近年来,研究人员发现过渡金属掺杂尖晶石材料LiMxMn2-xO4(M=Ni,Co,Cr,Cu,Fe,Al),放电平台可以达到5V左右.在这些材料中,由于LiNi0.5Mn1.5O4具有相对较高的容量,放电平台维持在4.7V,而备受关注.但是LiNi0.5 Mn1.5O4仍然存在结构不稳定、容量衰减比较严重等问题,研究人员通过掺杂金属离子或者取代部分氧来提高材料性能,以及通过包覆来减少材料与电解液的接触.综述了近年来为进一步提高LiNi0.5Mn1.5O4电化学性能而对其进行改性的一些研究成果.
参考文献
| [1] | 文衍宣,童张法,蒙丽丽.锂离子电池高电位正极材料的研究进展[J].中国锰业,2004(02):17-21. |
| [2] | 陈前火,童庆松,连锦明.5 V锂离子电池正极材料的制备和电化学性能研究[J].吉林化工学院学报,2003(03):5-9. |
| [3] | 叶乃清,刘长久,沈上越.锂离子电池正极材料LiNiO2存在的问题与解决办法[J].无机材料学报,2004(06):1217-1224. |
| [4] | 陈召勇,肖劲,朱华丽,刘业翔.不同原料对Li-Ni-Mn-O 5 V正极材料的结构和性能的影响[J].无机化学学报,2005(09):1417-1421. |
| [5] | 唐致远;胡冉;王雷 .[J].化工进展,2005,25(09):31. |
| [6] | Kiyoshi Kanamura .[J].Wataru Hoshikawm Solid State Ionics,2006,177:113. |
| [7] | Hiroo Kawai;Mikito Nagata;Hisashi Tukamoto .High-voltage lithium cathode materials[J].Journal of Power Sources,1999(0):67-72. |
| [8] | Yasushi Idemoto;Hirosuke Narai;Nobuyuki Koura .Crystal structure and cathode performance dependence on oxygen content of LiMn_(1.5)Ni_(0.5)O_4 as a cathode material for secondary lithium batteries[J].Journal of Power Sources,2003(119/121):125-129. |
| [9] | Sang-Ho Park;Yang-Kook Sun .Synthesis and electrochemical properties of 5 V spinel LiNi{sub}0.5Mn{sub}1.5O{sub}4 cathode materials prepared by ultrasonic spray pyrolysis method[J].Electrochimica Acta,2004(2/3):431-434. |
| [10] | Kiyoshi Kanamura;Wataru Hoshikawa;Takao Umegaki .[J].J The Electrochemical Soc,2002,149(03):A339. |
| [11] | Boris Markovsky;Yosef Talyossef;Gregory Salitra;Doron Aurbach;Hyeong-Jin Kim;Seungdon Choi .Cycling and storage performance at elevated temperatures of LiNi_(0.5)Mn_(1.5)O_4 positive electrodes for advanced 5 V Li-ion batteries[J].Electrochemistry communications,2004(8):821-826. |
| [12] | Caballero A;Heman L et al.[J].J E1ectrochem Soc,2005,152:A6. |
| [13] | Fang Haisheng;Wang Zhixing;Li Xinhai et al.[J].Journal of Power Sources,2006,153:174. |
| [14] | Schwenzel J;Thangadurai V;Weppner W .[J].Journal of Power Sources,2006,154:232. |
| [15] | Ali Eftekhari .[J].J Powar Sources,2003,124:182. |
| [16] | Kima J H;Myungb S T;Sun Y K .[J].Electrochimica Acta,2004,49:219. |
| [17] | Tsutomu Ohzuku;Sachio Takeda .[J].Masato Iwanagm Power Sources,1999,81-82:90. |
| [18] | Ooms FGB.;Kelder EM.;Schoonman J.;Wagemaker M.;Mulder FM. .High-voltage LiMg delta Ni0.5-delta Mn1.5O4 spinels for Li-ion batteries[J].Solid state ionics,2002(Pt.A):143-153. |
| [19] | Shiro Seki;Yo Kobayashi;Hajime Miyashiro et al.[J].Journal of the Electrochemical Society,2006,153(06):A1073. |
| [20] | George Ting-Kuo Fey;Lu Chengzkhang;Prem Kumar T .[J].Journal of Power Sources,2003,115:332. |
| [21] | Pérez Vicente C;Lloris J M;Tirado J L .[J].Electrochimica Acta,2004,49:1963. |
| [22] | Alca'ntara;Jaraba M;Lavela P et al.[J].Journal of the Electrochemical Society,2005,152(01):A13. |
| [23] | Ki-Joo Hong;Yang-Kook Sun .[J].Journal of Power Sources,2002,109:427. |
| [24] | Arunkumar T A;Manthiram A .[J].Electrochimica Acta,2005,50:5568. |
| [25] | Alca'ntara R;Jaraba M;Lavela P et al.[J].Electrochimica Acta,2002,47:1829. |
| [26] | Sung-Woo Oh;Sang-Ho Park;Jung-Hyun Kim .Improvement of electrochemical properties of LiNi_(0.5)Mn_(1.5)O_4 spinel material by fluorine substitution[J].Journal of Power Sources,2006(1):464-470. |
| [27] | Sun Y K;Yoon C S;Oh I H .[J].Electrochimica Acta,2003,48:503. |
| [28] | Sun Y K;Lee Y S;Yoshio M et al.[J].Electrochemical and Solid-State Letters,2002,5(05):A99. |
| [29] | Rojas R M;Amarilla J M;Pascual L et al.[J].Journal of Power Sources,2006,160:529. |
| [30] | Hwang B J;Santhanam R;Liu D G .[J].Journal of Power Sources,2006,101:86. |
| [31] | Yair Ein-Eli;John T. Vaughey;Michael M. Thackeray;Sanjeev Mukerjee;Xiao Q. Yang;James McBreen .LiNi{sub}xCu{sub}(0.5-x)Mn{sub}1.5O{sub}4 spinel electrodes, superior high-potential cathode materials for Li Batteries I. electrochemical and structural studies[J].Journal of the Electrochemical Society,1999(3):908-913. |
| [32] | Molenda J;Palubiak D;Marzec J .[J].Journal of Power Sources,2005,144:176. |
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