目的 研究Al2O3纳米粒子环氧复合涂层对钢筋的防护性能.方法 制备Al2O3纳米粒子,将其添加至环氧涂料中,并涂覆在工业钢筋表面成膜.通过XRD和SEM对Al2O3进行表征;利用电化学噪声、交流阻抗谱分析技术,对复合涂层在3.5%(质量分数)NaCl介质中对工业钢筋的防护性能进行测试分析.结果 制备的氧化铝纳米粒子的粒径平均为75 nm.通过对电化学噪声测试的有效数据进行时域和频域分析,通过交流阻抗谱分析及数据拟合,认为Al2 O3纳米粒子添加量为0.1%(以占环氧树脂质量的百分比计)时,涂层对钢筋的防护性能最好.结论 向环氧涂层中添加适量的Al2 O3纳米粒子,可以明显提升其对钢筋的防护性能.
参考文献
[1] | ShiGang Dong;Bing Zhao;Changjian Lin;RongGui Du;RongGang Hu;Gregory Xiaoge Zhang .Corrosion behavior of epoxy/zinc duplex coated rebar embedded in concrete in ocean environment[J].Construction and Building Materials,2012(1):72-78. |
[2] | 杨乐.混凝土的劣化对钢筋混凝土桥梁结构耐久性的影响[J].科技视界,2012(04):51-52. |
[3] | 吴德坤,郭瑞,白根华.基于海水状态下混凝土防腐的研究[J].科技资讯,2012(08):63-63. |
[4] | SHI Xian-ming;XIE Ning;KEITH Fortune et al.Durability of Steel Reinforced Concrete in Chloride Environments[J].Construction and Building Materials,2012,30:125-138. |
[5] | 赵璐,罗涛.桥梁钢筋混凝土防腐蚀技术研究与应用[J].中国科技信息,2007(07):44-45. |
[6] | Turri S;Alborghetti L;Levi M .Formulation and properties of a model two-component nanocomposite coating from organophilic nanoclays[J].Journal of Polymer Research,2008(5):365-372. |
[7] | ZENG Q H;WANG D Z .Synthesis of Polymer-montmorillonite Nanocomposites by in Situintercalative Polymerization[J].NANOTECHNOLOGY,2002,5:549. |
[8] | 孙毅,钟发春,舒远杰,郝晓飞,刘勇.聚苯胺涂层防腐行为的电化学研究方法[J].电镀与涂饰,2009(08):62-66. |
[9] | 梁永纯,赵书彦,聂铭,刘福春,林介东,韩恩厚.纳米Zr粒子改性环氧涂层的耐腐蚀性能[J].材料研究学报,2013(02):189-196. |
[10] | Dhoke, S.K.;Khanna, A.S. .Electrochemical impedance spectroscopy (EIS) study of nano-alumina modified alkyd based waterborne coatings[J].Progress in Organic Coatings: An International Review Journal,2012(1):92-99. |
[11] | ASHASSI-SORKHABI H;SEIFZADEH D;RAGHIBI-BOROUJENI M.Analysis of Electrochemical Noise Data in Both Time and Frequency Domains to Evaluate the Effect of ZnO Na-nopowder Addition on the Corrosion Protection Performance of Epoxy Coatings[J].Arabian Journal of Chemistry,2012:1-8. |
[12] | S. Girija;U. K. Mudali;V. R. Raju .Determination of corrosion types for AISI type 304L stainless steel using electrochemical noise method[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):188-195. |
[13] | 刘晓方,王汉功,权高峰,黄淑菊.电化学系统噪声分析进展[J].腐蚀科学与防护技术,2001(02):101-105. |
[14] | 李季,赵林,李博文,郑丽群,韩恩厚.304不锈钢点蚀的电化学噪声特征[J].中国腐蚀与防护学报,2012(03):235-240. |
[15] | 赵小玲 .纳米氧化铝的制备及改性工艺研究[D].西北大学,2003. |
[16] | Ashassi-Sorkhabi, H;Masoumi, B;Ejbari, P;Asghari, E .Corrosion inhibition of mild steel in acidic media by Basic yellow 13 dye[J].Journal of Applied Electrochemistry,2009(9):1497-1501. |
[17] | URUCHURTU J C;DAWSON J L .Noise Analysis of Pure Aluminum under Different Pitting Condition[J].CORROSION,1987,4(01):19-25. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%