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This paper describes work performed to determine some of the properties of the electroless Ni-W-P amorphous deposits. Phosphorus contents were varied up to 32 at.%, and the amorphous structure was found to be present at phosphorus contents above 5 at.%. Irrespective of P content, all the deposits exhibited excellent adhesion to metallic substrates. The addition of even small amounts of W provided greatly increased hardness compared with the plain Ni-P deposits. The wettability properties of the Ni-W-P deposits were found to be comparable to those of Ni-P and N-B-P deposits but inferior to those of Ni-B deposits. (C) Elsevier Science Inc., 1996