以顺丁烯二酸酐(MA)、双环戊二烯和乙二醇为原料,采用水解法,通过控制双环戊二烯与乙二醇(DCPD/EG)的质量比和酯化阶段的中控粘度,合成了增稠双环戊二烯改性不饱和聚酯树脂。结果表明:当双环戊二烯与乙二醇的质量比为1∶0.815,酯化阶段的树脂粘度在125℃下达23 P时,合成的不饱和聚酯树脂具有优良的增稠性,采用该树脂制备的片状模塑料(SMC)具有优良的工艺性,压制的板材具有优良的力学性能和电气性能。
Using maleic anhydride, dicyclopentadiene and ethylene glycol as raw materials, a thickened un-saturated polyester resin modified by dicyclopentadiene was synthesized by hydrolysis method and controlling the mass ratio of dicyclopentadiene and ethylene glycol(DCPD/EG) and the viscosity of resin at esterification stage. The results indicate that when the mass ratio of DCPD and EG is 1∶0.815, the viscosity of the resin under 125℃ at esterification stage is 23 P, the synthesized resin has good thicken-ing property. The sheet molding compound(SMC) prepared by the resin show good procesibility, and its laminate has excellent mechanical properties and electrical properties.
参考文献
[1] | 熊丽君,王淑华,陈晓农,张洋.高含量双环戊二烯型不饱和聚酯的制备[J].北京化工大学学报(自然科学版),2000(03):33-36. |
[2] | 孙军 .双环戊二烯改性不饱和聚酯树脂工艺及性能的研究[D].哈尔滨理工大学,2006. |
[3] | 胡福增;陈旭;周润培.乙烯基酯树脂的增稠[J].复合材料学报,1992(01):31-36. |
[4] | 王天堂,陆士平,王立刚,沈伟.特性乙烯基酯树脂的技术发展[J].纤维复合材料,2004(02):19-21,50. |
[5] | 张兰芬,吴盾,刘春林.不饱和聚酯树脂增稠特性的研究[J].玻璃钢/复合材料,2009(05):23-26. |
[6] | 肖淑红,王绪江.低温催化法合成双环戊二烯改性不饱和聚酯树脂[J].热固性树脂,2004(06):8-11. |
[7] | 张炳烛,吴命君.2步法合成双环戊二烯型不饱和聚酯树脂[J].热固性树脂,2005(06):5-6,10. |
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