利用开路电位和电化学阻抗谱研究09CuPCrNi-A耐大气腐蚀钢和F500L-Z普钢在3.5%NaCl溶液中的腐蚀行为.结果表明,随着浸泡时间的延长,试样的阻抗值先增大后减少,1272 h后趋于稳定;Bode图中曲线向低频方向移动,相位角曲线逐渐下降;09CuPCrNi-A耐大气腐蚀钢的耐腐蚀性优于普钢,表面锈层的生成和溶解是动态过程.
The corrosion behavior of a weathering steel 09CuPCrNi-A and a common steel F500L-Z in 3.5%NaCl solution was investigated by open circuit potential and electrochemical impedance spectrum(EIS) measurements.The results showed that the resistance of the steels increased first and then decreased with increasing soak time and tended to be steady after 1272 h. Bode charts indicated that the curves moved to low frequency and phase angle curves decreased gradually.Corrosion resistance of 09CuPCrNi-A was better than that of F500L-Z.
参考文献
[1] | Yamashita M, Miyuki H, Matsuda Y, et al. The long-term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a cen- tury[J]. Corros. Sci., 1994; 36: 283. |
[2] | Evas U R. Critical humidity for rusting in the presence of sea salt[J].Bri. Corros. J., 1974, 9(1): 26. |
[3] | 张万灵,刘建蓉.交流阻抗法对耐候钢腐蚀行为的研究[J].钢铁研究,1996,25(5):39. |
[4] | Mahdavian M, Attar M M. Another approach in analysis of paint coatings with EIS measurement: phase angle at high frequencies[J]. Corros. Sci., 2006, 48: 4152. |
[5] | Isao S. Recent evaluation of corrosion protective paint films by electrochemical methods[J]. Prog. Org. Coat., 1997, 31: 73. |
[6] | Ahmad R, Araman R. Morphology of rust formed on nat- urally weathered weathering steel bridge spans[J]. Prakt Met., 1986, 23: 223. |
[7] | 张全成,吴建生,郑文龙等.合金元素的二次分配对耐候钢抗大气腐蚀性能的影响[J].材料保护,2001,34:4. |
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