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  4. 相转移催化在高分子化合物合成中的应用

催化学报 , 2003, 24(9): 716-724.

相转移催化在高分子化合物合成中的应用

曲荣君 1, , 孙昌梅 2, , 王春华 3, , 纪春暖 4, , 成国祥 5,

1.天津大学材料科学与工程学院,天津,300072;烟台师范学院化学与材料科学学院,山东烟台,264025

2.烟台师范学院化学与材料科学学院,山东烟台,264025

3.烟台师范学院化学与材料科学学院,山东烟台,264025

4.烟台师范学院化学与材料科学学院,山东烟台,264025

5.天津大学材料科学与工程学院,天津,300072

基金项目:   山东省自然科学基金(Q99B15)   国家自然科学基金(29906008)  

关键词： 相转移催化 , 高分子合成 , 季铵盐 , 冠醚

Polymer Synthesis by Phase-Transfer Catalysis

综述了相转移催化用于高分子化合物合成的主要研究进展. 介绍了季铵盐类及冠醚类相转移催化剂在高聚物的亲核取代反应、阴离子开环聚合反应及自由基聚合反应中的应用. 重点总结了亲核取代反应中聚苯乙烯类化合物的功能化及化学修饰,包括合成路线、反应机理、温度以及催化剂和溶剂的种类与用量等因素对反应的影响. 冠醚类化合物的催化效果略优于季铵盐类化合物,而后者的成本低、毒性小、应用更广泛,其催化的反应应作为今后研究的重点,以期将相转移催化技术尽早用于工业化生产.

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