采用熔融拉伸法制备聚丙烯微孔膜,研究了不同冷拉程度对微孔膜微观结构和性能的影响.采用差示扫描量热仪、扫描电镜、毛细管流动分析仪测试后发现,随着冷拉拉伸比的增大,微孔膜拉伸曲线塑性平台减弱,对应差示扫描量热曲线中由于热定型过程结晶带来的吸热平台减弱.冷拉拉伸比为15％时,微孔膜具有较好的微观结构和透气性,冷拉拉伸比达到60％时,微孔分布和排列变差,孔径变小,孔隙率降低,透气性变差.热处理过程中由于Tie链结晶形成的不稳定结构在冷拉后转变为连接分离片晶的架桥,随着冷拉拉伸比的增大,这部分转变越彻底,但同时也带来片晶结构崩溃,导致孔径减小,性能变差.
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