非晶碳薄膜由sp2和sp3杂化的碳原子组成.sp2和sp3碳原子的比例是决定非晶碳膜的结构和性能的重要参数.如何定量或定性地分析碳薄膜中sp2和sp3碳的含量一直是十分重要的问题.目前用来测定sp2和sp3碳及其比例的实验方法有13C核磁共振谱(NMR)、电子能量损失谱(EELS)、X射线光电子能谱(XPS)、椭圆偏振谱、拉曼光谱(Raman)、红外光谱(IR)等.综述了这些测定方法及其特点.
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