本文报道了一种金属有机配位聚合物非线性光学晶体--丁二酸锌Zn(C4H4O4)大尺寸单晶生长.通过恒温蒸发法生长出尺寸为7 mm×8 mm×2 mm 的单晶.测定了它在水中溶解度-温度曲线.通过水溶液红外光谱阐明了不同pH值时溶液中各种粒子的浓度分布.借助红外光谱研究了pH值、温度等对晶体生长的影响.Kurtz粉末倍频效应测定证实了丁二酸锌具有非线性光学性能,其倍频强度是KDP的6.5倍.
参考文献
| [1] | Das S;Jana A;Ramanathan V et al.Design and Synthesis of 1,10-phenanthroline Based Zn(Ⅱ)Complexes Bearing 1D Push-pull NLO-phores for Tunable Quadratic Nonlinear Optical Properties[J].Journal of Organometallic Chemistr,2006,691:2512-2516. |
| [2] | Owen R.Evans;Wenbin Lin .Rational Design of Nonlinear Optical Materials Based on 2D Coordination Networks[J].Chemistry of Materials,2001(9):3009-3017. |
| [3] | Xintao Wu;Shaowu Du;Zhihua Li .Construction of two novel 2D layer Mo(W)/Cu/S polymers using bidentate thiolato ligands as linkers[J].Inorganic Chemistry Communications,2006(1):79-81. |
| [4] | Lin W B;Wang Z Y;Ma L .A Novel Octupolar Metal-organic NLO Material Based on a Chiral 2D Coordination Network[J].Journal of the American Chemical Society,1999,121:11249-11250. |
| [5] | Yong-Tao Wang;Hai-Hua Fan;He-Zhou Wang;Xiao-Ming Chen .A Solvothermally in Situ Generated Mixed-ligand Approach for NLO-Active Metal-Organic Framework Materials[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2005(12):4148-4150. |
| [6] | Yao Kang;Yuan-Gen Yao;Ye-Yan Qin;Jian Zhang;Yu-Biao Chen;Zhao-Ji Li;Yi-Hang Wen;Jian-Kai Cheng;Rui-Feng Hu .A novel ligand-unsupported 3D framework polymer of trimeric copper(I)) and its NLO property[J].Chemical communications,2004(9):1046-1047. |
| [7] | Cannan R K;Kibrick A .Complex Formation between Carboxylic Acids and Divalent Metal Cations[J].Journal of the American Chemical Society,1938,60:2314-2320. |
| [8] | Mcauley A;Nancollas G H;Torrance K .Thermodynamics of Ion Association.XIII.Divalent Metal Succinates[J].Inorganic Chemistry,1967,6:136-138. |
| [9] | Soga K;Imai E;Hattori I .Alternating Coplymerization of CO2 and Propylene Oxide with the Catalysts Prepared from Zn(OH)2 and Various Dicarboxylic Acids[J].Polymer Journal,1981,13(04):407-410. |
| [10] | Sun H;Pa M .Reduction of Catalyst Usage in Epoxide/CO2 Polymerization[P].United States Patent,USP:4789727,1988-6. |
| [11] | 李小俊,胡克良,黄允兰,周贵恩.红外光谱对碱土金属二元羧酸盐结构的研究[J].光谱学与光谱分析,2002(03):392-395. |
| [12] | Randhawa BS;Gandotra K .A comparative study on the thermal decomposition of some transition metal carboxylates[J].Journal of thermal analysis and calorimetry,2006(2):417-424. |
| [13] | ZHENG Yue-qing,PETERS Karl,von SCHNERING Hans Georg.Synthesis and Characterization of Zinc Succinate, Zn(C4H4O4)[J].高等学校化学研究(英文版),2001(01):20-25. |
| [14] | Thomas A B;Heather L M;Alexandra M Z S.Hydrothermal Syntheses and Crystal Structures of Three Zinc Succinates:Zn(C4H4O4)-α,Zn(C4H4O4)-β and K2Zn(C4H4O4)2[J].Dalton Transactions,2003:936-939. |
| [15] | 中本一雄;黄德如;汪仁庆.无机和配位化合物的红外和拉曼光谱[M].北京:化学工业出版社,1986:324. |
| [16] | Kagarise R E .Spectroscopic Studies on the Soaps of Phenylstearic Acid.I.Infrared Absorption Spectra and the Hydrolysis of Soap Films[J].Journal of Physical Chemistry,1955,59(03):271-277. |
| [17] | PDF No.51-2305.PDF No.51-2305.International Center for Diffraction Data[S].Pennsylvania,USA |
| [18] | Kurtz S K;Perry T T .A Powder Technique for the Evaluation of Nonlinear Optical Materials[J].Journal of Applied Physics,1968,39:3798-3813. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%