本文简要介绍了电沉积晶态、纳米晶、非晶态和复合镍钼基合金电极的研究现状,从几何因素上分析了不同表面结构的电极性能,并对比分析了相同表面结构下的二元、三元甚至多元镍钼基合金电极的电催化活性.最后指出探究非晶态与纳米晶混合结构的形成和析氢机理是今后研究电极材料的重要方向.
参考文献
[1] | Jaksic J M;Vojnovic M V et al.Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes[J].Electrochemical Acts,2000,45:4151. |
[2] | 查仝性.电极过程动力学导论[M].北京:科学出版社,2002:250. |
[3] | Jaksic M M .Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valance-bond theory[J].Journal of Molecular Catalysis,1986,38:161. |
[4] | Chen L;Lasia A .Hydrogen evolution reaction on nickel-molybdenum powder electrodes[J].Journal of the Electrochemical Society,1992,139(12):3458. |
[5] | Rodriguez-Valdez L M;Estrada-Guel I et al.Electrochemical performance of hydrogen evolution reaction of Ni-Mo electrodes obtained by mechanical aUoying[J].International Journal of Hydrogen Energy,2004,29(11):1411. |
[6] | Gennero de Chialvo M R;Chialvo A C .Hydrogen evolution reaction on smooth Ni(1 minus x) plus Mo(x) alloys (0 less than equivalent to x less than equivalent to 0.25)[J].Journal of Electroanalytical Chemistry,1998,448:87. |
[7] | 王传义,刘春艳,沈涛.半导体光催化剂的表面修饰[J].高等学校化学学报,1998(12):2013-2019. |
[8] | Simpraga R.;Conway BE.;Bai L. .REAL AREA AND ELECTROCATALYSIS FACTORS IN HYDROGEN EVOLUTION KINETICS AT ELECTRODEPOSITED NI-MO AND NI-MO-CD COMPOSITES - EFFECT OF CD CONTENT AND NATURE OF SUBSTRATE[J].Journal of Applied Electrochemistry,1995(7):628-641. |
[9] | Gala J;Malachowski A;Nawrat G .Electrolytic nickel-molyb-denum-vanadium alloy coatings as a material with a decreased hydrogen overvoltage[J].Journal of Applied Electrochemistry,1984,14:221. |
[10] | Raj I A;Vasu K I .Transition metal-based cathodes for hydrogen evolution in alkaline solution:electrocatalysis on nickelbased ternary electrolytic codeposits[J].Journal of Applied Electrochemistry,1992,22:471. |
[11] | 程鹏里;石秋芝.析氢电催化剂Ni-Mo-Pb合金的研究[J].河南化工,1996(06):119. |
[12] | 程鹏里;石秋芝;杨长春 .镍-钼-铊电极的析氢性能[J].郑州大学学报(自然科学版),1996,28(01):65. |
[13] | 李聪,许洪胤,杜朝军,郑盛会.电沉积Ni-Mo-P合金及其析氢电催化性能的研究[J].电镀与环保,2005(01):10-11. |
[14] | Huot J Y et al.Low hydrogen overpotential nanocrystalline Ni-Mo cathodes for alkaline water electrolysis[J].Journal of the Electrochemical Society,1991,138:1316. |
[15] | 黄令;许书楷;周绍民 等.纳米晶镍-钼合金电沉积层的结构与性能[J].应用化学,1999,16(02):38. |
[16] | 黄令;辜敏;杨防阻.纳米晶Ni-Mo-Fe合金薄膜的结构与析氢行为[A].,2001:215. |
[17] | 黄令,杨防阻,许书楷,周绍民.纳米晶Ni-M0-C0合金镀层的结构与析氢行为[J].应用化学,2001(10):767-771. |
[18] | 罗北平,龚竹青,任碧野,杨余芳,陈梦君.高析氢催化活性和稳定性的纳米晶Ni-Fe-Mo-Co合金[J].功能材料,2006(06):940-943. |
[19] | 谢支华,邱于兵,吴楼涛.一种新型活性阴极材料的制备和性能[J].材料研究学报,2003(01):83-86. |
[20] | 胡伟康;申泮文;张允什.电镀条件对镍钼合金镀层结构组织和催化活性的影响[J].南开大学学报(自然科学版),1994(03):17. |
[21] | Hu CC.;Weng CY. .Hydrogen evolving activity on nickel-molybdenum deposits using experimental strategies[J].Journal of Applied Electrochemistry,2000(4):499-506. |
[22] | 胡伟康;张允什;宋德瑛 等.非晶态Ni-Mo-Fe合金作电解水析氧反应电极[J].功能材料,1995,26(05):456. |
[23] | 杨静,张存中,吴仲达.非晶态Ni-Mo-Co合金电极的制备和析氢性能[J].应用化学,2000(05):475-478. |
[24] | 马洁,刘顺诚,江琳才,蒋雄.纳米晶Ni-Mo合金复合镀层中钼含量对析氢反应的影响[J].化学学报,1997(04):363-369. |
[25] | 虞慰曾.在纳米晶Co-Mo/Ni复合电极上的析氢反应[J].电化学,1996(01):47. |
[26] | 施晶莹,肖秀峰,朱则善.(Ni-Mo)-WC电极在碱性介质中的电催化析氢性能[J].福建师范大学学报(自然科学版),2002(03):46-49. |
[27] | 范少华;蔡乃才;桂岳琼 .古Ni-Mo和稀土储氢合金的电催化析氢电极[J].武汉大学学报(自然科学版),1998,44(04):703. |
[28] | 李克锋,王为,鞠峰,钱文鲲.电化学技术制备高效析氢电极[J].电镀与精饰,2004(01):27-30. |
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