在AZ31表面磁控溅射单层纳米Al2O3涂层,用FESEM、TEM、XRD等分析涂层的形貌和结构,用电化学工作站和摩擦磨损实验研究了涂层的耐蚀和耐磨性能.结果表明,磁控溅射获得了界面结合良好的单层致密的纳米AlO3陶瓷涂层,在3.5%(质量分数)NaC1溶液中腐蚀电位从-1.812V提高到了-1.298V,电流密度从2.009×10-4A/cm2下降到了6.792×10-6A/cm2;摩擦系数从0.21下降到了0.15,磨痕从841窄化为400μm.综上所述,磁控溅射单层纳米Al2O3涂层显著地改善了镁合金的耐腐蚀和耐磨损性能.
参考文献
[1] | J.E. Gray;B. Luan .Protective coatings on magnesium and its alloys-a critical review[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):88-113. |
[2] | 高正源,潘复生.镁合金表面功能涂层制备与界面表征技术的研究进展[J].功能材料,2012(14):1817-1821,1824. |
[3] | A.F. Galio;S.V. Lamaka;M.L. Zheludkevich;L.F.P. Dick;I.L. Mller;M.G.S. Ferreira .Inhibitor-doped sol–gel coatings for corrosion protection of magnesium alloy AZ31[J].Surface & Coatings Technology,2010(9/10):1479-1486. |
[4] | Lei, T.;Ouyang, C.;Tang, W.;Li, L.-F.;Zhou, L.-S. .Preparation of MgO coatings on magnesium alloys for corrosion protection[J].Surface & Coatings Technology,2010(23):3798-3803. |
[5] | López, A.J.;Rams, J.;Ure?a, A. .Sol-gel coatings of low sintering temperature for corrosion protection of ZE41 magnesium alloy[J].Surface & Coatings Technology,2011(17/18):4183-4191. |
[6] | Rosero-Navarro, N.C.;Curioni, M.;Castro, Y.;Aparicio, M.;Thompson, G.;Durán, A. .Glass-like CexOy sol-gel coatings for corrosion protection of aluminium and magnesium alloys[J].Surface & Coatings Technology,2011(2/3):257-264. |
[7] | Wu, G.;Dai, W.;Zheng, H.;Wang, A. .Improving wear resistance and corrosion resistance of AZ31 magnesium alloy by DLC/AlN/Al coating[J].Surface & Coatings Technology,2010(7):2067-2073. |
[8] | Iranipour, N.;Azari Khosroshahi, R.;Parvini Ahmadi, N. .A study on the electroless Ni-P deposition on WE43 magnesium alloy[J].Surface & Coatings Technology,2010(7):2281-2286. |
[9] | Ko, Y.G.;Namgung, S.;Shin, D.H. .Correlation between KOH concentration and surface properties of AZ91 magnesium alloy coated by plasma electrolytic oxidation[J].Surface & Coatings Technology,2010(7):2525-2531. |
[10] | M. Feinaeugle;A.P. Alloncle;Ph. Delaporte;C.L Sones;R.W. Eason .Time-resolved shadowgraph imaging of femtosecond laser-induced forward transfer of solid materials[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(22):8475-8483. |
[11] | Hamdy, AS;Farahat, M .Chrome-free zirconia-based protective coatings for magnesium alloys[J].Surface & Coatings Technology,2010(16/17):2834-2840. |
[12] | Mosia(l)ek M;Mordarski G;Nowak P et al.Phosphatepermanganate conversion coatings on the AZ31 magnesium alloy:SEM,EIS and XPS studies[J].Surface and Coatings Technology,2011,206(01):51-62. |
[13] | Mandelli, A.;Bestetti, M.;Da Forno, A.;Lecis, N.;Trasatti, S.P.;Trueba, M. .A composite coating for corrosion protection of AM60B magnesium alloy[J].Surface & Coatings Technology,2011(19):4459-4465. |
[14] | Uematsu, Y.;Kakiuchi, T.;Teratani, T.;Harada, Y.;Tokaji, K. .Improvement of corrosion fatigue strength of magnesium alloy by multilayer diamond-like carbon coatings[J].Surface & Coatings Technology,2011(8/9):2778-2784. |
[15] | Long, Y.;Javed, A.;Shapiro, I.;Chen, Z.-K.;Xiong, X.;Xiao, P. .The effect of substrate position on the microstructure and mechanical properties of SiC coatings on carbon/carbon composites[J].Surface & Coatings Technology,2011(2/3):568-574. |
[16] | Jianning Ding;Yonggang Meng;Shizhu Wen .Mechanical properties and fracture toughness of multilayer hard coatings using nanoindentation[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2000(1/2):178-182. |
[17] | Roest, R.;Latella, B.A.;Heness, G.;Ben-Nissan, B. .Adhesion of sol-gel derived hydroxyapatite nanocoatings on anodised pure titanium and titanium (Ti6Al4V) alloy substrates[J].Surface & Coatings Technology,2011(11):3520-3529. |
[18] | Lu Lei;Shen Yongfeng;Chen Xianhua et al.Ultrahigh strength and high electrical conductivity in copper[J].Science,2004,304(5669):422-426. |
[19] | S. Yugeswaran;A.Kobayashi;K. Suresh;K.P. Rao;B. Subramanian .Wear behavior of gas tunnel type plasma sprayed Zr-based metallic glass composite coatings[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(22):8460-8468. |
[20] | 高正源,潘复生.AZ31镁合金表面纳米陶瓷涂层的组织与力学性能分析[J].重庆大学学报:自然科学版,2012(07):67-71. |
[21] | Chang Jianwei;Fu Penghuai;Guo Xingwu et al.The effects of heat treatment and zirconium on the corrosion behaviour of Mg3Nd0.2Zn0.4Zr (wt%) alloy[J].Corrosion Science,2007,49(06):2612-2627. |
[22] | Xing-Wu Guo;Jian-Wei Chang;Shang-Ming He;Wen-Jiang Ding;Xishu Wang .Investigation of corrosion behaviors of Mg-6Gd-3Y-0.4Zr alloy in NaCl aqueous solutions[J].Electrochimica Acta,2007(7):2570-2579. |
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