采用超声粉碎分散团聚磁性纳米Fe3O4粒子,用油酸对分散好的磁性粒子表面进行改性.结果表明,在纳米Fe3O4中油酸用量为0.5mL、超声次数为15次、每次2min、间隔时间为15s、pH值为7.5的条件下,改性效果最好,改性指数为0.87.红外光谱分析证明,油酸通过-COOH的"均化"与纳米Fe3O4粒子的表面结合实现了包覆改性,无分解和其它化学反应发生,改性效果良好.
参考文献
[1] | 都有为 .超微颗粒的物理特性[J].材料导报,1992,6(05):1. |
[2] | Jeong U;Teng X;Wang Y et al.Supermagnetic colloids controlled synthsis and niche applications[J].Advanced Materials,2007,19(01):33. |
[3] | Kondo A;Hiroko Kamura H;Higashitani K .Development and application of themo-sensitive magnetic immunomicro-spheres for antibody purification[J].Applied Microbiology and Biotechnology,1994,41(01):99. |
[4] | Goodwin S .Magnetic targeted carriers offer site-specific drug delivery[J].Oncol News Int,2000,9(05):22. |
[5] | Pitkethly M J.Radar absorbing materials and their potential use in aircraft structures[J].IEEE Colloquium on Low Profile Absorbers Scatters,1992(07):1. |
[6] | 龚涛,汪长春.具有核壳结构磁性复合微球的制备与表征[J].高分子学报,2008(11):1037-1042. |
[7] | R. Badescu;D. Condurache .Ferrofluid with modified stabilisant[J].Journal of Magnetism and Magnetic Materials,1999(1):197-200. |
[8] | 张金升,尹衍升,吕忆农,张银燕,马来鹏,张淑卿.磁性流体中纳米Fe3O4粒子包覆结构的研究[J].中国科学E辑,2003(07):609-613. |
[9] | 杨华,黄可龙,李卫.水基Fe3O4磁流体的制备和磁光特性[J].中南工业大学学报(自然科学版),2003(03):258-261. |
[10] | Chia-Lung Lin;Chia-Fen Lee;Wen-Yen Chiu .Preparation and properties of poly(acrylic acid)oligomer stabilized superparamagnetic ferrofluid[J].Journal of Colloid and Interface Science,2005(2):411-420. |
[11] | 王秀宇,杨桂琴,张之圣,严乐美,孟建华.磁流体制备中磁性颗粒的表面处理[J].应用化学,2005(05):525-529. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%