石墨烯材料的制备及其在电化学领域的应用

材料导报, 2011, 25(5): 55-78.

石墨烯材料的制备及其在电化学领域的应用

吴诗德 ^1, , 宋彦良 ^2, , 李超 ^3, , 王力臻 ^4, , 夏同驰 ^5, , 卫应亮 ^6, , 陈荣峰 ^7,

1.郑州轻工业学院河南省表界面科学重点实验室,郑州450002

2.郑州轻工业学院河南省表界面科学重点实验室,郑州450002

3.郑州轻工业学院河南省表界面科学重点实验室,郑州450002;河南省科学院,郑州450002;

4.郑州轻工业学院河南省表界面科学重点实验室,郑州450002

5.郑州轻工业学院河南省表界面科学重点实验室,郑州450002

6.郑州轻工业学院河南省表界面科学重点实验室,郑州450002;洛阳理工学院环境工程与化学系,洛阳471023

7.河南省科学院,郑州450002

基金项目: 国家自然科学基金(20871107) 河南省教育厅自然科学基金(2009A150031) 河南省杰出青年科学基金(0612002700)

关键词：石墨烯 , 结构 , 性质 , 制备方法 , 电化学 , 应用

Preparation and Applications in Electrochemistry of Graphene-based Materials

石墨烯具有独特的结构和优异的电学、热学、力学等性能,自从2004年被成功制备出来,一直是全世界范围内的一个研究热点.由于石墨烯具有巨大的表面体积比和独特的高导电性等特性,石墨烯及其复合材料在电化学领域中有着诱人的应用前景,因此,石墨烯材料的制备及其在电化学领域应用的研究是石墨烯材料研究的一个重要领域.综述了石墨烯与石墨烯复合材料的制备及其在超级电容器、锂离子电池、太阳能电池、燃料电池等电化学领域中应用的研究现状,展望了石墨烯材料的制备及其在电化学领域应用的未来发展前景.

