介绍了合金负极的种类、反应类型以及制备方法,分析了嵌过程对结构和体积变化的影响,充放电区间对循环性能的影响以及首次循环不可逆容量产生的原因.合计负极材料因其高的理论比容量受到了越来越多的关注,但必须解决其体积膨胀大、循环性能不好的问题.按照结构相容性选择合适的合金体系和不同的制备方法,人们已经取得了一定的成果,但是离实用化还有一定的距离,必须有更大的创新.
参考文献
| [1] | K.D.Kepler;J.T.Vaughey .LixCu6Sn5 (0<x<13): An Intermetallic Insertion Electrode for Rechargeable Lithium Batteries[J].Electrochemical and solid-state letters,1999(7):307-309. |
| [2] | LareherD;Beaulieu L Y;Dahn J R et al.InsituX-RaystudyoftheelectrochemicalreactionofLiwithη'-Cu6Sn5[J].Journal of the Electrochemical Society,2000,147(05):1658. |
| [3] | FranssonL;Nordstrom;Thacheray M M et al.Structuraltransformationsinlithiatedη'-Cu6Sn5electrodesprobedbyinsituMossbauerspectroscopyandX-Raydiffraction[J].Journal of the Electrochemical Society,2002,149(06):A736. |
| [4] | XiaYY;Sakai T;Yoshinaga H et al.FlakeCu-Snalloysanegativeelectrodematerialsforrechargeablelithiumbatteries[J].Journal of the Electrochemical Society,2001,148(05):A471. |
| [5] | WolfenstineJ;Campos S;Behl W K et al.Nano-scaleCu6Sn5anodes[J].Journal of Power Sources,2002,109:230. |
| [6] | KimDG;Kim H;Kang T et al.NanosizedSn-Cu-Balloyanodepreparedbychemicalreductionforsecondarylithiumbatteries[J].Journal of Power Sources,2002,104:221. |
| [7] | Noriyuki Tamura;Ryuji Ohshita;Masahisa Fujimoto .Advanced Structures in Electrodeposited Tin Base Negative Electrodes for Lithium Secondary Batteries[J].Journal of the Electrochemical Society,2003(6):A679-A683. |
| [8] | S. D. Beattie;J. R. Dahn .Single Bath, Pulsed Electrodeposition of Copper-Tin Alloy Negative Electrodes for Lithium-ion Batteries[J].Journal of the Electrochemical Society,2003(7):A894-A898. |
| [9] | J.Yang;M.Wachtler .Sub-Microcrystalline Sn and Sn-SnSb Powders as Lithium Storage Materials for Lithium-Ion Batteries[J].Electrochemical and solid-state letters,1999(4):161-163. |
| [10] | Rom I.;Papst I.;Schmied M.;Besenhard JO.;Hofer F.;Winter M.;Wachtler M. .Electron microscopical characterization of Sn/SnSb composite electrodes for lithium-ion batteries[J].Solid state ionics,2001(3/4):329-336. |
| [11] | WachtlerM;Besenhard J O;Winter M .Tinandtin-basedintermetallicsasnewanodematerialsforlithium-ioncells[J].Journal of Power Sources,2001,94:189. |
| [12] | WachtlerM;Winter M;Besenhard J O .AnodicmaterialsforrechargeableLi-batteries[J].Journal of Power Sources,2002,105:151. |
| [13] | Beaulieu L.Y.;Dahn J.R. .The Reaction of Lithium with Sn-Mn-C Intermetallics Prepared by Mechanical Alloying[J].Journal of the Electrochemical Society,2000(9):3237-3241. |
| [14] | MaoO;Dunlap R A;Dahn J R .MechanicallyalloyedSnFe-CpowdersasanodematerialsforLi-ionbatteriesITheSn2Fe-Csystem[J].Journal of the Electrochemical Society,1999,146:405. |
| [15] | MaoO;Dahn J R .MechanicallyalloyedSn-Fe-CpowdersasanodematerialsforLi-ionbatteriesⅡTheSn-Fesystem[J].Journal of the Electrochemical Society,1999,146:414. |
