综述了TiO_2纳米薄膜光催化剂制备方法的最新进展,讨论了传统技术的新发展如改进的溶胶-凝胶法和微波辅助沉积法,同时也详述了水热溶剂热法、原位生长法及自组装法等新型制备技术,最后提出了TiO_2纳米薄膜制备技术今后的发展方向.
In this review,the latest advances in research on fabrications of titanium dioxide nano film photoca-talyst are summarized.Improvements of traditional techniques such as modified sol-gel method and microwave assisted deposition are discussed.Several novel preparing techniques including hydrothermal solvothermal technique,self-as-sembly and in situ synthesis are also explained in detail Suggestions for future research are put forward last.
参考文献
| [1] | Yijie Zhang;Xianfeng Li;Xiaoshe Hua .Sunlight photocatalysis in coral-like TiO_2 film[J].Scripta materialia,2009(3):296-299. |
| [2] | YONG-GANG ZHANG;LI-LI MA;JIA-LIN LI .In Situ Fenton Reagent Generated from TiO2/Cu2O Composite Film:a New Way to Utilize TiO2 under Visible Light Irradiation[J].Environmental Science & Technology: ES&T,2007(17):6264-6269. |
| [3] | Zhang X W;Lei L C .Effect of preparation methods on the structure and catalytic performance of TiO_2/AC photocata-lysts[J].Journal of Hazardous Materials,2008,153(1-2):827. |
| [4] | Watanabe T;Fukayama S;Miyauchi M et al.Photocata-lytic activity and photo-induced wettability conversion of TiO_2 thin film prepared by sol-gel process on a soda-lime glass[J].Journal of Sol-Gel Science and Technology,2000,19(1-3):71. |
| [5] | Deki S;Iizuka S;Mizuhata M et al.Fabrication of nano-structured materials from aqueous solution by liquid phase deposition[J].Journal of Electroanalytical Chemistry,2005,584(01):38. |
| [6] | Segawa K;Katsuta M .Kameda E TiO_2-coated on Al_2O_3 support prepared by the CVD method for HDS catalysts[J].Catalysis Today,1996,29(1-4):215. |
| [7] | 吴钧,施利毅,袁帅,陈怡,张雨.纳米TiO2/Ti管阵列薄膜催化剂的制备和性能[J].化学反应工程与工艺,2008(02):147-152. |
| [8] | 万晔,杨龙刚,于欢.溶胶凝胶法制备纳米TiO2薄膜及其性能的研究[J].沈阳建筑大学学报(自然科学版),2009(01):139-142. |
| [9] | 崔玉民,张文保.WO3/TiO2薄膜光催化降解ARB性能研究[J].稀有金属,2008(04):489-492. |
| [10] | H. Ichinose;H.Katsuki .Photocatalytic Activities of films prepared from peroxo-modified anatase sol with added TiO2 powder[J].Journal of the Ceramic Society of Japan,1999(1):73-77. |
| [11] | 戈磊,徐明霞,方海波,李岩.过氧钛酸溶胶前驱体制备TiO2薄膜及其光催化性能[J].硅酸盐学报,2005(03):330-334. |
| [12] | Ge L;Xu MX;Fang HB;Sun M .Preparation of TiO2 thin films from autoclaved Sol containing needle-like anatase crystals[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(2):720-725. |
| [13] | Ge L;Xu MX;Fang HB .Synthesis of titanium oxide layers on glass substrates with aqueous refluxed sols (RS) and photocatalytic activities[J].Journal of Materials Science,2007(13):4926-4934. |
| [14] | Balasubramanian G.;Dionysiou DD.;Suidan MT.;Subramanian Y.;Baudin I. Laine JM. .Titania powder modified sol-gel process for photocatalytic applications[J].Journal of Materials Science,2003(4):823-831. |
| [15] | Keshmiri M;Mohseni M;Troczynski T .Development of novel TiO2 sol-gel-derived composite and its photocatalytic activities for trichloroethylene oxidation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2004(4):209-219. |
| [16] | Chen Y;Dionysiou DD .A comparative study on physicochemical properties and photocatalytic behavior of macroporous TiO2-P25 composite films and macroporous TiO2 films coated on stainless steel substrate[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):129-137. |
| [17] | L.L.P. Lim;R.J. Lynch;S.-I. In .Comparison of simple and economical photocatalyst immobilisation procedures[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2009(2):214-221. |
