为了探讨时效制度及pH值对7003铝合金腐蚀类型与腐蚀性能的影响,采用慢应变速率拉伸试验(SSRT)、扫描电子显微镜(SEM)和动电位极化曲线,研究了峰时效(PA)、双峰时效(DPA)以及回归再时效(RRA)状态下的7003铝合金在不同pH值(4,7,11)的3.5 ％NaCl溶液中预浸泡脆化现象.结果表明:7003铝合金在不同pH值的腐蚀溶液中的腐蚀类型不同,在pH值为4时,铝合金在腐蚀介质中点蚀与全面腐蚀共同作用于试样表面,其中点蚀占主导作用;pH值为7时,点蚀控制整个腐蚀过程;而在pH值为11时,发生全面腐蚀;结合慢应变速率拉伸试验与断口形貌分析可知,随腐蚀介质pH值的不同,合金预浸泡脆化敏感性(Ipee)也随之产生变化,具体表现为Ipee(pH=4)＞Ipee(pH=11)＞Ipee(pH=7);7003铝合金时效状态对材料预浸泡脆化敏感性(Ipee)也有显著影响,表现为Ipee(PA)＞Ipee(DPA)＞Ipee(RRA).
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