掺有过渡金属氧化物的氧化铁系统陶瓷在不同温度下烧结,如CuO-Fe2O3和ZnO-Fe2O3系统,形成α-Fe2O3和含有铁空位的尖晶石晶相.材料对还原气体具有显著的气敏性.尖晶石相和其中的铁空位浓度随组成和烧结温度而变化.文章认为材料的气敏性因铁空位而产生,并随铁空位浓度增加灵敏度上升.
The ferric oaide system with transition metal oxides such as CuO-Fe2O3 and ZnO-Fe2O3, were Sintered at different temperatures and formed a porous ceramic with a-Fe2O3 and spinel crystal phases. This ceramic possesses a remarked sensitivity to reductive gases. The special property is considered to relate to the ferric vacancy coccentration in a spinel phase. The ferric vacancy concentration varies with composition and heating temperature. The gas sensitivity can be improved by the increment of the ferric vacancy concentration.
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