考察纯镁浸泡于模拟体液(SBF)中所发生的化学和物理过程,实验材料为扩散退火态,浸泡时间3~21 d.结果发现,镁的腐蚀速率随时间增加而降低,同时溶液pH递增;裂纹和腐蚀坑是材料损伤的主要形貌特征,而MgCl2的局部富积是形成腐蚀坑的重要原因;随着浸泡时间延长,Mg(OH)2沉积于试样表面并逐步增长,成为Ca、P在Mg表面沉积的屏障,因此抑制Mg(OH)2的形成和生长是诱导磷酸钙陶瓷在Mg表面沉积的必要条件.
参考文献
[1] | Zartner P;Cesnjevar R;Singer H;Weyand M .First successful implantation of a biodegradable metal stent into the left pulmonary artery of a preterm baby.[J].Catheterization and cardiovascular interventions: Official journal of the Society for Cardiac Angiography & Interventions,2005(4):590-594. |
[2] | Schranz D;Zartner P;Michel Behnke I;Akinturk H .Bioabsorbable metal stents for percutaneous treatment of critical recoarctation of the aorta in a newborn.[J].Catheterization and cardiovascular interventions: Official journal of the Society for Cardiac Angiography & Interventions,2006(5):671-673. |
[3] | Di Mario C;Griffiths H;Goktekin O;Peeters N;Verbist J;Bosiers M;Deloose K;Heublein B;Rohde R;Kasese V;Ilsley C;Erbel R .Drug-eluting bioabsorbable magnesium stent.[J].Journal of interventional cardiology,2004(6):391-395. |
[4] | Witte F;Kaese V;Haferkamp H;Switzer E;Meyer Lindenberg A;Wirth CJ;Windhagen H .In vivo corrosion of four magnesium alloys and the associated bone response.[J].Biomaterials,2005(17):3557-3563. |
[5] | Staiger MP;Pietak AM;Huadmai J;Dias G .Magnesium and its alloys as orthopedic biomaterials: A review[J].Biomaterials,2006(9):1728-1734. |
[6] | Witte F;Fischer J;Nellesen J;Crostack HA;Kaese V;Pisch A;Beckmann F;Windhagen H .In vitro and in vivo corrosion measurements of magnesium alloys[J].Biomaterials,2006(7):1013-1018. |
[7] | 任伊宾,黄晶晶,杨柯,张炳春,姚治铭,王浩.纯镁的生物腐蚀研究[J].金属学报,2005(11):1228-1232. |
[8] | 宋光铃,宋诗哲.镁在人体模拟液中的腐蚀行为[J].物理化学学报,2006(10):1222-1226. |
[9] | Kokubo T;Takadama H .How useful is SBF in predicting in vivo bone bioactivity?[J].Biomaterials,2006(15):2907-2915. |
[10] | ASTM-G31-1972.ASTM-G31-1972.Standard Practice for Laboratory Immersion Corrosion Testing of Metals[S]. |
[11] | Song G L;Atrens A .Understanding magnesium corrosion-A framework for improved alloy performance[J].Advanced Engineering Materials,2004,5(12):837-858. |
[12] | Baril G;Galicia G;Deslouis C;Pebere N;Tribollet B;Vivier V .An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions[J].Journal of the Electrochemical Society,2007(2):C108-C113. |
[13] | Song G L;Atrens A;Stjohn D;Nairn J Lit Y .The electrochemical corrosion of pure magnesium in 1 N NaCl[J].Corrosion Science,1997,39(05):855-875. |
[14] | E. Slavcheva;G. Petkova;P. Andreev .Inhibition of corrosion of AZ91 magnesium alloy in ethylene glycol solution in presence of chloride anions[J].Materials and Corrosion,2005(2):83-87. |
[15] | Ambat R.;Zhou W.;Aung NN. .Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy[J].Journal of Applied Electrochemistry,2000(7):865-874. |
[16] | Song G L;Atrens A;Wu X L;Zhang B .Corrosion behaviour of AZ21,AZ501 And AZ91 in sodium chloride[J].Corrosion Science,1998,40(10):1769-1791. |
[17] | Li LC;Gao JC;Wang Y .Evaluation of cyto-toxicity and corrosion behavior of alkali-heat-treated magnesium in simulated body fluid[J].Surface & Coatings Technology,2004(1):92-98. |
[18] | Vereecke G .Calculation of the solubility diagrams in the system Ca(OH)2-H3PO4-KOH-CO2-H2O[J].Journal of Crystal Growth,1990,104(04):820-832. |
[19] | TenHuisen K S;Brown P W .Effects of magnesium on the formation of calcium-deficient hydroxyapatite from CaHPO4-2H2O and Ca4(PO4)2O[J].Journal of Biomedical Materials Research,1997,36(03):306-314. |
[20] | Abbona F.;Baronnet A. .A XRD AND TEM STUDY ON THE TRANSFORMATION OF AMORPHOUS CALCIUM PHOSPHATE IN THE PRESENCE OF MAGNESIUM[J].Journal of Crystal Growth,1996(1/2):98-105. |
[21] | Barrere F;Layrolle P;van Blitterswijk C A;de Groot K .Biomimetic calcium phosphate coatings on ti6al4v:A crystal growth study of octacalcium phosphate and inhibition by Mg2+ and[J].Bone,1999,25(02):107S-111S. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%