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The experimental research on refining slag systems for ultra-low sulphur steel was carried out in a 10 kg induction furnace. It was proved that sulphur element in molten steel can be removed to less than 5×10-6 by adding CaO-Al2O3-SiO2-MgO-CaF2 slag on the surface of molten steel and feeding CaO-BaO-CaF2 wire into molten steel. And Ls, which is the coefficient of sulphur between slag and molten steel, that is ω(S)/ω[S], increases by increasing I (I=ωBaO/ωCaO). When I=5/3, Ls can be up to its maximum of 633. The CaSi is effective for deep desulphurization, especially when it is added to the slag of wire feeding.

参考文献

[1] Oguchi S;Robertson D G C .Kinetic Model for Refining by Submerged Power Injection:Part 1,Transitory and Permanent Contact Reactions[J].Ironmaking and Steelmaking,1984,11(03):262-267.
[2] Ma Jie .Study on Function of BaO-CaO-CaF2-CaCl2 Slag in Desulphurization of Molten Steel[J].上海金属,1996,18(05):16-20.
[3] Zhou Hong .Sulphur Distribution between CaO-Al2O3 Molten Slag Liquid Steel[J].Iron and Steel,1995,30(04):14-18.
[4] PATSIOGIANNIS Filippos .Incorporation of Sulphur in an Optimized Ladle Steelmaking Slag[J].ISIJ International,1996,25(06):402-408.
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