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采用双螺杆挤出机制备了聚丙烯(PP)/回收聚酯(PET),回收PET/相容剂和不同相容剂增容PP/回收PET共混物,研究了以上共混物的剪切黏度、剪切应力与剪切速率的关系.结果表明,PP剪切黏度随回收PET含量增加而降低,剪切速率越高,剪切黏度降低越明显,具有典型的剪切变稀特性.加入PP-g-MA能提高PP/回收PET共混物剪切黏度,但加入PP-g-GMA会降低PP/回收PET共混物剪切黏度.PP/回收PET共混物剪切应力随r-PET含量增加而降低.PP-g-MA使回收PET/PP共混物剪切应力增大,但PP-g-GMA使共混物剪切应力降低.

参考文献

[1] Natalie Zdrazilova;Berenika Hausnerova;Petr Saha;Takeshi Kitano .Rheological Behaviour of PP/PET and Modified PP/PET Blends.I.Steady State Flow Properties[J].Polymers & Polymer Composites,2003(6):487-504.
[2] Natalie Zdrazilova;Berenika Hausnerova;Takeshi Kitano;Petr Saha .Rheological Behaviour of PP/PET and Modified PP/PET Blends.II.Dynamic Viscoelastic Properties[J].Polymers & Polymer Composites,2004(5):433-447.
[3] Chiu HT;Hsiao YK .Compatibilization of poly(ethylene terephthalate)/polypropylene blends with maleic anhydride grafted polyethylene-octene elastomer[J].Journal of Polymer Research,2006(2):153-160.
[4] Heino M.;Hietaoja P.;Seppala J.;Kirjava J. .COMPATIBILIZATION OF POLYETHYLENE TEREPHTHALATE/POLYPROPYLENE BLENDS WITH STYRENE-ETHYLENE/BUTYLENE-STYRENE (SEBS) BLOCK COPOLYMERS[J].Journal of Applied Polymer Science,1997(2):241-249.
[5] Tao YJ;Mai KC .Non-isothermal crystallization and melting behavior of compatibilized polypropylene/recycled poly(ethylene terephthalate) blends[J].European Polymer Journal,2007(8):3538-3549.
[6] 陈蕾,喻爱芳,胡祖明,刘兆峰.PMMA-PET共混体系流变性能[J].高分子材料科学与工程,2003(03):152-155.
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