利用分子束质谱结合真空紫外同步辐射光电离技术研究了低压层流预混二甲醚/氧气/氩气火焰.通过测量火焰物种的离子信号强度随燃烧炉位置的关系曲线,计算了主要火焰物种的摩尔分数曲线.分析了燃料当量比(φ)为0.8,1.0和1.5时主要火焰物种的摩尔分数曲线,阐述了燃烧当量比对低压层流预混二甲醚/氧气/氩气火焰化学结构的影响.研究为进一步认识二甲醚燃烧提供了实验数据.
参考文献
[1] | Cool A T;Wang J;Hansen N et al.Photoionization Mass Spectrometry and Modeling Studies of the Chemistry of Fuel-Rich Dimethyl Ether Flames[J].Proceedings of the Combustion Institute,2007,31:285-293. |
[2] | Yoshiaki Hidaka;Kazutaka Sato;Masatsugu Yamane .High-temperature pyrolysis of dimethyl ether in shock waves[J].Combustion and Flame,2000(1/2):1-22. |
[3] | Curran H J;Fischer S L;Dryer F L .The Reaction Kinetics of Dimethyl Ether Ih Low-Temperature Oxidation in Flow Reactors[J].International Journal of Chemical Kinetics,2000,32:741-759. |
[4] | Francisco Joseph S. .On the competition between hydrogen abstraction versus C-O bond fission in initiating dimethyl ether combustion[J].Combustion and Flame,1999(1):312-316. |
[5] | Jing-Yao Liu;Ze-sheng Li;Jia-yan Wu;Zhi-gang Wei;Gang Zhang;Chia-Chung Sun .Theoretical study and rate constant calculation of the CH_2O+CH_3 reaction[J].The Journal of Chemical Physics,2003(14):7214-7221. |
[6] | Qi F;Yang R;Yang B;Huang CQ;Wei LX;Wang J;Sheng LS;Zhang YW .Isomeric identification of polycyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoionization[J].Review of Scientific Instruments,2006(8):84101-1-84101-5-0. |
[7] | Cool A T;Nakajima K;Craig A T et al.Studies of a Fuel-Rich Propane Flame with Photoionization Mass Spectrometry[J].Proceedings of the Combustion Institute,2005,30:1681-1688. |
[8] | Curran H J;Pitz W J;Westbrook C K et al.A Wide Range Modeling Study of Dimethyl Ether Oxidation[J].International Journal of Chemical Kinetics,1998,30:229-241. |
[9] | Wang H;Frenklach M .A Detailed Kinetic Modeling Study of Aromatics Formation in Laminar Premixed Acetylene and Ethylene Flames[J].Combustion and Flame,1997,110:173-221. |
[10] | Bozzelli J W;Dean A M .Hydrocarbon Radical Reactions with Oxygen:Comparison of Allyl,Formyl,and Vinyl to Ethyl[J].Journal of Physical Chemistry,1993,97:4427-4441. |
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