以二乙醇胺、甲基丙烯酸十三氟辛酯为原料,通过迈克尔加成反应合成一种含氟二元醇(F-DEA),并以此为含氟单体,通过缩合共聚的方法与异佛尔酮二异氰酸酯(IPDI)、聚四亚甲基醚二醇(PTMG-1000)、N-甲基二乙醇胺(MDEA)以及季戊四醇三丙烯酸酯(PETA)反应合成一种阳离子型水性UV固化含氟聚氨酯树脂.利用FT-IR、1H-NMR等手段对产物的分子结构进行表征.采用粒径分析、接触角、X射线光电子能谱(XPS)以及各种性能测试手段,对乳液、光固化过程及涂膜性能进行分析研究.结果表明:在一定条件下,该树脂能稳定分散在水中,随着含氟量的增加,乳液粒径增大,但光固化效率有所降低,同时热处理后的氟碳链迁移至涂膜表面,所得的光固化涂膜各种性能较好,特别是耐水和耐酸碱性有明显改善.
参考文献
| [1] | Xu, D;Wu, K;Zhang, QH;Hu, HY;Xi, K;Chen, QM;Yu, XH;Chen, JN;Jia, XD .Synthesis and biocompatibility of anionic polyurethane nanoparticles coated with adsorbed chitosan[J].Polymer: The International Journal for the Science and Technology of Polymers,2010(9):1926-1933. |
| [2] | Xu, H.;Qiu, F.;Wang, Y.;Wu, W.;Yang, D.;Guo, Q. .UV-curable waterborne polyurethane-acrylate: Preparation, characterization and properties[J].Progress in Organic Coatings: An International Review Journal,2012(1):47-53. |
| [3] | Czech, Z;Pelech, R .Thermal decomposition of polyurethane pressure-sensitive adhesives dispersions[J].Progress in Organic Coatings: An International Review Journal,2010(1):72-75. |
| [4] | Jeong EH;Yang J;Hong JH;Kim TG;Kim JH;Youk JH .Effective preparation of montmorillonite/polyurethane nanocomposites by introducing cationic groups into the polyurethane main chain[J].European Polymer Journal,2007(6):2286-2291. |
| [5] | EMIL C BURUIANA;TINCA BURUIANA .Synthesis and characterization of novel polyurethane cationomers with dipeptide sequences and alkylammonium groups[J].Journal of Biomaterials Science,2004,6(15):781-795. |
| [6] | Lu, Y.;Larock, R.C. .Soybean oil-based, aqueous cationic polyurethane dispersions: Synthesis and properties[J].Progress in Organic Coatings: An International Review Journal,2010(1):31-37. |
| [7] | Scrinzi, E.;Rossi, S.;Deflorian, F.;Zanella, C. .Evaluation of aesthetic durability of waterborne polyurethane coatings applied on wood for interior applications[J].Progress in Organic Coatings: An International Review Journal,2011(1/2):81-87. |
| [8] | Guo, Y.-H.;Guo, J.-J.;Li, S.-C.;Li, X.;Wang, G.-S.;Huang, Z..Properties and paper sizing application of waterborne polyurethane emulsions synthesized with TDI and IPDI[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2013:53-61. |
| [9] | García-Pacios, V.;Costa, V.;Colera, M.;Martín-Martínez, J.M. .Waterborne polyurethane dispersions obtained with polycarbonate of hexanediol intended for use as coatings[J].Progress in Organic Coatings: An International Review Journal,2011(2):136-146. |
| [10] | Zubielewicz, M;Krolikowska, A .The influence of ageing of epoxy coatings on adhesion of polyurethane topcoats and protective properties of coating systems[J].Progress in Organic Coatings: An International Review Journal,2009(2):129-136. |
| [11] | Guo, Y.-H.;Li, S.-C.;Wang, G.-S.;Ma, W.;Huang, Z. .Waterborne polyurethane/poly(n-butyl acrylate-styrene) hybrid emulsions: Particle formation, film properties, and application[J].Progress in Organic Coatings: An International Review Journal,2012(1):248-256. |
| [12] | Naghash, H.J.;Abili, B. .Synthesis of a silicone containing allylic monomer and its uses in the waterborne polyurethane/vinyl acetate-acrylic hybrid emulsion copolymers[J].Progress in Organic Coatings: An International Review Journal,2010(4):486-494. |
| [13] | Wetzel, C.;Sch?nfelder, J.;Schwarz, W.;Funk, R.H.W. .Surface modification of polyurethane and silicone for therapeutic medical technics by means of electron beam[J].Surface & Coatings Technology,2010(5):1618-1623. |
| [14] | 蒋海林 .光固化水性含氟聚氨酯-丙烯酸酯树脂涂料的制备与研究[D].广东工业大学,2012. |
| [15] | Liu, T.;Pan, X.;Wu, Y.;Zhang, T.;Zheng, Z.;Ding, X.;Peng, Y. .Synthesis and characterization of UV-curable waterborne polyurethane acrylate possessing perfluorooctanoate side-chains[J].Journal of Polymer Research,2012(2):9741-1-9741-8. |
| [16] | Kaewpirom, S.;Kunwong, D. .Curing behavior and cured film performance of easy-to-clean UV-curable coatings based on hybrid urethane acrylate oligomers[J].Journal of Polymer Research,2012(11):9995-1-9995-12. |
| [17] | Jian-Feng Cai;Zhi Guan;Yan-Hong He .The lipase-catalyzed asymmetric C-C Michael addition[J].Journal of molecular catalysis, B. Enzymatic,2011(3/4):240-244. |
| [18] | SEO S W;KIM S J .Enantioselective organocatalytic Michael addition of 2-arylacetates and 2-arylacetonitriles having an electron-withdrawing group to α,3-unsaturated aldehydes[J].Tetrahedron Letters,2012,53(23):2809-2812. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%