| [18] | 管自生.高湿度下紫外光辐射对sol-gel TiO2薄膜强度、结构和亲水性能的影响[J].化学学报,2003(12):2025-2028. |
| [19] | 吕玉娟;洪伟良;李继贞 等.微波辐射溶胶-凝胶法制备TiO_2 薄膜及其降解铬黑T的活性[J].中国材料科技与设备,2006,3(04):39. |
| [20] | 任典君,王荣昌,夏四清.微波辅助液相沉积法制备TiO2薄膜光催化性能[J].稀有金属材料与工程,2008(06):989-994. |
| [21] | Vigil E.;Gonzalez B.;Zumeta I.;Doeteur S.;Peiro AM.;Gutierrez-Tauste D.;Domingo C.;Domenech X.;Ayllon JA. .The role of conducting-oxide-substrate type and morphology in TiO2 films grown by microwave chemical bath deposition (MW-CBD) and their photovoltaic characteristics[J].Journal of Crystal Growth,2004(1/4):366-374. |
| [22] | Zumeta I;Gonzalez B;Espinosa R et al.Two-layer TiO_2 nanostructured photoeleetrode with underlying film obtained by microwave-activated chemical bath deposition(MW-CBD)[J].Semiconductor Science and Technology,2004,19(05):L52. |
| [23] | Vigil, E.;Dixon, D.;Hamilton, J. W. J.;Byrne, J. A. .Deposition of TiO2 thin films on steel using a microwave activated chemical bath[J].Surface & Coatings Technology,2009(23):3614-3617. |
| [24] | Yuxiang Li;Min Guo;Mei Zhang;Xidong Wang .Hydrothermal synthesis and characterization of TiO_2 nanorod arrays on glass substrates[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2009(6):1232-1237. |
| [25] | Lee S H;Kang M S;Cho S M et al.Synthesis of TiO_2 photocatalyst thin film by solvothermal method with a small amount of water and its photocatalytic performance[J].Journal of Photochemistry and Photobiology A:Chemistry,2001,146(1-2):121. |
| [26] | Peng XS;Chen AC .Aligned TiO2 nanorod arrays synthesized by oxidizing titanium with acetone[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(16):2542-2548. |
| [27] | Xinsheng Peng;Jingpeng Wang;Dan F Thomas .Tunable growth of TiO_2 nanostructures on Ti substrates[J].Nanotechnology,2005(10):2389-2395. |
| [28] | Wu GS;Chen A .Direct growth of F-doped TiO2 particulate thin films with high photocatalytic activity for environmental applications[J].Journal of Photochemistry and Photobiology, A. Chemistry,2008(1):47-53. |
| [29] | Wu JM;Zhang TW;Zeng YW;Hayakawa S;Tsuru K;Osaka A .Large-scale preparation of ordered titania nanorods with enhanced photocatalytic activity[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(15):6995-7002. |
| [30] | Wu JM .Photodegradation of rhodamine B in water assisted by titania nanorod thin films subjected to various thermal treatments[J].Environmental Science & Technology: ES&T,2007(5):1723-1728. |
| [31] | Wu JM .Low-temperature preparation of titania nanorods through direct oxidation of titanium with hydrogen peroxide[J].Journal of Crystal Growth,2004(2/4):347-355. |
| [32] | Tengvall P;Elwing H;Lundstrom I .Titanium gel made from metallic titanium and hydrogen peroxide[J].Journal of Colloid and Interface Science,1989,130(02):405. |
| [33] | Yahui Wu;Mingce Long;Weimin CaiI;Sidi Dai;Chao Chen;Deyong Wu;Jing Bai .Preparation of photocatalytic anatase nanowire films by in situ oxidation of titanium plate[J].Nanotechnology,2009(18):185703-8. |
| [34] | Gao YF;Nagai M;Seo WS;Koumoto K .Template-free self-assembly of a nanoporous TiO2 thin film[J].Journal of the American Ceramic Society,2007(3):831-837. |
| [35] | Kim JH;Fujita S;Shiratori S .Fabrication and characterization of TiO2 thin film prepared by a layer-by-layer self-assembly method[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):83-89. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%