以含硼酚醛树脂为碳前驱体,通过溶剂挥发诱导自组装制备了含硼中孔炭.利用低温氮气吸脱附、小角X射线散射、透射电镜等分析手段对中孔炭样品进行了结构表征,并采用三电极体系对中孔炭样品进行了电化学性能测试.讨论了硼掺杂量对中孔炭的孔结构及电化学性能的影响.结果表明:随硼含量增加,中孔炭孔径缩小且有序度降低.硼质量分数为0.3%时,中孔炭在电流密度为75mA·g-1下的单位面积比电容达到0.51 F·m-2,是未掺杂样品的1.9倍,并且仍能够保持有序的孔道结构.
参考文献
[1] | A. G. Pandolfe;A. F. Hollenkamp .Carbon properties and their role in supercapacitors[J].Journal of Power Sources,2006(1):11-27. |
[2] | Hongliang Guo;Qiuming Gao .Boron And Nitrogen Co-doped Porous Carbon And Its Enhanced Properties As Supercapacitor[J].Journal of Power Sources,2009(2):551-556. |
[3] | Hidetaka Konno .High capacitance B/C/N composites for capacitor electrodes synthesized by a simple method[J].Journal of Power Sources,2010(6):1739. |
[4] | 司维江,周晋,邢伟,禚淑萍.孔径渐变的有序介孔炭的合成及电化学应用[J].无机化学学报,2010(10):1844-1850. |
[5] | 王大伟,李峰,刘敏,成会明.硝酸氧化改性SBA-15 模板合成的中孔炭电容性能研究[J].新型炭材料,2007(04):307-314. |
[6] | Wooyoung Kim;Ji Bong Joo;Namdong Kim .Preparation of nitrogen-doped mesoporous carbon nanopipes for the electrochemical double layer capacitor[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(5):1407-1411. |
[7] | Hulicova-Jurcakova, D;Puziy, AM;Poddubnaya, OI;Suarez-Garcia, F;Tascon, JMD;Lu, GQ .Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons[J].Journal of the American Chemical Society,2009(14):5026-5027. |
[8] | Yongde Xia;Robert Mokaya .Synthesis of Ordered Mesoporous Carbon and Nitrogen-Doped Carbon Materials with Graphitic Pore Walls via a Simple Chemical Vapor Deposition Method[J].Advanced Materials,2004(17):1553-1558. |
[9] | Abramovic BF.;Bjelica LJ.;Gaal FF.;Guzsvany VJ.;Jovanovic LS. .Some electrochemical characteristics of boron- and phosphorus-doped glassy carbon electrodes[J].Electroanalysis,2003(10):878-884. |
[10] | Ikuo Yanase;Riichi Ogawara;Hidehiko Kobayashi .Synthesis Of Boron Carbide Powder From Polyvinyl Borate Precursor[J].Materials Letters,2009(1):91-93. |
[11] | Ozaki J;Kimura N;Anahara T et al.Preparation and axygen reduction activity of BN-doped carbons[J].CARBO,2007,45:1847-1853. |
[12] | Kawaguchi M;Kawashima T .Synthesis of a new graphite-like layered material of composition BC3N[J].Journal of the Chemical Society,Chemical Communications,1993,21:1133-1134. |
[13] | Xiaochen Zhao;Aiqin Wang;Jingwang Yan .Synthesis and Electrochemical Performance of Heteroatom-incorporated Ordered Mesoporous Carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(19):5463-5473. |
[14] | Peng Li;Yan Song;Jingli Shi.Preparation and electrochemical properties of ordered mesoporous carbons with various pore structure[A].Japan:Beppu,2010 |
[15] | Yan Meng;Dong Gu;Fuqiang Zhang;Yifeng Shi;Haifeng Yang;Zheng Li;Chengzhong Yu;Bo Tu;Dongyuan Zhao .Ordered Mesoporous Polymers and Homologous Carbon Frameworks:Amphiphilic Surfactant Templating and Direct Transformation[J].Angewandte Chemie,2005(43):7053-7059. |
[16] | Brinker CJ.;Sellinger A.;Fan HY.;Lu YF. .Evaporation-induced self-assembly: Nanostructures made easy[J].Advanced Materials,1999(7):579-585. |
[17] | 孟岩 .有序的有机高分子介孔材料的合成与结构[D].复旦大学,2006. |
[18] | Da-Wei Wang;Feng Li;Zhi-Gang Chen .Synthesis and Electrochemical Property of Boron-Doped Mesoporous Carbon in Supercapacitor[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(22):7195-7200. |
[19] | 王玉乾,王兵,孟祥钦,甘孔银.掺硼对超纳米金刚石薄膜的影响[J].材料研究学报,2009(03):288-292. |
[20] | 王平平,薛锐生.活性碳/碳纳米管掺杂材料的制备及其有机双层电容器电极性能[J].科学技术与工程,2010(18):4419-4424. |
[21] | 郏建波.碳薄膜电极材料在电分析化学中的应用[J].化学进展,2007(11):1800-1805. |
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