参考文献

[1]	Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5296):666.
[2]	李旭,赵卫峰,陈国华.石墨烯的制备与表征研究[J].材料导报,2008(08):48-52.
[3]	傅强,包信和.石墨烯的化学研究进展[J].科学通报,2009(18):2657-2666.
[4]	杨全红,吕伟,杨永岗,王茂章.自由态二维碳原子晶体-单层石墨烯[J].新型炭材料,2008(02):97-103.
[5]	黄桂荣,陈建.石墨烯的合成与应用[J].炭素技术,2009(01):35-39.
[6]	Partoens B;Peeters FM .From graphene to graphite: Electronic structure around the K point[J].Physical review, B. Condensed matter and materials physics,2006(7):5404-1-5404-11-0.
[7]	Jiang Z;Zhang Y;Tan Y et al.Quantum hall effect in graphene[J].Solid State Communications,2007,143:14.
[8]	Geim A K .Graphene:Status and prospects[J].Science,2009,324:1530.
[9]	Zhang Y;Tan J W;Kim Ph et al.Experimental observation of the quantum hall effect and Berry's phase in graphene[J].Nature,2005,438:201.
[10]	Schadler LS.;Ajayan PM.;Giannaris SC. .Load transfer in carbon nanotube epoxy composites[J].Applied physics letters,1998(26):3842-3844.
[11]	Chae HK;Siberio-Perez DY;Kim J;Go Y;Eddaoudi M;Matzger AJ .A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature,2004(6974):523-527.
[12]	Stoller MD;Park SJ;Zhu YW;An JH;Ruoff RS .Graphene-Based Ultracapacitors[J].Nano letters,2008(10):3498-3502.
[13]	杨全红,唐致远.新型储能材料--石墨烯的储能特性及其前景展望[J].电源技术,2009(04):241-244.
[14]	Novoselov K S;Geim A K;Morozov S V et al.Two-di-mensional gas of massless dirac fermions in graphene[J].Nature,2005,438:197.
[15]	Seyller T;Bostwick A;Emtsev KV;Horn K;Ley L;McChesney JL;Ohta T;Riley JD;Rotenberg E;Speck F .Epitaxial graphene: a new material[J].Physica status solidi, B. Basic research,2008(7):1436-1446.
[16]	Pan Yi,Shi Dong-Xia,Gao Hong-Jun.Formation of graphene on Ru(0001) surface[J].中国物理B（英文版）,2007(11):3151-3153.
[17]	Cai W;Piner R D;Stadermann F J et al.Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide[J].Science,2008,321:1815.
[18]	Michael J.McAllister;Je-Luen Li;Douglas H.Adamson .Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(18):4396-4404.
[19]	Si Y;Samulski ET .Synthesis of water soluble graphene[J].Nano letters,2008(6):1679-1682.
[20]	Dato A;Radmilovic V;Lee ZH;Phillips J;Frenklach M .Substrate-free gas-phase synthesis of graphene sheets[J].Nano letters,2008(7):2012-2016.
[21]	Sidorov AN;Yazdanpanah MM;Jalilian R;Ouseph PJ;Cohn RW;Sumanasekera GU .Electrostatic deposition of graphene[J].Nanotechnology,2007(13):35301-1-35301-4-0.
[22]	Parvizi F;Teweldebrhan D;Ghost S et al.Properties of graphene produced by the high pressure high temperature growth process[J].Micro & Nano Letters,2008,3(01):29.
[23]	Dengyu Pan;Jingchun Zhang;Zhen Li;Minghong Wu .Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots[J].Advanced Materials,2010(6):734-738.
[24]	Elias D C;Nair R R;Mohiuddin T M G et al.Control of graphene's properties by reversible hydrogenation:Evidence for graphene[J].Science,2009,323(5914):610.
[25]	Huai-Ping Cong;Jia-Jun He;Yang Lu;Shu-Hong Yu .Water-Soluble Magnetic-Functionalized Reduced Graphene Oxide Sheets: In situ Synthesis and Magnetic Resonance Imaging Applications[J].Small,2010(2):169-173.
[26]	Zhang X Y;Huang Y;Wang Y et al.Synthesis and characterization of a graphene-C60 hybrid material[J].Carbon,2008,47:334.
[27]	Wei T;Luo G L;Fan Z J et al.Preparation of graphene nanosheet/polymer composites using in situ reduction-extractive dispersion[J].Carbon,2009,47:2290.
[28]	Y. Ding;Y. Jiang;F. Xu;J. Yin;H. Ren;Q. Zhuo;Z. Long;P. Zhang .Preparation of nano-structured LiFePO4/graphene composites by co-precipitation method[J].Electrochemistry communications,2010(1):10-13.
[29]	Chao Xu;Xin Wang;Junwu Zhu .Graphene—Metal Particle Nanocomposites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(50):19841-19845.
[30]	Williams G;Seger B;Kamat P V .TiO2-graphene nanocomposites UV-assisted photocatalytic reduction of graphene oxide[J].Nano Letters,2008,2(07):1487.
[31]	Nethravathi C;Rajamathi JT;Ravishankar N;Shivakumara C;Rajamathi M .Graphite oxide-intercalated anionic clay and its decomposition to graphene-inorganic material nanocomposites[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(15):8240-8244.
[32]	S R C VIVEKCHAND;CHANDRA SEKHAR ROUT;K S SUBRAHMANYAM .Graphene-based electrochemical supercapacitors[J].Journal of Chemical Sciences,2008(1):9-13.
[33]	Li, FH;Song, JF;Yang, HF;Gan, SY;Zhang, QX;Han, DX;Ivaska, A;Niu, L .One-step synthesis of graphene/SnO2 nanocomposites and its application in electrochemical supercapacitors[J].Nanotechnology,2009(45):455602:1-455602:6.
[34]	Wang, D.-W.;Li, F.;Zhao, J.;Ren, W.;Chen, Z.-G.;Tan, J.;Wu, Z.-S.;Gentle, I.;Lu, G.Q.;Cheng, H.-M. .Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode[J].ACS nano,2009(7):1745-1752.
[35]	Peng Guo;Huaihe Song;Xiaohong Chen .Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries[J].Electrochemistry communications,2009(6):1320-1324.
[36]	Wang G;Shen X;Yao J et al.Graphene nanosheets for enhanced lithium storage in lithium ion batteries[J].Carbon,2009,47:2049.
[37]	Yoo E J;Kim J;Hosono E et al.Large reversible Li storage graphene nanosheet families for use in rechargeable lithiumion batteries[J].Nano Letters,2008,8(08):2277.
[38]	Paek SM;Yoo E;Honma I .Enhanced Cyclic Performance and Lithium Storage Capacity of SnO2/Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure[J].Nano letters,2009(1):72-75.
[39]	Wang, D.;Choi, D.;Li, J.;Yang, Z.;Nie, Z.;Kou, R.;Hu, D.;Wang, C.;Saraf, L.V.;Zhang, J.;Aksay, I.A.;Liu, J. .Self-assembled tio2-graphene hybrid nanostructures for enhanced Li-ion insertion[J].ACS nano,2009(4):907-914.
[40]	Wang X;Zhi LJ;Mullen K .Transparent, conductive graphene electrodes for dye-sensitized solar cells[J].Nano letters,2008(1):323-327.
[41]	Wu J;Becerril H A;Bao Z et al.Organic solar cells with solution-processed graphene transparent electrodes[J].Applied Physics Letters,2008,92:263.
[42]	Li XL;Zhang GY;Bai XD;Sun XM;Wang XR;Wang E;Dai HJ .Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature nanotechnology,2008(9):538-542.
[43]	Muszynski R;Seger B;Kamat PV .Decorating graphene sheets with gold nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(14):5263-5266.
[44]	Zanella I;Fagan S B;Mota R et al.Electronic and magnetic properties of Ti and Fe on graphene[J].Journal of Physical Chemistry C,2008,112:9163.
[45]	Dimitrakakis GK;Tylianakis E;Froudakis GE .Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage[J].Nano letters,2008(10):3166-3170.

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