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采用动电位扫描与恒电位阳极氧化的电化学解吸研究了钢中的氢。通过测定08F和20号钢的充氢电位及这两种钢和1Cr18Ni9Ti不锈钢经不同介质充氢、不同条件解吸后的解吸氢量,结合理论分析,找出了阴极进入氢与阳极解吸氢的某些规律及其相互关系。

Potentiodynamic sweep and electrochemical desorption under potentiostatic oxidation are used to investigate the hydrogen in steel. Samples of 08F and mild carbon steel were galvanostaically H-charged for various times with the H-chargingpotential, φ_H, measured. The amount of H-desorbed electrochemically for both steels mentioned above and for 1 Crl8Ni9Ti stainless steel was determined in various H-charging media with different conditions of desorption. Some relationship between cathodic H-entering and anodic H-desorbing, as well as that between the H-ingress and the H-egress can be found.

参考文献

[1] Bockris, J. OM, et al., edited: Comprehesive Treatise of Electrochemisty, Volume4: Electrochemical Materials Science, 411~462(1981)
[2] Hydrogen In Metals, proceedings of the 2nd international Congress, 1, 1As, 3E3, 3E4(1977)
[3] Devanathan, M. A. V., Stachuski, Z., proc. Roy. Soc., A270 90(1962)
[4] 姚禄安,周仲柏,陶映初,武汉大学学报,(自然科学版),1,75~79(1980)
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[9] 陶映初,姚禄安等,武汉大学学报(自然科学版),4,75~80(1984)
[10] Pressouyer, G. M. and Bernstein, I. M., Metall. Trans. A, 12A, 835(1981)
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