,28(09):2395. |
[4] | Daniele Mirabile Gattia;Marco Vittori Antisari;Leonardo Giorgi;Renzo Marazzi;Emanuela Piscopiello;Amelia Montone;Serafina Bellitto;Silvia Licoccia;Enrico Traversa .Study of different nanostructured carbon supports for fuel cell catalysts[J].Journal of Power Sources,2009(1):38-44. |
[5] | Yun Hau Ng;Shigeru Ikeda;Takashi Harada;Suguni Higashida;Takao Sakata;Hirotaro Mori;Michio Matsumura .Fabrication of Hollow Carbon Nanospheres Encapsulating Platinum Nanoparticles Using a Photocatalytic Reaction[J].Advanced Materials,2007(4):597-601. |
[6] | Saito Yahachi;Matsumoto Takehisa .Carbon nano-cages created as cubes[J].Nature,1998,392(6673):237. |
[7] | Wang JN;Zhang L;Niu JJ;Yu F;Sheng ZM;Zhao YZ;Chang H;Pak C .Synthesis of high surface area, water-dispersible graphitic carbon nanocages by an in situ template approach[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(3):453-459. |
[8] | Bao Yu Xia;Jian Nong Wang;Xiao Xia Wang;Jun Jie Niu;Zhao Min Sheng;Ming Ruo Hu;Qing Chun Yu .Synthesis and Application of Graphitic Carbon with High Surface Area[J].Advanced functional materials,2008(12):1790-1798. |
[9] | Ying Liu;Jie Ling;Wei Li .Effective synthesis of carbon-coated Co and Ni nanocrystallites with improved magnetic properties by AC arc discharge under an N_2 atmosphere[J].Nanotechnology,2004(1):43-47. |
[10] | Ma YW;Hu Z;Huo KF;Lu YN;Hu YM;Liu Y;Hu JH;Chen Y .A practical route to the production of carbon nanocages[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1667-1672. |
[11] | Wang ZL.;Yin JS. .Graphitic hollow carbon calabashes[J].Chemical Physics Letters,1998(1/2):189-192. |
[12] | Shang Jun Teng;Jian Nong Wang;Xiao Xia Wang .Synthesis of thin-walled carbon nanocages and their application as a new kind of nanocontainer[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(14):5443-5450. |
[13] | Shang Jun Teng .Preparation of hollow carbon nanocages by iodine-assisted heat treatment[J].Journal of Power Sources,2010(4):1065. |
[14] | X.H. Chen;C.S. Chen;Q. Chen;F.Q. Cheng;G. Zhang;Z.Z. Chen .Non-destructive purification of multi-walled carbon nanotubes produced by catalyzed CVD[J].Materials Letters,2002(3):734-738. |
[15] | Sheng, ZM;Wang, JN .Thin-walled carbon nanocages: Direct growth, characterization, and applications[J].Advanced Materials,2008(5):1071-1075. |
[16] | Hernadi K;Fonseca A et al.Catalytic synthesis and purification of carbon nanotubes[J].Synthetic Metals,1996,77(1-3):31. |
[17] | Colomer J F;Pierdigrosso P et al.Different purification methods of carbon nanotubes produced by catalytic synthesis[J].Synthetic Metals,1999,103(1-3):2482. |
[18] | Holzinger M.;Hirsch A. .A new purification method for single-wall carbon nanotubes (SWNTs)[J].Applied physics, A. Materials science & processing,2000(5):599-602. |
[19] | Ebbesen T W;Ajayan P M et al.Purification of nanotubes[J].Nature,1994,367(6463):519. |
[20] | Rinzler AG.;Dai H.;Nikolaev P.;Huffman CB.;Rodriguez-Macias FJ.;Boul PJ.;Lu AH.;Heymann D.;Colbert DT.;Lee RS.;Fischer JE.;Rao AM.;Eklund PC.;Smalley RE.;Liu J. .Large-scale purification of single-wall carbon nanotubes: process, product, and characterization[J].Applied physics, A. Materials science & processing,1998(1):29-37. |
[21] | Jiao J.;Wang XK.;Withers JC.;Seraphin S. .PREPARATION AND PROPERTIES OF FERROMAGNETIC CARBON-COATED FE, CO, AND NI NANOPARTICLES[J].Journal of Applied Physics,1996(1):103-108. |
[22] | Li XG.;Takahashi S.;Sato M.;Chiba A. .Oxidation characteristics and magnetic properties of iron ultrafine particles[J].Journal of Applied Physics,1998(7):3871-3875. |
[23] | 柳刚,秦伯雄,郭院波,范荣焕,吕楠.铁纳米颗粒的热行为及热稳定性[J].兵器材料科学与工程,2003(04):18-22. |
[24] | Bremm Stephan;Gerd Meyer .Reactivity of ammoniun halides:Action of ammonium chloride and bromide on iron and iron(Ⅲ)chloride and bromide[J].Zeitschrift Fur Anorganische Und Allgemeine Chemie,2003,629(10):1875. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%