锌在SO_2污染环境中的腐蚀规律王振尧,郑逸苹,刘寿荣(中国科学院金属腐蚀与防护研究所沈阳110015)1前言在我国西南地区,由于地理环境的影响,酸沉降日趋严重.含硫煤燃烧所排放的SO2造成雨水酸化,酸沉降引起的腐蚀问题受到人们关注.因此,在该地区进行材料的腐蚀研究具有重要的现实意义.SO。在高湿条件下对大多数金属和合金有强烈的加速腐蚀作用[1].Sherry等[2-4]就高湿条件下低浓度SO....
The corrosion process of zinc in Guiyang and Huitong areas and under the condition of high concentration of SO2 can be described by a formula: △W = Ktn, where △W stands for weight loss, t represents duration of expose, while n and K are constats. The greater the pollution of SO2 and the relative humidity, the more serious the corrosion of zinc. The X-ray diffraction data show that, the corrosion product is mainly composed of sulfates of zinc. The corrosion productproduct formed in SO2-containing environment hinder anodic process of zinc corrosion.
参考文献
[1] | GraneseSL,RosalesBM,FernandezA.Pro.11thInt.Corrosion,Florence,1990,2:2.71—2.782SherryBS,JohnsonJB,WoodGC.CorrosionScience,1988,28:6573SherryBS,JohnsonJB,WoodGC.CorrosionScience,1988,28:6974SkerryBS,JohnsonJB,WoodGC.CorrosionScience,1988,28:7215BiedekT.Atmosphericcorrosion,ed.AilorWH.NewYork:JohaWily,1982.p6316SpenceJW,etal.Advancedlaboratoryandfieldexposuresystemsfortestingmaterials,ASTMSTP1000,ASTM1990.p191-207 |
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