采用快速凝固气体雾化工艺制备Al-27%Si合金粉末,研究合金粉末形貌和热处理对组织的影响,利用X射线衍射仪和显微硬度计等对Al-27%Si合金粉末中硅相的析出与长大进行表征。结果表明:快速凝固Al-27%Si合金粉末由基体α(Al)相、块状β-Si 相和枝晶状共晶硅相组成;经热处理后,β-Si相发生粗化,共晶硅相逐渐转变为块状相且发生粗化;在500℃下加热保温后,α(Al)相和β-Si相的衍射峰强度随时间延长而增大,α(Al)相衍射峰向低角度偏移;合金粉末显微硬度在500℃下加热,初期有下降趋势,但随时间延长,不再下降,而是维持相对稳定。
The rapidly solidified powders of Al-27%Si alloy were manufactured by gas atomization process. The effects of morphologies of alloy powders and heat treatment on the microstructure were studied. The precipitation and growth of silicon phase were investigated with X-ray diffractometer and microscope hardness tester. The results show that the rapidly solidified powders of Al-27%Si alloy are composed of α(Al) phase, β-Si bulk phase and dendritic structure eutectic silicon phase. After heat treatment, theβ-Si bulk phase is coarsened and the eutectic silicon phase is changed to bulk phase and then coarsens. When held at 500℃, the diffraction peak intensities of theα(Al) phase andβ-Si phase are enhanced with the time prolonging, and the position of theα(Al) phase peak shifts to lower angle. At the beginning of heat treatment at 500℃, the microhardness of the alloy powers decreases, followed by remaining relatively constant as the time prolonging.
参考文献
[1] | 解立川,彭超群,王日初,王小锋,蔡志勇,刘兵.高硅铝合金电子封装材料研究进展[J].中国有色金属学报,2012(09):2578-2587. |
[2] | 刘正春,王志法,姜国圣.金属基电子封装材料进展[J].兵器材料科学与工程,2001(02):49-53. |
[3] | 余琨,李少君,陈立三,赵为上,李鹏飞.电子封装材料过共晶硅-铝合金的组织特征和热性能[J].中国有色金属学报(英文版),2012(06):1412-1417. |
[4] | Seung Chae Yoon;Soon-Jik Hong;Sun Ig Hong;Hyoung Seop Kim .Mechanical properties of equal channel angular pressed powder extrudates of a rapidly solidified hypereutectic Al-20 wt% Si alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1/2):966-970. |
[5] | 俞佳,姚继蓬,郦剑.快速凝固/粉末冶金高硅铝合金的研究进展[J].热处理技术与装备,2008(02):4-7. |
[6] | Dinda, G.P.;Dasgupta, A.K.;Mazumder, J. .Evolution of microstructure in laser deposited Al-11.28%Si alloy[J].Surface & Coatings Technology,2012(8/9):2152-2160. |
[7] | 谢壮德,沈军,董寅生,周彼德,李庆春.快速凝固铝硅合金的制备、组织特征及断裂行为[J].粉末冶金技术,2000(02):111-116. |
[8] | 赵爱民,毛卫民,甄子胜,姜春梅,钟雪友.冷却速度对过共晶铝硅合金凝固组织和耐磨性能的影响[J].中国有色金属学报,2001(05):827-833. |
[9] | 甘卫平,陈招科,杨伏良,周兆锋.高硅铝合金轻质电子封装材料研究现状及进展[J].材料导报,2004(06):79-82. |
[10] | Srivastava VC.;Ojha SN.;Mandal RK. .Microstructure and mechanical properties of Al-Si alloys produced by spray forming process[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(0):555-558. |
[11] | ZHOU J;DUSZCAYK J;KOREVAAR B M .As-spray-deposited structure of an Al-20Si-5Fe spray perform and its development during subsequent processing[J].Journal of Materials Science,1991,26:5275-5291. |
[12] | 杨伏良,甘卫平,陈招科,刘泓.快速凝固/粉末冶金制备高硅铝合金材料的组织与力学性能[J].中国有色金属学报,2004(10):1717-1722. |
[13] | LAVERNIA E J;AYERS J D;SRIVATSAN T S .Rapid solidification processing with specific application to aluminum alloys[J].International Materials Reviews,1992,37(01):1-44. |
[14] | 李元元;张大童;夏伟 .高压水雾化法制备的高硅铝合金粉末特性[J].金属学报,1998,34(01):95-99. |
[15] | 谢壮德,沈军,孙剑飞,周彼德,李庆春.超音速气雾化高硅铝合金粉末高温加热组织及性能演变[J].粉末冶金技术,2002(04):205-208. |
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