利用γ-(2,3-环氧丙氧基)丙基三甲氧基硅烷(KH560)对重质碳酸钙表面进行接枝改性,并以改性后的重钙为填料制备了环氧涂层.采用傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)、热重分析仪(TG)和粒径分析对改性重钙进行表征,使用电化学阻抗谱(EIS)、高温高压釜等设备测试涂层的附着力和耐腐蚀性等性能.结果表明:重钙表面化学键合了KH560有机官能团,提高了环氧涂层的相容性、耐腐蚀性和热稳定性.
参考文献
[1] | Tran, H.V.;Tran, L.D.;Vu, H.D.;Thai, H. .Facile surface modification of nanoprecipitated calcium carbonate by adsorption of sodium stearate in aqueous solution[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2010(1/3):95-103. |
[2] | G S DESHMUKH;S U PATHAK;D R PESHWE .Effect of uncoated calcium carbonate and stearic acid coated calcium carbonate on mechanical, thermal and structural properties of poly(butylene terephthalate) (PBT)/calcium carbonate composites[J].Bulletin of Materials Science,2010(3):277-284. |
[3] | PLUEDDEMANN E P.The silicone and titanate coupling agents[M].上海:上海科学技术文献出版社,1987 |
[4] | Rungruang P;Grady BP;Supaphol P .Surface-modified calcium carbonate particles by admicellar polymerization to be used as filler for isotactic polypropylene[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2006(1/3):114-125. |
[5] | 贾仁广,吴香发,何杰.超声促进钛酸酯偶联剂与CaCO3表面相互作用研究[J].安徽理工大学学报(自然科学版),2011(04):46-50. |
[6] | Shi, X.;Rosa, R.;Lazzeri, A. .On the coating of precipitated calcium carbonate with stearic acid in aqueous medium[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(11):8474-8482. |
[7] | 任晓玲,骆振福,吴成宝,杨玉芬,盖国胜.重质碳酸钙的表面改性研究[J].中国矿业大学学报,2011(02):269-272,304. |
[8] | Osman MA.;Suter UW. .Surface treatment of calcite with fatty acids: Structure and properties of the organic monolayer[J].Chemistry of Materials,2002(10):4408-4415. |
[9] | Ridgway CJ;Gane PAC;Schoelkopf J .Modified calcium carbonate coatings with rapid absorption and extensive liquid uptake capacity[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2004(1/3):91-102. |
[10] | Dongya, Y.;Hanqing, Z.;Fengxian, Q.;Li, H. .Investigation of polyurethane (urea)/modified nano-calcium carbonate hybrid aqueous dispersions and their films[J].Journal of Applied Polymer Science,2012(4):2896-2901. |
[11] | Fan-Long Jin;Soo-Jin Park .Thermal Stability of Trifunctional Epoxy Resins Modified with Nanosized Calcium Carbonate[J].Bulletin of the Korean Chemical Society,2009(2):334-338. |
[12] | Silviu Jipa;Traian Zaharescu;Pitt Supaphol .Thermal stability of isotactic polypropylene modified with calcium carbonate nanoparticles[J].Polymer bulletin,2010(8):783-790. |
[13] | Pal, M.K.;Singh, B.;Gautam, J. .Thermal stability and UV-shielding properties of polymethyl methacrylate and polystyrene modified with calcium carbonate nanoparticles (Conference Paper)[J].Journal of thermal analysis and calorimetry,2012(1):85-96. |
[14] | 高红云,张招贵.硅烷偶联剂的偶联机理及研究现状[J].江西化工,2003(02):30-34. |
[15] | 张云浩,翟兰兰,王彦,刘若望,袁继新,兰云军.硅烷偶联剂KH-570表面改性纳米SiO2[J].材料科学与工程学报,2012(05):752-756. |
[16] | 曹楚南;张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002 |
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