噻咯(silole音译)因具有独特的电子结构和光电性能,已成为近年来研究的热点.官能化噻咯作为重要的噻咯衍生物,不仅在有机合成领域占重要地位,而且是建构新型π共轭体系的重要组成部分.本文介绍了官能化噻咯的两种重要合成方法,即炔的内向-内向型分子内还原关环法和环内金属转换法,并对其特点、适用范围及发展方向作了分析和展望.
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