研究了烧结Nd-Fe-B磁体表面渗镀Dy2O3对磁体组织结构与磁性能的影响. 表面渗镀Dy2O3后, N40的矫顽力由1017 kA · m-1提高到1146 kA · m-1, 38H的矫顽力由1575 kA · m-1提高到1753 kA · m-1, 而通过传统合金化添加同量Dy, N40和38H的矫顽力分别为1061和1634 kA · m-1. 磁体表面渗镀Dy2O3后热稳定性也大大改善. 组织分析表明, 元素Dy从表面扩散并渗入磁体的内部约20 μm厚, Nd2Fe14B晶粒表层附近Dy含量比晶界中高, 说明Dy2O3中的Dy通过扩散与富Nd相及Nd2Fe14B晶粒表面层的部分Nd发生置换反应, 增强了Nd2Fe14B晶粒表面层的磁晶各向异性. 在此基础上, 提出了高矫顽力高热稳定性渗Dy的烧结Nd-Fe-B磁体中Dy分布的理想模型.
参考文献
[1] | Herbst J F .R2Fe14B materials:Intrinsic properties and technological aspects[J].Reviews of Modern Physics,1991,63:819. |
[2] | Bai G;Gao R W;Sun Y;Han G B Wang B .Study of high-coercivity sintered Nd-Fe-B magnets[J].Journal of Magnetism and Magnetic Materials,2007,308:20. |
[3] | Faria RN. .The influence of zirconium addition and process parameters on the magnetic properties of Pr-Fe-B sintered magnets[J].Journal of Magnetism and Magnetic Materials,2002(1):56-64. |
[4] | Yan A R;Song X P;Chen Z M;Wang X T .Characterization of microstructure and coercivity of Nd-Fe-B magnets with Ti and Al or Cu addition[J].Journal of Magnetism and Magnetic Materials,1998,185:369. |
[5] | Pandian S.;Chandrasekaran V.;Markandeyulu G.;Iyer KJL.;Rao KVSR. .Effect of Al, Cu, Ga, and Nb additions on the magnetic properties and microstructural features of sintered NdFeB[J].Journal of Applied Physics,2002(10):6082-6086. |
[6] | Gabay AM.;Zhang Y.;Hadjipanayis GC. .Effect of very small additions on the coercivity of Dy-free Nd-Fe-(Co)-B-sintered magnets[J].Journal of Magnetism and Magnetic Materials,2002(2/3):226-232. |
[7] | Menushenkov V P;Savchenko A G .Effects of post-sintering annealing on magnetic properties of Nd-Fe-B sintered magnets[J].Journal of Magnetism and Magnetic Materials,2003,258-259:558. |
[8] | 谭春林,白书欣,张虹,高艳丽,张家春,蔡珣.回火处理对烧结钕铁硼永磁材料组织和磁性能的影响[J].中国有色金属学报,2002(z1):64-66. |
[9] | 王伟,罗伟,文玉华,于濂清,严密.二级回火对(NdDy)FeCoCuB磁体磁性能和微结构的影响[J].稀有金属材料与工程,2005(10):1633-1636. |
[10] | 周圣银,周廉,陈绍楷,罗建军.热处理对烧结NdFeB磁体微观结构和磁性能的影响[J].稀有金属材料与工程,2006(06):1006-1008. |
[11] | Yu LQ;Wen YH;Yan M .Effects of Dy and Nb on the magnetic properties and corrosion resistance of sintered NdFeB[J].Journal of Magnetism and Magnetic Materials,2004(2/3):353-356. |
[12] | Pandian S;Chandrasekaran V;Markandeyulu G;Iyer K J L Rama Rao K V S .Effect of Co,Dy and Ga on the magnetic properties and the microstructure of powder metallurgically processed Nd-Fe-B magnets[J].Journal of Alloys and Compounds,2004,364:295. |
[13] | De Groot DH.;de Boer FR.;Buschow KHJ. .Two-powder Nd2Fe14B magnets with DyGa addition[J].Journal of Applied Physics,1998(1):388-393. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%