采用碳纳米管改善纤维与基体间的界面结合,同时利用碳纳米管自身的优异性能对碳化硅纤维增强碳化硅复合材料(SiCf/SiC)进行二次增强.通过化学气相沉积工艺(CVD)在SiC纤维编织件内原位生长碳纳米管,优化碳纳米管原位生长过程中的碳源流量、反应温度和反应时间等工艺参数,对碳纳米管的原位生长工艺及机理进行系统分析,并结合先驱体浸渍裂解工艺(PIP)制备CNTs-SiCf/SiC复合材料,探讨原位生长碳纳米管的引入对复合材料力学性能的影响.结果表明,优化后的工艺参数如下:反应温度750℃,C2H2、H2和N2流量比1/1/3,C2H2流量100～150 mL/min,反应时间60 min;碳纳米管的引入使SiCf/SiC复合材料的弯曲强度、弯曲模量和断裂韧性分别提高了16.3％、90.4％和106.3％.
参考文献
| [1] | ALAIN L;PATRICK S;ALAIN A;ERIC B,GEORGES H.Ceramic matrix composites to make breakthroughs in aircraft engine performance[A].Palm Springs:American Institute of Aeronautics and Astronautics,Inc,2009:1-11. |
| [2] | DICARLO J A;YUN H M;MORSCHER G N;BHATT R T .SiC/SiC composites for 1 200 ℃ and above[R].Washington:NASA Center for AeroSpace Information,2004. |
| [3] | PAPPU L N M;NOEL N N;DAVID N B;SUBODH M .Probabilistic analysis of a SiC/SiC ceramic matrix composite turbine vane[R].Washington:NASA Center for AeroSpace Information,2004. |
| [4] | ROY R G;KASHALIKAR U K;MAJI A.Lightweight and cost-effective SiC optical structures[A].San Diego:American Institute of Aeronautics and Astronautics,Inc,2004:1-8. |
| [5] | 胡海峰,张玉娣,邹世钦,周新贵,张长瑞.SiC/SiC复合材料及其在航空发动机上的应用[J].航空制造技术,2010(06):90-91. |
| [6] | Katoh Y;Snead LL;Henager CH;Hasegawa A;Kohyama A;Riccardi B;Hegeman H .Current status and critical issues for development of SiC composites for fusion applications[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2007(a):659-671. |
| [7] | Kohyama A.;Abe K.;Muroga T.;Matsui H.;Jitsukawa S.;Matsuda S.;Seki M. .Interactions between fusion materials R&D and other technologies[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2000(Pt.A):20-27. |
| [8] | ZHAO S;ZHOU X G;YU H J;WANG H L WU Y C HUANG Q Y ZHU Z Q HUANG Z L .Compatibility of SiCf/SiC with LiPb at 700 ℃[J].Fusion Engineering and Design,2010,85:1624-1626. |
| [9] | Enrique J. Garcia;Brian L Wardle;A. John Hart;Namiko Yamamoto .Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown In Situ[J].Composites science and technology,2008(9):2034-2041. |
| [10] | MATHUR R B .Growth of caibon nanotubes on carbon fiber substrates to produce hybrid/pjenolic composites with improved mechanical properties[J].Computer Science and Technology,2008,68:1608-1615. |
| [11] | K.L. Kepple;G.P. Sariborn;P.A. Lacasse .Improved fracture toughness of carbon fiber composite functionalized with multi walled carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(15):2026-2033. |
| [12] | K.H. Hung;W.S. Kuo;T.H. Ko .Processing and tensile characterization of composites composed of carbon nanotube-grown carbon fibers[J].Composites, Part A. Applied science and manufacturing,2009(8):1299-1304. |
| [13] | Veedu VP;Cao AY;Li XS;Ma KG;Soldano C;Kar S;Ajayan PM;Ghasemi-Nejhad MN .Multifunctional composites using reinforced laminae with carbon-nanotube forests[J].Nature materials,2006(6):457-462. |
| [14] | Haipeng Li;Naiqin Zhao;Yuan Liu .Fabrication and properties of carbon nanotubes reinforced Fe/hydroxyapatite composites by in situ chemical vapor deposition[J].Composites. Part A, Applied science and manufacturing,2008(7):1128-1132. |
| [15] | 居艳,李凤仪,魏任重.镍基催化剂上催化裂解甲烷生长碳纳米管[J].合肥工业大学学报（自然科学版）,2004(12):1528-1531. |
| [16] | Porwal D;Mukhopadhyay K;Ram K;Mathur GN .Investigation of the synthesis strategy of CNTs from CCVD by thermal analysis[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2007(1/2):53-59. |
| [17] | HIURA H;EBBESEN T;TANIGAKI K;TAKAHASHI H .Raman studies of carbon nanotubes[J].Chemical Physics Letters,1993,202:509-512. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%