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铝冶炼过程中会产生大量铝灰,铝灰中AlN对其综合利用和安全处置会产生显著影响.在系统分析AlN水解热力学基础上,以再生铝生产过程中产生的铝灰为原料,运用Design Expert软件设计二次正交旋转试验,研究铝灰中AlN的水解特征.结果表明:在303~373 K的温度范围内,铝灰中AlN的水解自发进行;液固比和水解时间对水解pH影响显著(P<0.01);水解温度和液固比间的交互作用影响明显(P<0.01).水解pH值与水解温度、液固比和水解时间的二次回归方程理论预测值与试验值相对误差仅为1%,可以用来预测和指导铝灰中AlN水解行为.

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