以高氢稀释的硅烷(SiH4)为反应气体,硼烷(B2H6)为掺杂气体,利用RF-PECVD方法,在玻璃衬底上制备出掺硼的氢化非晶硅(a-Si∶H)薄膜,研究了硼掺杂量对氢化非晶硅(a-Si∶H)薄膜的光学性能的影响.利用NKD-7000W光学薄膜分析系统测试薄膜的透射谱和反射谱,并利用该系统的软件拟合得出薄膜的折射率、消光系数、吸收系数等光学性能参数,利用Tauc法计算掺硼的非晶硅薄膜的光学带隙.实验结果表明,随着硼掺杂量的增加,掺杂非晶硅薄膜样品在同一波长处的折射率先增大后减小,而且每一样品均随着入射光波长的增加而减小,在波长500 nm处的折射率均达到4.3以上;薄膜的消光系数和吸收系数随着硼掺杂量的增大而增大,在500 nm处的吸收系数可高达1.5×105 cm-1.在实验的硼掺杂范围内,光学带隙从1.81 eV变化到1.71 eV.
参考文献
[1] | Spear W E;Lecomber P G .Substitutional doping of amorphous silicon[J].Solid State Communications,1975,17(09):1193-1196. |
[2] | 余云鹏,林舜辉,黄翀,林璇英.非晶硅薄膜厚度均匀性对其透射光谱的影响[J].汕头大学学报(自然科学版),2004(01):50-54. |
[3] | 韩大星,王万录,张智.非晶硅电致发光机理及用电致发光谱研究太阳能电池本征层中的缺陷态能量分布[J].物理学报,1999(08):1484-1490. |
[4] | 朱嘉琦,卢佳,田桂,檀满林,耿达.非晶硅太阳电池窗口层材料掺硼非晶金刚石的研究[J].无机材料学报,2008(05):1064-1066. |
[5] | 倪牮,张建军,王先宝,李林娜,侯国付,孙建,耿新华,赵颖.低温高速率沉积非晶硅薄膜及太阳电池[J].光电子·激光,2010(02):217-221. |
[6] | Platz R.;Hof C.;Shah A.;Wieder S.;Rech B.;Wagner S. .Influence of excitation frequency, temperature, and hydrogen dilution on the stability of plasma enhanced chemical vapor deposited a-Si : H[J].Journal of Applied Physics,1998(7):3949-3953. |
[7] | Hishikawa Y;Tsuda S;Nakamura N et al.Device-quality wide-gap hydrogenated amorphous silicon films deposited by plasma chemical vapor deposition at low substrate temperatures[J].Journal of Applied Physics,1991,69(01):508-510. |
[8] | Chen GH;Zhu XH;Yin SY;Hu YH;Zhang WL .Improvement on the conventional MWECR-CVD system and preparation of hydrogenated amorphous silicon films[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2005(3):355-358. |
[9] | Goncalves C.;Charvet S.;Zeinert A.;Clin M.;Zellama K. .Nanocrystalline silicon thin films prepared by radiofrequency magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(0):91-96. |
[10] | 罗士雨,冯磊,汪洪,林辉,滕浩,黄涛华,周圣明.非晶硅薄膜制备及其晶化特性研究[J].人工晶体学报,2008(05):1191-1194. |
[11] | Tarui H;Kishi Y;Nakamura N et al.On P layers for high efficiency amorphous silicon solar cells[J].Solar Energy Materials,1991,23(2-4):227-238. |
[12] | Ke Tao;Dexian Zhang;Jingfang Zhao;Linshen Wang;Hongkun Cai;Yun Sun .Low temperature deposition of boron-doped microcrystalline Si:H thin film and its application in silicon based thin film solar cells[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2010(6/8):299-303. |
[13] | 钱祥忠.硼轻掺杂对非晶硅薄膜光电性能的影响[J].光电子技术,2004(02):93-95,103. |
[14] | Chattopadhyay S;Das D .Efficient boron incorporation in hydrogenated amorphous silicon films by a novel combination of rf glow discharge technique and heated filament[J].Japanese Journal of Applied Physics,1995,34(10):5743-5748. |
[15] | Fedders PA.;Drabold DA. .Simulations of boron doping in a-Si : H[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1998(Pt.A):376-379. |
[16] | 何宇亮;陈光华;张仿清.非晶态半导体物理学[M].北京:高等教育出版社,1989:284-292. |
[17] | 汪昌州,杨仕娥,卢景霄.硅基薄膜太阳电池窗口材料的研究进展[J].材料导报,2007(01):14-17. |
[18] | P. Delli Veneri;L.V. Mercaldo;C. Minarini;C. Privato .VHF PECVD microcrystalline silicon: from material to solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(3):269-273. |
[19] | Yamasaki S;Matsuda A;Tanaka K .Anomalous optical and structural properties of B-doped a-Si∶H[J].Japanese Journal of Applied Physics,1982,21(12):789-791. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%