| [16] | MaoO;Dahn J R .MechanicallyalloyedSn-Fe-CpowdersasanodematerialsforLi-ionbatteriesⅢtheSn2Fe:SnFe3Cactive/inactivecomposites[J].Journal of the Electrochemical Society,1999,146:423. |
| [17] | L. Y. Beaulieu;K. C. Hewitt;R. L. Turner .The Electrochemical Reaction of Li with Amorphous Si-Sn Alloys[J].Journal of the Electrochemical Society,2003(2):A149-A156. |
| [18] | eaulieuLY;Hatchard T D;Dahn J R et al.ReactionofLiwithalloythinfilmstudiesbyinsituAFM[J].Journal of the Electrochemical Society,2003,150(11):A1457. |
| [19] | Jingtian Yin;Masashi Wada;Seiji Yoshida .New Ag-Sn Alloy Anode Materials for Lithium-Ion Batteries[J].Journal of the Electrochemical Society,2003(8):A1129-A1135. |
| [20] | LeeHY;Jang S W;Baik H K et al.LithiumstoragepropertiesofnanocrystallineNi3Sn4alloyspreparedbymechanicalalloying[J].Journal of Power Sources,2002,112:8. |
| [21] | Lianbang Wang;Shingo Kitamura;Tsukasa Sonoda .Electroplated Sn-Zn Alloy Electrode for Li Secondary Batteries[J].Journal of the Electrochemical Society,2003(10):A1346-A1350. |
| [22] | FangL;Chowdari B V R .Sn-Caamorphousalloyasanodeforlithium-ionbattery[J].Journal of Power Sources,2001,97-98:181. |
| [23] | FranssonLML;Vaughey J T;Thacheray M M et al.PhasetransitioninlithiumedCu2Sbanodesforlithiumbatteries:aninsituX-Raydiffractionstudy[J].Electrochemistry Communications,2001,3:317. |
| [24] | VaugheyJT;O'Hara J;Thacheray M M .Intermetallicinsertionelectrodeswithazinc-blende-typestructureforLibatteries:astudyofLixInSb0x3[J].Electrochemical and Solid-State Letters,2000,3:13. |
| [25] | KimH;Choi J;Kang T et al.TheinsertionmechanismoflithiumintoMg2SianodematerialsforLi-ionbatteries[J].Journal of the Electrochemical Society,1999,146:4401. |
| [26] | Wang G.X.;Sun L. .Nanocrystalline NiSi alloy as an anode material for lithium-ion batteries[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):249-252. |
| [27] | WangGX;Sun L;Liu H K et al.Innovativenanosizelithiumstoragealloyswithsilicaasactivecenter[J].Journal of Power Sources,2000,88:278. |
| [28] | enedekR;Thacheray M M .Lithiumreactionswithintermetallic-compoundelectrodes[J].Journal of Power Sources,2002,110:406. |
| [29] | ThacherayMM;Vaughey J T;Edstrom K et al.Structuralconsiderationsofintermetallicelectrodesforlithiumbatteries[J].Journal of Power Sources,2003,113:124. |
| [30] | TamuraN;Ohshita R;Yonezu I et al.StudyontheanodebehaviorofSnandSn-Cualloythin-filmelectrodes[J].Journal of Power Sources,2002,107(01):48. |
| [31] | L.Y. Beaulieu;S.D. Beattie;T.D. Hatchard .The Electrochemical Reaction of Lithium with Tin Studied By In Situ AFM[J].Journal of the Electrochemical Society,2003(4):A419-A424. |
| [32] | S.D. Beattie;T. Hatchard;A. Bonakdarpour .Anomalous, High-Voltage Irreversible Capacity in Tin Electrodes for Lithium Batteries[J].Journal of the Electrochemical Society,2003(6):A701-A705. |
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