热压摩尔比为n(TiC):n(Ti):n(Si):n(Al)=2:1:1:0.2混合粉末制备的Ti3Si(1-x)AlxC2(0＜x≤0.16)材料在900℃～1 300℃空气中的恒温氧化行为遵循抛物线规律,但在1 200℃和1 300℃是一个两步抛物线过程.随着温度升高,氧化抛物线速率常数kp从900℃的2.45×10-10 kg2·m-4·s-1增大到1 300℃的5.71×10-9 kg2·m-4·s-1,计算的氧化活化能为110 kJ·mol-1±10kJ·mol-1.弥散分布在基体中的Al改变了Ti3SiC2材料的氧化机制,使试样表面形成由大量α-Al2O3和少量TiO2与SiO2组成的致密氧化层,从而提高了材料的抗氧化性.
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