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The secondary hardening, the austenite grain coarsening and the surface decarburization phenomenon of Nb-bearing spring steel were investigated, and the effects of niobium on tempered microstructure was studied using scanning electron microscope. The results show that the micro-addition of niobium increases the tempering resistance and produces secondary hardening. The effect of niobium on the size and distribution of cementite particles is one of the primary reasons to increase the hardness after tempering. The grain-coarsening temperature of the spring steel is raised 150 ℃ due to Nb-addition. Furthermore, both the secondary hardening and the austenite grain coarsening phenomenon congruously demonstrate niobium begins observably dissolving above 1100 ℃ in the spring steel. Besides, niobium microalloying is an effective and economy means to decrease the decarburization sensitivity of the spring steels.

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