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Nanosized amorphous TiO2 powders with a specific surface area of 501 m2•g-1 were prepared by hydrolysis. After calcined at 400 °C for 2 h, the prepared amorphous TiO2 powders were fully transformed into anatase crystallites with a specific surface area of 141 m2•g-1. Differential scanning calorimetric (DSC) experiments were performed on the samples of nanosized amorphous TiO2 mixed with microsized anatase, nanosized anatase, or nanosized α-Al2O3 respectively. Effects of sample packing, anatase addition, or α-Al2O3 addition on the crystallization behavior of nanosized amorphous TiO2 were analyzed.

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