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聚酰亚胺(PI)材料具有介电常数低,分解温度高及化学稳定性好等优点,是很有前途的电子封装材料.Cu具有低的电阻和高的抗电迁移能力,是PI基板金属化的首选材料.采用物理气相沉积(PVD)方法在PI基板上沉积Cu薄膜,利用TiN陶瓷薄膜阻挡Cu向PI基板内部扩散.研究热处理条件下TiN陶瓷薄膜阻挡层的阻挡效果、Cu膜电阻变化以及Cu膜的结合强度,俄歇谱图分析表明TiN可以有效地阻挡Cu向PI内的扩散.300℃热处理消除了Cu膜内应力,提高了Cu膜的结合强度.

参考文献

[1] Tummala R R.Microelectronics Packaging Handbook[M].Boston:Kluwer Academic Publishers,2000:165-207.
[2] Doppelt P .Copper CVD Precursors and Process for Advanced Metallization[J].Microelectronic Engineering,1997,37/38:89-95.
[3] S. Kim;J. -M. Park;D. -J. Choi .The carrier gas and surface passivation effects on selectivity in chemical vapor deposition of copper films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(1):95-102.
[4] 黄鹤,朱晓东,徐可为,何家文.PCVD TiN膜的界面制备及性能[J].稀有金属材料与工程,1999(06):395-397.
[5] 黄鹤,王学刚,朱晓东,陈华,何家文.离子束辅助磁控溅射沉积TiN薄膜的研究[J].稀有金属材料与工程,2002(03):205-208.
[6] Laurila T .Tantalum Carbide and Nitride Diffusion Barriers for Cu Metallization[J].Microelectronic Engineering,2002,60:71-80.
[7] P. Motte;M. Swaanen;J. Torres .Damascene test structures for the evaluation of barrier layer performance against copper diffusion[J].Microelectronic engineering,2001(1/4):291-296.
[8] Kim Dong Jin .Application of ALE TIN Films as Cu/Si Diffusion Barriers[J].Thin Solid Films,2000,372:276-283.
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