The effects of boron on the solidification behaviors of Ti45AlxB alloys were studied by high temperature samples. These samples were melted at 1823 K, followed by cooling to the designated temperature, and then quickly water-quenched to preserve the solidification features. Optical microscopy and scanning electron microscopy analysis shows that the solidus temperature of Ti45AI was really reduced by 20 K when adding 0.8 at. pct B, and it was also observed that boride precipitated before the appearance of β phase. Besides, solidification structure confirmed that B addition does not obviously refine β phase, α grain refinement by certain amount of B in alloy probably clarifies the mechanism of B refining lamellar microstructure at room temperature.
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