金属及活性氧化物表面的析氧电催化活性

功能材料, 2002, 33(4): 363-370.

金属及活性氧化物表面的析氧电催化活性

胡吉明 ^1, , 张鉴清 ^2, , 王建明 ^3, , 曹楚南 ^4,

1.浙江大学化学系电化学研究室,浙江杭州,310027

2.浙江大学化学系电化学研究室,浙江杭州,310027;金属腐蚀与防护国家重点实验室,辽宁沈阳,110016

3.浙江大学化学系电化学研究室,浙江杭州,310027

4.浙江大学化学系电化学研究室,浙江杭州,310027;金属腐蚀与防护国家重点实验室,辽宁沈阳,110016

基金项目: 中国博士后科学基金国家研究发展基金(G19990650)

关键词：金属 , 氧化物 , 析氧 , 电催化活性

Electrocatalytic activities of metals and active oxides for oxygen evolution

不同的金属及活性氧化物表现出析氧电催化活性上的差异.电极的析氧活性由电催化剂的自身材料因素与电极的活性表面积决定.在本文中对由材料因素引起的析氧电催化活性的内在差异、电催化活性与材料的其它相关物理化学参数间的关联进行介绍.重点介绍决定金属及氧化物析氧活性的"氧化物对控制"理论.

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金属及活性氧化物表面的析氧电催化活性

Electrocatalytic activities of metals and active oxides for oxygen evolution

参考文献