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以PR方程结合vdW混合法则,利用修正的二元交互作用系数kij差值模型,对HFC/HC三元混合工质进行了推算,并与文献给出的5种三元混合工质(HFC32/HFC125/HFC134a、HFC290/HC600a/HFC32、HFC125/HFC143a/HFC134a、HFC32/HC290/HFC227ea、HFC32/ HFC125/HC290)的实验值和REFPROP 8.0数据库中的12种三元混合工质(R404A、R407A、R407B、R407C、R407D、R407E、R417A、R422A、R422B、R422C、R422D、R425A)的计算值进行了对比验证,结果表明该模型具有较高的预测能力和计算精度,其中压力计算平均偏差为1.29%,组分计算平均偏差为0.0053.

参考文献

[1] Jian-Xin Chen;Peng Hu;Ze-Shao Chen .Study on the Interaction Coefficients in PR Equation with vdW Mixing Rules for HFC and HC Binary Mixtures[J].International Journal of Thermophysics,2008(6):1945-1953.
[2] Kobayashi M.;Nishiumi H. .Vapor-liquid equilibria for the pure, binary and ternary systems containing HFC32, HFC125 and HFC134a[J].Fluid Phase Equilibria,1998(1/2):191-202.
[3] Akasaka R;Higashi Y;Tanaka K;Kayukawa Y;Fujii K .Vapor-liquid equilibrium measurements and correlations for the binary mixture of difluoromethane plus isobutane and the ternary mixture of propane plus isobutane plus difluoromethane[J].Fluid Phase Equilibria,2007(1/2):286-291.
[4] Coquelet C;Chareton A;Richon D .Vapour-liquid equilibrium measurements and correlation of the difluoromethane (R32) plus propane (R290) plus 1,1,1,2,3, 3,3-heptafluoropropane (R227ea) ternary mixture at temperatures from 269.85 to 328.35 K[J].Fluid Phase Equilibria,2004(2):209-214.
[5] Hou, S.-X.;Duan, Y.-Y. .Vapor-liquid equilibrium measurement and modeling for the difluoromethane+pentafluoroethane+propane ternary mixture[J].Fluid Phase Equilibria,2010(1):106-112.
[6] 胡芃,高静轩,陈龙祥,陈则韶.PR方程结合vdW混合法则推算二元及三元HFC/HC混合工质汽液相平衡性质[J].化工学报,2012(02):350-355.
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