采用溶胶-凝胶法制备了LiFePO4.研究了聚乙二醇对LiFePO4材料形貌和电化学性能的影响.结果表明,添加聚乙二醇制备的材料具有更小的粒径,更大的比表面积;该材料以0.2C、1C、5C、10C的倍率放电,首次放电比容量分别达到143.9mAh/g、133.4mAh/g、124.2mAh/g、ll2.7mAh/g,比没添加聚乙二醇制备的材料具有更好的倍率性能.
参考文献
[1] | Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194. |
[2] | Prosini PP.;Lisi M.;Zane D.;Pasquali M. .Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid state ionics,2002(1/2):45-51. |
[3] | K.S. Park;J.T. Son;H.T. Chung;S.J. Kim;C.H. Lee;K.T. Kang;H.G. Kim .Surface modification by silver coating for improving electrochemical properties of LiFePO_4[J].Solid State Communications,2004(5):311-314. |
[4] | Shin H C;Cho W I;Jang H .Electrochemical properties of carbon-coated LiFePO4 cathode using graphite,carbon black,and acetylene black[J].Electrochimica Acta,2006,52(04):1472. |
[5] | Jae-Kwang Kim;Jae-Won Choi;Gouri Cheruvally .A modified mechanical activation synthesis for carbon-coated LiFePO_4 cathode in lithium batteries[J].Materials Letters,2007(18):3822-3825. |
[6] | Chung S Y;Bloking J T;Chiang Y M .Electronically conductive phospho-olivines as lithium storage electrodes[J].Nature Materials,2002,1:123. |
[7] | Shenouda A Y;Liu H K .Studies on electrochemical behaviour of zinc-doped LiFePO4 for lithium battery positive electrode[J].Journal of Alloys and Compounds,2009,477(1-2):498. |
[8] | Tsung-Hsien Teng;Mu-Rong Yang;She-hung Wu;Yi-Ping Chiang .Electrochemical properties of LiFe0.9Mg0.1PO4 / carbon cathode materials prepared by ultrasonic spray pyrolysis[J].Solid State Communications,2007(7):389-392. |
[9] | A. Yamada;S.C. Chung;K. Hinokuma .Optimized LiFePO_4 for Lithium Battery Cathodes[J].Journal of the Electrochemical Society,2001(3):A224-A229. |
[10] | Zhang S S;Allen J L;Xu K et al.Optimization of reaction condition for aolid-state synthesis of LiFePO4-C composite cathode[J].Journal of Power Sources,2005,147(1-2):234. |
[11] | K.S.Park;T.K.Kang;S.B.Lee;G.Y.Kim;Y.J.Park;H.G.Kim .Synthesis of LiFePO_4 with fine particle by co-precipitation method[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2004(12):1803-1810. |
[12] | Dokko K;Koizumi S;Sharaishi K et al.Electrochemical properties of LiFePO4 prepared via hydrothermal route[J].Journal of Power Sources,2007,165(02):656. |
[13] | Song M S;Kang Y M;Kim J H et al.Simple and fast synthesis of LiFePO4-C composite for lithium rechargeable batteries by ball-milling and microwave heating[J].Journal of Power Sources,2007,166(01):260. |
[14] | Sanchez MAE;Brito GES;Fantini MCA;Goya GF;Matos JR .Synthesis and characterization of LiFePO4 prepared by sol-gel technique[J].Solid state ionics,2006(5/6):497-500. |
[15] | Andersson A S;Thomas J O .The source of first-cycle capacity loss in LiFePO4[J].Journal of Power Sources,2001,97-98:498. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%